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A non-local description of advection-diffusion with application to dispersion in porous media

Published online by Cambridge University Press:  21 April 2006

Donald L. Koch
Affiliation:
Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA Present address: School of Chemical Engineering, Cornell University, Ithaca, NY 14853, USA.
John F. Brady
Affiliation:
Chemical Engineering, California Institute of Technology, Pasadena, CA 91125, USA

Abstract

When the lengthscales and timescales on which a transport process occur are not much larger than the scales of variations in the velocity field experienced by a tracer particle, a description of the transport in terms of a local, averaged macroscale version of Fick's law is not applicable. Here, a non-local transport theory is developed in which the average mass flux is not simply proportional to the average local concentration gradient, but is given by a convolution integral over space and time of the average concentration gradient times a spatial- and temporal-wavelength-dependent diffusivity. The non-local theory is applied to the transport of a passive tracer in the advective field that arises in the bulk fluid of a porous medium, and the complete residence-time distribution - space-time response to a unit source input - of the tracer is determined. It is also shown how the method of moments may be simply recovered as a special case of the non-local theory. While developed in the context of and applied to tracer dispersion in porous media, the non-local theory presented here is applicable to the general problem of determining the average transport behaviour in advection-diffusion-type systems in which spatial and temporal variations are occurring on scales comparable with the scale of interest.

Type
Research Article
Copyright
© 1987 Cambridge University Press

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References

Acrivos, A., Hinch, E. J. & Jeffrey, D. J. 1980 Heat transfer to a slowly moving fluid from a dilute bed of heated spheres. J. Fluid Mech. 101, 403421.Google Scholar
Beran, M. J. & McCoy, J. J. 1970 Mean field variation in random media. Q. Appl. Maths 28, 245258.Google Scholar
Chatwin, P. C. 1970 The approach to normality of the concentration distribution of a solute in a solvent flowing along a straight pipe. J. Fluid Mech. 43, 321352.Google Scholar
Frisch, U. 1968 Probabilistic Methods in Applied Mathematics (ed. A. T. Bharucha-Reid). Academic.
Gill, W. N. & Sankarasubramanian, R. 1970 Exact analysis of unsteady convective diffusion. Proc. R. Soc. Lond. A 316, 341350.Google Scholar
Hinch, E. J. 1977 An averaged-equation approach to particle interactions in a fluid suspension. J. Fluid Mech. 83, 695720.Google Scholar
Jackson, J. D. 1975 Classical Electrodynamics (2nd edn), chapter 7. John Wiley.
Keller, J. B. 1962 Wave propagation in random media. Proc. Symp. Appl. Maths, vol. 13, pp. 227246.
Keller, J. B. 1977 Effective behavior of heterogeneous media. Statistical Mechanics and Statistical Methods in Theory and Applications (ed. U. Landman), pp. 631644. Plenum.
Koch, D. L. 1986 Dispersion in heterogeneous media. Ph.D. thesis, Massachusetts Institute of Technology.
Koch, D. L. & Brady, J. F. 1985 Dispersion in fixed beds. J. Fluid Mech. 154, 399427.Google Scholar
Koch, D. L. & Brady, J. F. 1987a Nonlocal dispersion in porous media: nonmechanical effects. Chem. Eng. Sci. (to appear).
Koch, D. L. & Brady, J. F. 1987b Anomalous diffusion in heterogeneous porous media. Phys. Fluids. (submitted).
Koch, D. L. & Brady, J. F. 1987c On the symmetry properties of the effective diffusivity tensor in anisotropic porous media. Phys. Fluids 30, 642650.Google Scholar
Landau, L. D., Lifshitz, E. M. & Pitaevskií, L. P. 1984 Electrodynamics of Continuous Media, p. 358. Pergamon.
Mcquarrie, D. A. 1976 Statistical Mechanics, chapters 21–22. Harper & Row.
Pagitsas, M., Nadim, A. & Brenner, H. 1986 A multiple time scale analysis of macrotransport processes. Physica 135A, 533–550.Google Scholar
Reis, J. F. G., Lightfoot, E. N., Noble, P. T. & Chiang, A. S. 1979 Chromatography in a bed of spheres. Sep. Sci. Tech. 14, 367394.Google Scholar
Smith, R. 1981 A delay-diffusion description for contaminant dispersion. J. Fluid Mech. 105, 469486.Google Scholar