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Influence of growth temperature on the structure, composition and bonding character of nitrogen-doped multiwalled carbon nanotubes

Published online by Cambridge University Press:  09 February 2011

Yu Zhang ,
Lujun Pan ,
Bin Wen ,
Xiaoyang Song ,
Chenguang Liu  and
Tingju Li
Yu Zhang*
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
Lujun Pan
Affiliation:
School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
Bin Wen
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
Xiaoyang Song
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
Chenguang Liu
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
Tingju Li*
Affiliation:
School of Materials Science and Engineering, Dalian University of Technology, Dalian, Liaoning 116024, People’s Republic of China
*
a)Address all correspondence to this author. e-mail: [email protected]
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Abstract

Nitrogen-doped multiwalled carbon nanotubes (N-doped MWNTs) were synthesized in a large quantity by the pyrolysis of pyridine at various temperatures in the range of 750–950 °C. The influence of temperature on the morphology, composition, thermal stability, and bonding nature of N-doped MWNTs was investigated. It is found that the yield of N-doped MWNTs increases linearly with the increase of the growth temperature. The maximum N content (4.6 at%) in MWNTs was obtained from a sample grown at 900 °C. N-doped MWNTs synthesized at 950 °C possess a unique drumlike morphology with the highest oxidizing temperature (535 °C). It is evidenced that N atoms are incorporated into the graphitic network in three different bonding forms and their relative content is affected by the growth temperature, which shows a clear influence on the morphology of N-doped MWNTs.

Keywords

Chemical Vapor Deposition (CVD) (deposition)Thermogravimetric Analysis (TGA)X-ray Photoelectron Spectroscopy (XPS)
Type
Articles
Information
Journal of Materials Research , Volume 26 , Issue 3 , 14 February 2011 , pp. 443 - 448
Copyright
Copyright © Materials Research Society 2011

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