Hostname: page-component-cd9895bd7-8ctnn Total loading time: 0 Render date: 2024-12-18T05:28:11.558Z Has data issue: false hasContentIssue false
  • English
  • Français

Facile synthesis of nearly monodisperse AgCu alloy nanoparticles with synergistic effect against oxidation and electromigration

Published online by Cambridge University Press:  12 March 2019

Qianqian Dou Open the ORCID record for Qianqian Dou [Opens in a new window] ,
Yang Li ,
Ka Wai Wong  and
Ka Ming Ng
Qianqian Dou
Affiliation:
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong 999077, China
Yang Li
Affiliation:
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong 999077, China
Ka Wai Wong
Affiliation:
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong 999077, China
Ka Ming Ng*
Affiliation:
Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, Hong Kong 999077, China
*
a)Address all correspondence to this author. e-mail: [email protected]
Get access

Abstract

Bimetallic nanoparticles (NPs) have attracted a great deal of attention due to the synergistic interaction between metal components. In this work, the thermal process in which the reducing agent is not expensive or hazardous as those in traditional methods was employed to prepare alloy Ag–Cu NPs. The molar ratio between Ag and Cu was varied from 1:9 to 9:1. Nearly monodisperse NPs with alloy structure were characterized by X-ray diffraction and high-resolution transmission electron microscopy with energy dispersive spectroscopy In comparison with monometallic Ag and Cu NPs, the alloyed Ag–Cu NPs showed better monodispersity, especially when the ratio between Ag and Cu was 1:1. Moreover, the alloyed Ag–Cu NPs exhibited enhanced resistance to electromigration and oxidation, the respective problem of pure Ag and Cu. The alloyed Ag–Cu NPs also exhibited improved properties than a mixture of Ag–Cu NPs. This study should serve as the foundation for exploring high performance alloyed bimetallic NPs.

Keywords

coppersilveralloyoxidationelectromigration
Type
Article
Information
Journal of Materials Research , Volume 34 , Issue 12 , 28 June 2019 , pp. 2095 - 2104
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Karthik, P. and Singh, S.P.: Conductive silver inks and their applications in printed and flexible electronics. RSC Adv. 5, 77760 (2015).Google Scholar
Karthik, P. and Singh, S.P.: Copper conductive inks: Synthesis and utilization in flexible electronics. RSC Adv. 5, 63985 (2015).Google Scholar
Paszkiewicz, M., Gołąbiewska, A., Rajski, Ł., Kowal, E., Sajdak, A., and Zaleska-Medynska, A.: Synthesis and characterization of monometallic (Ag, Cu) and bimetallic Ag–Cu particles for antibacterial and antifungal applications. J. Nanomater. 2016, 6 (2016).CrossRefGoogle Scholar
Lee, C., Kim, N.R., Koo, J., Lee, Y.J., and Lee, H.M.: Cu–Ag core–shell nanoparticles with enhanced oxidation stability for printed electronics. Nanotechnology 26, 455601 (2015).CrossRefGoogle ScholarPubMed
Gao, Y., Zhang, H., Jiu, J., Nagao, S., Sugahara, T., and Suganuma, K.: Fabrication of a flexible copper pattern based on a sub-micro copper paste by a low temperature plasma technique. RSC Adv. 5, 90202 (2015).CrossRefGoogle Scholar
Carenco, S., Boissiere, C., Nicole, L., Sanchez, C., Le Floch, P., and Mézailles, N.: Controlled design of size-tunable monodisperse nickel nanoparticles. Chem. Mater. 22, 1340 (2010).CrossRefGoogle Scholar
Jo, Y.H., Jung, I., Choi, C.S., Kim, I., and Lee, H.M.: Synthesis and characterization of low temperature Sn nanoparticles for the fabrication of highly conductive ink. Nanotechnology 22, 225701 (2011).CrossRefGoogle ScholarPubMed
Chen, Z., Mochizuki, D., Maitani, M.M., and Wada, Y.: Facile synthesis of bimetallic Cu–Ag nanoparticles under microwave irradiation and their oxidation resistance. Nanotechnology 24, 265602 (2013).CrossRefGoogle ScholarPubMed
Butovsky, E., Perelshtein, I., and Gedanken, A.: Air stable core–shell multilayer metallic nanoparticles synthesized by RAPET: Fabrication, characterization and suggested applications. J. Mater. Chem. 22, 15025 (2012).CrossRefGoogle Scholar
Choi, E., Lee, S., and Piao, Y.: A solventless mix–bake–wash approach to the facile controlled synthesis of core–shell and alloy Ag–Cu bimetallic nanoparticles. CrystEngComm 17, 5940 (2015).CrossRefGoogle Scholar
Wu, W., Lei, M., Yang, S., Zhou, L., Liu, L., Xiao, X., Jiang, C., and Roy, V.A.: A one-pot route to the synthesis of alloyed Cu/Ag bimetallic nanoparticles with different mass ratios for catalytic reduction of 4-nitrophenol. J. Mater. Chem. A 3, 3450 (2015).CrossRefGoogle Scholar
Rout, L., Kumar, A., Dhaka, R.S., and Dash, P.: Bimetallic Ag–Cu alloy nanoparticles as a highly active catalyst for the enamination of 1,3-dicarbonyl compounds. RSC Adv. 6, 49923 (2016).CrossRefGoogle Scholar
Sun, S., Murray, C.B., Weller, D., Folks, L., and Moser, A.: Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices. Science 287, 1989 (2000).CrossRefGoogle ScholarPubMed
He, M., Protesescu, L., Caputo, R., Krumeich, F., and Kovalenko, M.V.: A general synthesis strategy for monodisperse metallic and metalloid nanoparticles (In, Ga, Bi, Sb, Zn, Cu, Sn, and their alloys) via in situ formed metal long-chain amides. Chem. Mater. 27, 635 (2015).CrossRefGoogle Scholar
Wang, Y., Zhao, H., and Zhao, G.: Iron–copper bimetallic nanoparticles embedded within ordered mesoporous carbon as effective and stable heterogeneous Fenton catalyst for the degradation of organic contaminants. Appl. Catal., B 164, 396–406 (2015).CrossRefGoogle Scholar
Kim, D., Resasco, J., Yu, Y., Asiri, A.M., and Yang, P.: Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles. Nat. Commun. 5 (2014).CrossRefGoogle ScholarPubMed
Chowdhury, S., Bhethanabotla, V.R., and Sen, R.: Effect of Ag–Cu alloy nanoparticle composition on luminescence enhancement/quenching. J. Phys. Chem. C 113, 13016 (2009).CrossRefGoogle Scholar
Huang, X., Li, Y., Zhou, H., Zhong, X., Duan, X., and Huang, Y.: Simplifying the creation of dumbbell‐like Cu–Ag nanostructures and their enhanced catalytic activity. Chem. - Eur. J. 18, 9505 (2012).CrossRefGoogle ScholarPubMed
Li, Y.S., Lu, Y.C., Chou, K.S., and Liu, F.J.: Synthesis and characterization of silver–copper colloidal ink and its performance against electrical migration. Mater. Res. Bull. 45, 1837 (2010).CrossRefGoogle Scholar
Hau-Riege, C.S.: An introduction to Cu electromigration. Microelectron. Reliab. 44, 195 (2004).CrossRefGoogle Scholar
Vogel, R.H.: Electromigration and the structure of metallic nanocontacts. Appl. Phys. Rev. 4, 031302 (2017).CrossRefGoogle Scholar
Bhagat, S., Theodore, N.D., Chenna, S., and Alford, T.: Effect of copper addition on electromigration behavior of silver metallization. Appl. Phys. Express 2, 096502 (2009).CrossRefGoogle Scholar
Dou, Q.Q. and Ng, K.M.: Synthesis of various metal stearates and the corresponding monodisperse metal oxide nanoparticles. Powder Technol. 301, 949 (2016).CrossRefGoogle Scholar
Dou, Q.Q., Wong, K.W., Li, Y., and Ng, K.M.: Novel nanosheets of ferrite nanoparticle arrays in cabon matrix from single source precursors: An anode materials for lithium-ion batteries. J. Mater. Sci. 53, 4456 (2018).CrossRefGoogle Scholar
Wu, S.H. and Chen, D.H.: Synthesis of high-concentration Cu nanoparticles in aqueous CTAB solutions. J. Colloid Interface Sci. 273, 165 (2004).CrossRefGoogle ScholarPubMed
Qiu, S., Dong, J., and Chen, G.: Preparation of Cu nanoparticle from water-in-oil microemulsions. J. Colloid Interface Sci. 216, 230 (1999).CrossRefGoogle ScholarPubMed
Zhu, H.T., Zhang, C.Y., and Yin, Y.S.: Rapid synthesis of copper nanoparticles by sodium hypophosphite reduction in ethylene glycol under microwave irradation. J. Cryst. Growth 270, 722 (2004).CrossRefGoogle Scholar
Sopousek, J., Krystofova, A., Premovic, M., Zobac, O., Polsterova, S., Broz, P., and Bursik, J.: Au–Ni nanoparticles: Phase diagram prediction, synthesis, characterization, and thermal stability. Calphad 58, 25 (2017).CrossRefGoogle Scholar
Weng, W.L., Hsu, C.Y., Lee, J.S., Fan, H.H., and Liao, C.N.: Twin-mediated epitaxial growth of highly lattice-mismatched Cu/Ag core–shell nanowires. Nanoscale 10, 9862 (2018).CrossRefGoogle ScholarPubMed
Qu, S., Zhang, P., Wu, S.D., Zang, Q.S., and Zhang, Z.F.: Twin boundaries: Strong or weak? Scr. Mater. 59, 1131 (2008).CrossRefGoogle Scholar
Zhong, K., Peabody, G., Blankenhorn, E., Glicksman, H., and Ehrman, S.A.: Spray pyrolysis approach for the generation of patchy particles. Aerosol Sci. Technol. 47, i–v (2013).CrossRefGoogle Scholar
Park, J., Joo, J., Kwon, S.G., Jang, Y., and Hyeon, T.: Synthesis of monodisperse spherical nanocrystals. Angew. Chem., Int. Ed. 46, 4630 (2007).CrossRefGoogle ScholarPubMed
Embden van, J., Chesman, A.S.R., and Jasieniak, J.J.: The heat-up synthesis of colloidal nanocrystals. Chem. Mater. 27, 2246 (2015).CrossRefGoogle Scholar
Fievet, F., Lagier, J., and Figlarz, M.: Preparing monodisperse metal powders in micrometer and submicrometer sizes by the polyol process. MRS Bull. 14, 29 (1989).CrossRefGoogle Scholar
Lahtonen, K., Hirsimäki, M., Lampimäki, M., and Valden, M.: Oxygen adsorption-induced nanostructures and island formation on Cu{100}: Bridging the gap between the formation of surface confined oxygen chemisorption layer and oxide formation. J. Chem. Phys. 129, 124703 (2008).CrossRefGoogle ScholarPubMed
Abrikosov, I., Olovsson, W., and Johansson, B.: Valence-band hybridization and core level shifts in random Ag–Pd alloys. Phys. Rev. Lett. 87, 176403 (2001).CrossRefGoogle ScholarPubMed
Supplementary material: File

Dou et al. supplementary material

Figures S1-S7

Download Dou et al. supplementary material(File)
File 8.6 MB