Hostname: page-component-586b7cd67f-vdxz6 Total loading time: 0 Render date: 2024-11-30T23:56:41.296Z Has data issue: false hasContentIssue false
  • English
  • Français

Upconversion fluorescence in Nd3+/Yb3+ co-doped titanate glasses prepared by containerless method

Published online by Cambridge University Press:  14 November 2011

Xiuhong Pan ,
Jianding Yu ,
Yan Liu  and
Minghui Zhang
Xiuhong Pan*
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Jianding Yu
Affiliation:
Japan Aerospace Exploration Agency, ISS Science Project Office, Tsukuba 305-8500, Japan
Yan Liu
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
Minghui Zhang
Affiliation:
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Nd3+/Yb3+ co-doped TiO2–La2O3 glasses modified by ZrO2 were fabricated by containerless method. Under the excitation of 980 nm lasers, three intense emissions centered at 521, 545, and 655 nm were observed, which are assigned to the Nd3+: 4G9/2→4I9/2, 4G7/2→4I9/2, and 4G7/2→4I13/2 transitions, respectively. Besides, two very weak emission bands at 496 and 603 nm were also found due to the Nd3+ transition of 2G9/2→4I9/2 and 4G5/2 (or 2G7/2)→4I9/2, respectively. Pumping powder dependence of emission intensity suggests a two-photon adsorption process responsible for the upconversion luminescence. A combined phonon-assisted and cooperative sensitization mechanism is presented to interpret the energy transfer from Yb3+ to Nd3+ ions. In addition, the highest intensity of luminescence was found for the glass with 1.2 mol% Nd3+, and the upconversion efficiency can be enhanced by increasing of ZrO2 content.

Keywords

LuminescenceNdOxide
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 23 , 14 December 2011 , pp. 2907 - 2911
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1.Giri, N.K., Singh, A.K., and Rai, S.B.: Efficient blue upconversion emission in Tm3+ via energy transfer from Yb3+ doped in lithium modified tellurite glass. J. Appl. Phys. 101, 033102 (2007).CrossRefGoogle Scholar
2.Silva, D.M., Kassab, L.R.P., Luthi, S.R., Araujo, C.B., Gomes, A.S.L., and Bell, M.J.V.: Frequency upconversion in Er3+ doped PbO-GeO2 glasses containing metallic nanoparticles. Appl. Phys. Lett. 90, 081913 (2007).CrossRefGoogle Scholar
3.Fernandez, J., Balda, R., Mendioroz, A., Sanz, M., and Adam, J.L.: Up-conversion processes in Nd3+ -doped fluorochloride glass. J. Non-Cryst. Solids 287, 437 (2001).CrossRefGoogle Scholar
4.Annapurna, K., Dwivedi, R.N., Kundu, P., and Buddhudu, S.: NIR emission and upconversion luminescence spectra of Nd3+:ZnO-SiO2-B2O3 glass. Mater. Lett. 57, 2095 (2003).CrossRefGoogle Scholar
5.Verma, R.K., Kumar, K., and Rai, S.B.: UV/blue upconversion in Nd3+:TeO2 glass: Effect of modifiers and heat treatment on the fluorescence bands. Spectrochim. Acta, Part A 74, 776 (2009).CrossRefGoogle ScholarPubMed
6.Lakshminarayana, G., Ruan, J., and Qiu, J.: NIR luminescence from Er-Yb, Bi-Yb and Bi-Nd codoped germinate glasses for optical amplication. J. Alloy. Compd. 476, 878 (2009).CrossRefGoogle Scholar
7.Zhang, W.J., Chen, Q.J., Qian, Q., Zhang, Q.Y., and Jiang, Z.H.: Cooperative energy transfer in Tb3+/Yb3+ and Nd3+/Yb3+/Tb3+ codoped oxyfluorede glasses. Physica B 405, 1062 (2010).CrossRefGoogle Scholar
8.Som, T. and Karmakar, B.: Green and red fluorescence upconversion in neodymium doped low phonon antimony glasses. J. Alloy. Compd. 476, 383 (2009).CrossRefGoogle Scholar
9.Iparraguirre, I., Azkargorta, J., Fernandez-Navarro, J.M., Al-Saleh, M., Fernandez, J., and Balda, R.: Laser action and upconversion of Nd3+ in tellurite bulk glass. J. Non-Cryst. Solids 353, 990 (2007).CrossRefGoogle Scholar
10.Kumar, J.S., Babu, A.M., Sasikala, T., and Moorthy, L.R.: NIR fluorescence and visible upconversion studies of Nd3+ ions in calcium fluorobarate glasses. Chem. Phys. Lett. 484, 207 (2010).CrossRefGoogle Scholar
11.Porto, S.P.S., Fleury, P.A., and Damen, T.C.: Raman spectra of TiO2, MgF2, ZnF2, FeF2, and MnF2. Phys. Rev. 154, 522 (1967).CrossRefGoogle Scholar
12.Mazza, T., Barborini, E., Piseri, P., Milani, P., Cattaneo, D., Li Bassi, A., Bottani, C.E., and Ducati, C.: Raman spectroscopy characterization of TiO2 rutile nanocrystals. Phys. Rev. B 75, 045416 (2007).CrossRefGoogle Scholar
13.Mendioroz, A., Balda, R., Al-Saleh, M., and Fernanders, J.: Origin of the infrared to visible upconversion mechanisms in Nd3+-doped potassium lead chloride crystal. Opt. Mater. 27, 1704 (2005).CrossRefGoogle Scholar
14.Zhang, J., Heo, J., Zhao, X., and Chung, W.: Compositional dependences on the mechanism of upconversion in Nd3+/Tm3+ co-doped chalcohalide glasses. J. Non-Cryst. Solids 357, 2421 (2011).CrossRefGoogle Scholar
15.Wei, D., Huang, Y., Shi, L., Qiao, X., and Seo, H.J.: Upconversion luminescence from Nd3+ ions doped in NaBi(WO4)2 single crystal. J. Rare Earths 27, 905 (2009).CrossRefGoogle Scholar
16.Wang, D., Guo, Y., Wu, X., and Zhang, Y.: Green, orange, and red upconversion luminescence in Nd3+/Yb3+:Cs2NaGdCl6 powders under 785nm laser excitation. J. Rare Earths 26, 880 (2008).CrossRefGoogle Scholar
17.Rosa, E.D., Torres, L.A.D., Salas, P., and Rodriguez, R.A.: Visible light emission under UV and IR excitation of rare earth doped ZrO2 nanophosphor. Opt. Mater. 27, 1320 (2005).CrossRefGoogle Scholar
18.Pollnau, M., Gamelin, D.R., Luthi, S.R., Gudel, H.U., and Hehlen, M.P.: Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems. Phys. Rev. B 61, 3337 (2000).CrossRefGoogle Scholar
19.Singh, S.K., Kumar, K., and Rai, S.B.: Optical properties and switching behavior in Gd2O3:Er3+ nanophosphor. J. Appl. Phys. 106, 093520 (2009).CrossRefGoogle Scholar
20.Zhou, B., Pun, E.Y., Lin, H., Yang, D., and Huang, L.: Judd-Ofelt analysis, frequency upconversion, and infrared photoluminescence of Ho3+ doped and Ho3+/Yb3+ codoped lead bismuth gallate oxide glasses. J. Appl. Phys. 106, 103105 (2009).CrossRefGoogle Scholar
21.Santos, P.V., Vermelho, M.V.D., Gouveia, E.A., De Araujo, M.T., Neto, A.S.G., Cassanjes, F.C., Ribeiro, S.J.L., and Messaddeq, Y.: Infrared-to-visible frequency upconversion in Pr3+/Yb3+ and Er3+/Yb3+ codoped tellurite glasses. J. Alloy. Compd. 344, 304 (2002).CrossRefGoogle Scholar
22.Eiichiro, N. and Shigeo, S.: Cooperative luminescence in YbPO4. Phys. Rev. Lett. 25, 1710 (1970).Google Scholar
23.Tirtha, S. and Basudeb, K.: Nano Au enhanced upconversion in dichroic Nd3+: Au-antimony glass nanocomposites. Solid State Sci. 11, 1044 (2009).CrossRefGoogle Scholar