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Removal of Co2+, Ni2+, and Pb2+ by Manganese Oxide-Coated Zeolite: Equilibrium, Thermodynamics, and Kinetics Studies

Published online by Cambridge University Press:  01 January 2024

Mehdi Irannajad  and
Hossein Kamran Haghighi
Mehdi Irannajad*
Affiliation:
Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran
Hossein Kamran Haghighi
Affiliation:
Department of Mining and Metallurgical Engineering, Amirkabir University of Technology, Tehran, Iran
*
*E-mail address of corresponding author: [email protected]
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Abstract

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The removal of Co2+, Ni2+, and Pb2+ from aqueous solutions using a modified zeolite was investigated because of the need to eliminate toxic contaminants from wastewaters. In the present study the ways in which equilibrium, thermodynamics, and kinetics parameters affected the removal of heavy metals were evaluated and compared. An Iranian clinoptilolite with a Si/Al ratio of 6.5 was used as an adsorbent. In order to increase the adsorption capacity of the adsorbent, it was converted to a manganese oxide-coated zeolite (MOCZeo) using various Mn solutions. The initial concentration of metals, pH, contact time, and temperature were the variables studied and optimal conditions were established. The maximum amount of Co2+, Ni2+, AND Pb2+ adsorption on MOCZeo was ascertained. A thermodynamics study, using ΔG, ΔH, and ΔS state functions showed that adsorption of Pb2+ was more spontaneous than that of Co2+, Ni2+ ions. The adsorption of these ions on MOCZeo was an endothermic reaction. Investigation of the adsorption models revealed that the adsorption of Pb2+, Co2+, and Ni2+ on MOCZeo followed both the Langmuir and Freundlich models. Kinetics studies showed that the adsorption of Pb2+, Co2+, and Ni2+ on MOCZeo followed the pseudo-second order kinetics model with a high correlation coefficient.

Keywords

Ion-exchange AdsorptionManganese OxideWastewaterZeolite Kinetics and Thermodynamics
Type
Article
Information
Clays and Clay Minerals , Volume 65 , Issue 1 , February 2017 , pp. 52 - 62
Copyright
Copyright © Clay Minerals Society 2017

References

Al-Degs, Y.S. Tutunju, M.F. and Shawabkeh, R.A., 2000 The feasibility of using diatomite and Mn-diatomite for remediation of Pb2+, Cu2+, and Cd2+ from water Separation Science and Technology 35 2299–2310.CrossRefGoogle Scholar
Ahmadpour, A. Tahmasbi, M. Bastami, T.R. and Besharati, J.A., 2009 Rapid removal of cobalt ion from aqueous solutions by almond green hull Journal of Hazardous Materials 166 925–930.CrossRefGoogle ScholarPubMed
Aklil, A. Mouflih, M. and Sebti, S., 2004 Removal of heavy metal ions from water by using calcined phosphate as a new adsorbent Journal of Hazardous Materials 112 183–190.CrossRefGoogle ScholarPubMed
Alver, E. and Metin, A., 2012 Anionic dye removal from aqueous solutions using modified zeolite: Adsorption kinetics and isotherm studies Chemical Engineering Journal 200 59–67.CrossRefGoogle Scholar
Arshadi, M A ^MJ ^S, 2014 Kinetic, equilibrium and thermodynamic investigations of Ni(II), Cd(II), Cu(II) and Co(II) adsorption on barley straw ash Water Resources and Industry 6 1–17.CrossRefGoogle Scholar
van Asokbunyarat, V. Hullebusch, E.D. Lens, P.N. and Annachhatre, A.P., 2015 Adsorption of heavy metals from acid mine drainage by coal bottom ash Proceedings of the 4th International Conference on Research Frontiers in Chalcogen Cycle Science and Technology 29.Google Scholar
Azari, A. Kakavandi, B. Kalantary, R.R. Ahmadi, E. Gholami, M. Torkshavand, Z. and Azizi, M., 2015 Rapid and efficient magnetically removal of heavy metals by magnetite-activated carbon composite: A statistical design approach Journal of Porous Materials 22 1083–1096.CrossRefGoogle Scholar
Babel, S. and Kurniawan, T.A., 2003 Low-cost adsorbents for heavy metals uptake from contaminated water: A review Journal of Hazardous Materials 97 219–243.CrossRefGoogle ScholarPubMed
Barakat, M.A., 2011 New trends in removing heavy metals from industrial wastewater Arabian Journal of Chemistry 4 361–377.CrossRefGoogle Scholar
Bhatnagar, A. Minocha, A.K. and Sillanpää, M., 2010 Adsorptive removal of cobalt from aqueous solution by utilizing lemon peel as biosorbent Biochemical Engineering Journal 48 181–186.CrossRefGoogle Scholar
Bhattacharyya, R. and Ray, S.K., 2015 Removal of congo red and methyl violet from water using nano clay filled composite hydrogels of poly acrylic acid and polyethylene glycol Chemical Engineering Journal 260 269–283.CrossRefGoogle Scholar
Biškup, B. and Subotić, B., 2004 Kinetic analysis of the exchange processes between sodium ions from zeolite a and cadmium, copper and nickel ions from solutions Separation and Purification Technology 37 17–31.CrossRefGoogle Scholar
Boujelben, N. Bouzid, J. and Elouear, Z., 2009 Adsorption of nickel and copper onto natural iron oxide-coated sand from aqueous solutions: Study in single and binary systems Journal of Hazardous Materials 163 376–382.CrossRefGoogle ScholarPubMed
Chantawong, V. Harvey, N.W. and Bashkin, V.N., 2004 Comparison of heavy metal adsorptions by Thai kaolin and ballclay Water, Air, and Soil Pollution 148 111–125.CrossRefGoogle Scholar
Çoruh, S., 2008 The removal of zinc ions by natural and conditioned clinoptilolites Desalination 225 41–57.CrossRefGoogle Scholar
Doula, M.K., 2006 Removal of Mn2+ ions from drinking water by using clinoptilolite and a clinoptilolite-Fe oxide system Water Research 40 3167–3176.CrossRefGoogle Scholar
El-Kamash, A.M., 2008 Evaluation of zeolite A for the sorptive removal of Cs+ and Sr2+ ions from aqueous solutions using batch and fixed bed column operations Journal of Hazardous Materials 151 432–445.CrossRefGoogle ScholarPubMed
Erto, A. Giraldo, L. Lancia, A. and Moreno-Pirajá, J.C., 2013 A comparison between a low-cost sorbent and an activated carbon for the adsorption of heavy metals from water Water, Air, Soil Pollution 224 1–10.CrossRefGoogle Scholar
Farghali, A.A. Bahgat, M. Enai,et, a. l. A, Khedr, M.H. et al. , 2013 Adsorption of Pb(II) ions from aqueous solutions using copper oxide nanostructures Beni-Suef University Journal of Basic and Applied Sciences 2 61–71.CrossRefGoogle Scholar
Freundlich, H., 1906 Over the adsorption in solution Journal of Physical Chemistry 57 e470.Google Scholar
Fröhlich, D.R., 2015 Sorption of neptunium on clays and clay minerals - a review Clays and Clay Minerals 63 262–276.CrossRefGoogle Scholar
Ghorbel-Abid, I. and Trabelsi-Ayadi, M., 2015 Competitive adsorption of heavy metals on local landfill clay Arabian Journal of Chemistry 8 25–31.CrossRefGoogle Scholar
Gonzalez, M.R. Pereyra, A.M. Zerbino, R. and Basaldella, E.I., 2015 Removal and cementitious immobilization of heavy metals: Chromium capture by zeolite-hybridized materials obtained from spent fluid cracking catalysts Journal of Cleaner Production 91 187–190.CrossRefGoogle Scholar
Guo, N. Wang, J.-S. Li, J. Teng, Y.-G. and Zhai, Y.-Z., 2014 Dynamic adsorption of Cd2+ onto acid-modified attapulgite from aqueous solution Clays and Clay Minerals 62 415–424.CrossRefGoogle Scholar
Gupta, N. Kushwaha, A.K. and Chattopadhyaya, M.C., 2012 Adsorptive removal of Pb2+, Co2+ and Ni2+ by hydroxyapatite/ chitosan composite from aqueous solution Journal of the Taiwan Institute of Chemical Engineers 43 125–131.Google Scholar
Han, R. Zou, W. Li, H. Li, Y. and Shi, J., 2006 Copper(II) and lead(II) removal from aqueous solution in fixed-bed columns by manganese oxide coated zeolite Journal of Hazardous Materials 137 934–942.CrossRefGoogle ScholarPubMed
Han, R. Zou, W. Wang, Y. and Zhu, L., 2007 Removal of uranium(VI) from aqueous solutions by manganese oxide coated zeolite: Discussion of adsorption isotherms and ph effect Journal of Environmental Radioactivity 93 127–143.CrossRefGoogle ScholarPubMed
Hashemian, S. Saffari, H. and Ragabion, S., 2014 Adsorption of cobalt(II) from aqueous solutions by Fe3O4/ bentonite nanocomposite Water, Air, & Soil Pollution 226 2212.CrossRefGoogle Scholar
Ho, Y.-S. and McKay, G., 1998 Sorption of dye from aqueous solution by peat Chemical Engineering Journal 70 115–124.CrossRefGoogle Scholar
Hu, J. Chen, G. and Lo, I.M., 2006 Selective removal of heavy metals from industrial wastewater using maghemite nanoparticle: Performance and mechanisms Journal of Environmental Engineering 132 7 (709).CrossRefGoogle Scholar
Hui, K.S. Chao, C.Y.H. and Kot, S.C., 2005 Removal of mixed heavy metal ions in wastewater by zeolite 4a and residual products from recycled coal fly ash Journal of Hazardous Materials 127 89–101.CrossRefGoogle ScholarPubMed
Inglezakis, V.J. Loizidou, M.D. and Grigoropoulou, H.P., 2002 Equilibrium and kinetic ion exchange studies of Pb2+, Cr3+, Fe3+ and Cu2+ on natural clinoptilolite Water Research 36 2784–2792.CrossRefGoogle ScholarPubMed
Inglezakis, V.J. Stylianou, M.A. Gkantzou, D. and Loizidou, M.D., 2007 Removal of Pb(II) from aqueous solutions by using clinoptilolite and bentonite as adsorbents Desalination 210 248–256.CrossRefGoogle Scholar
Irannajad, M. Kamran Haghighi, H. and Safarzadeh, E., 2015 Development of kinetic and equilibrium models for removal of Cd2+ and Zn2+ ions from aqueous solutions by clinoptilolite Environmental Progress & Sustainable Energy 35 633–641.CrossRefGoogle Scholar
Irannajad, M} Kamran Haghighi, H. and Mohammadjafari, A., 2016a Heavy metals adsorption by nanozeolites: Effect of sodium hexametaphosphate Environmental Earth Sciences 75 1–7.CrossRefGoogle Scholar
Irannajad, M. Kamran Haghighi, H. and Mohammadjafari, A., 2016b Kinetic, thermodynamic and equilibrium studies on the removal of copper ions from aqueous solutions by natural and modified clinoptilolites Korean Journal of Chemical Engineering 1–11.CrossRefGoogle Scholar
Irannajad, M. Kamran Haghighi, H. and Soleimanipour, M., 2016c Adsorption of Zn2+, Cd2+ and Cu2+ on zeolites coated by manganese and iron oxides Physicochemical Problems of Mineral Processing 52 894–908.Google Scholar
Ismadji, S. Soetaredjo, F.E. and Ayucitra, A., 2015 Clay Materials for Environmental Remediation Berlin Springer.CrossRefGoogle Scholar
Jiménez-Cedillo, M.J. Olguín, M.T. Fall, C. and Colín, A., 2011 Adsorption capacity of iron- or iron-manganesemodified zeolite-rich tuffs for As(III) and As(V) water pollutants Applied Clay Science 54 206–216.CrossRefGoogle Scholar
Kalantari, K. Ahmad, M.B. Masoumi, H.R.F. Shameli, K. Basri, M. and Khandanlou, R., 2015 Rapid and high capacity adsorption of heavy metals by Fe3O4/montmorillonite nanocomposite using response surface methodology: Preparation, characterization, optimization, equilibrium isotherms, and adsorption kinetics study Journal of the Taiwan Institute of Chemical Engineers 49 192–198.CrossRefGoogle Scholar
Karnib, M. Kabbani, A. Holail, H. and Olama, Z., 2014 Heavy metals removal using activated carbon, silica and silica activated carbon composite Energy Procedia 50 113–120.CrossRefGoogle Scholar
Kocaoba, S. Orhan, Y. and Akyüz, T., 2007 Kinetics and equilibrium studies of heavy metal ions removal by use of natural zeolite Desalination 214 1–10.CrossRefGoogle Scholar
Kushwaha, A.K. Gupta, N. and Chattopadhyaya, M., 2017 Adsorption behavior of lead onto a new class of functionalized silica gel Arabian Journal of Chemistry S81–S89.CrossRefGoogle Scholar
Langmuir, I., 1916 The constitution and fundamental properties of solids and liquids Part I. Solids. Journal of the American Chemical Society 38 2221–2295.CrossRefGoogle Scholar
Lazarevic, S. Jankovic-Castvan, I. Djokic, V. Radovanovic, Z. Janackovic, D. and Petrovic, R., 2010 Iron-modified sepiolite for Ni2+ sorption from aqueous solution: An equilibrium, kinetic, and thermodynamic study Journal of Chemical & Engineering Data 55 5681–5689.CrossRefGoogle Scholar
Li, Z. Teng, T.T. Alkarkhi, A.F.M. Rafatullah, M. and Low, L.W., 2013 Chemical modification of imperata cylindrica leaf powder for heavy metal ion adsorption Water, Air, & Soil Pollution 224 1–14.CrossRefGoogle Scholar
Lu, A. Zhang, S. and Shan, X.-Q., 2005 Time effect on the fractionation of heavy metals in soils Geoderma 125 225–234.CrossRefGoogle Scholar
Lu, C. Yu, S. Yao, T. Zeng, C. Wang, C. and Zhang, L., 2015 Zeolite X/chitosan hybrid microspheres and their adsorption properties for Cu(II) ions in aqueous solutions Journal of Porous Materials 22 1255–1263.CrossRefGoogle Scholar
Mahmoud, D.K. Salleh, M.A.M. Karim, WAWA Idris, A. and Abidin, Z.Z., 2012 Batch adsorption of basic dye using acid treated kenaf fibre char: Equilibrium, kinetic and thermodynamic studies Chemical Engineering Journal 181 449–457.CrossRefGoogle Scholar
Mallampati, R. Xuanjun, L. Adin, A. and Valiyaveettil, S., 2015 Fruit peels as efficient renewable adsorbents for removal of dissolved heavy metals and dyes from water ACS Sustainable Chemistry & Engineering 3 1117–1124.CrossRefGoogle Scholar
Mehdizadeh, S. Sadjadi, S. Ahmadi, S. and Outokesh, M., 2014 Removal of heavy metals from aqueous solution using platinum nanopartcles/zeolite-4A Journal of Environmental Health Science and Engineering 12 1–7.CrossRefGoogle ScholarPubMed
Merrikhpour, H. and Jalali, M., 2013 Comparative and competitive adsorption of cadmium, copper, nickel, and lead ions by iranian natural zeolite Clean Technologies and Environmental Policy 15 303–316.CrossRefGoogle Scholar
Milićević, S. Milošević, V. Povrenović, D. Stojanović, J. Martinović, S. and Babić, B., 2013 Removal of heavy metals from aqueous solution using natural and Fe(III) oxyhydroxide clinoptilolite Clays and Clay Minerals 61 508–516.CrossRefGoogle Scholar
Moattar, F. and Hayeripour, S., 2004 Application of chitin and zeolite adsorbents for treatment of low level radioactive liquid wastes International Journal of Environmental Science & Technology 1 45–50.CrossRefGoogle Scholar
Mohapatra, M. Mohapatra, L. Singh, P. Anand, S. and Mishra, B., 2010 A comparative study on Pb(II), Cd(II), Cu(II), Co(II) adsorption from single and binary aqueous solutions on additive assisted nano-structured goethite International Journal of Engineering, Science and Techlogy, 2, 89–103.Google Scholar
Mouflih, M. Aklil, A. and Sebti, S., 2005 Removal of lead from aqueous solutions by activated phosphate Journal of Hazardous Materials 119 183–188.CrossRefGoogle ScholarPubMed
Nouh, E.S.A. Amin, M. Gouda, M. and Abd-Elmagid, A., 2015 Extraction of uranium(VI) from sulfate leach liquor after iron removal using manganese oxide coated zeolite Journal of Environmental Chemical Engineering 3 523–528.CrossRefGoogle Scholar
Ören, A.H. and Kaya, A., 2006 Factors affecting adsorption characteristics of Zn2+ on two natural zeolites Journal of Hazardous Materials 131 59–65.CrossRefGoogle ScholarPubMed
Ouki, S.K. and Kavannagh, M., 1997 Performance of natural zeolites for the treatment of mixed metal-contaminated effluents Waste Management & Research 15 383–394.CrossRefGoogle Scholar
Park, S.-J. Kim, Y.-M. and Shin, J.-S., 2005 Cu(II) adsorption of activated carbon fibers produced by radiation- induced graft polymerization Journal of Porous Materials 12 41–46.CrossRefGoogle Scholar
Poots, V. McKay, G. and Healy, J., 1978 Removal of basic dye from effluent using wood as an adsorbent Journal (Water Pollution Control Federation) 926–935.Google Scholar
Rahmani, A. Mahvi, A. Mesdaghinia, A. and Nasseri, S., 2004 Investigation of ammonia removal from polluted waters by clinoptilolite zeolite International Journal of Environmental Science & Technology 1 125–133.CrossRefGoogle Scholar
Ricordel, S. Taha, S. Cisse, I. and Dorange, G., 2001 Heavy metals removal by adsorption onto peanut husks carbon: Characterization, kinetic study and modeling Separation and Purification Technology 24 389–401.CrossRefGoogle Scholar
Shannon, R.D., 1976 Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Acta Crystallographica Section A: Crystal Physics Diffraction Theoretical and General Crystallography, 32, 751–767.CrossRefGoogle Scholar
Şőlener, M. Tunali, S. Özcan, A.S. Özcan, A. and Gedikbey, T., 2008 Adsorption characteristics of lead (II) ions onto the clay/poly (methoxyethyl) acrylamide (pmea) composite from aqueous solutions Desalination 223 308–322.CrossRefGoogle Scholar
Srivastava, V.C. Swamy, M.M. Mall, I.D. Prasad, B. and Mishra, I.M., 2006 Adsorptive removal of phenol by bagasse fly ash and activated carbon: Equilibrium, kinetics and thermodynamics Colloids and Surfaces A: Physicochemical and Engineering Aspects 272 89–104.CrossRefGoogle Scholar
Taffarel, S.R. and Rubio, J., 2010 Removal of Mn2+ from aqueous solution by manganese oxide coated zeolite Minerals Engineering 23 1131–1138.CrossRefGoogle Scholar
Tahir, S.S. and Rauf, N., 2003 Thermodynamic studies of Ni(II) adsorption onto bentonite from aqueous solution The Journal of Chemical Thermodynamics 35 2003–2009.CrossRefGoogle Scholar
Treybal, R.E. and Treybal Robert, E., 1968 Mass-transfer Operations New York McGraw-Hill.Google Scholar
Turtureanu, A. Georgescu, C. and Oprean, L., 2008 Nickel removal from aqueous solutions by flotation with cationic collector Determination of the optimum separation conditions. Chemical Bulletin “POLITEHNICA” Univ. (Timişoara) 53 286–288.Google Scholar
Tzvetkova, P. Vassileva, P. and Nickolov, R., 2009 Modified silica gel with 5-amino-1,3,4-thiadiazole-2-thiol for heavy metal ions removal Journal of Porous Materials 17 459–463.CrossRefGoogle Scholar
Violante, A. Ricciardella, M. and Pigna, M., 2003 Adsorption of heavy metals on mixed Fe-Al oxides in the absence or presence of organic ligands Water, Air, and Soil Pollution, 145, 289–306.CrossRefGoogle Scholar
Wingenfelder, U. Nowack, B. Furrer, G. and Schulin, R., 2005 Adsorption of Pb and Cd by amine-modified zeolite Water Research 39 3287–3297.CrossRefGoogle ScholarPubMed
Wu, H. Hu, L. Zhang, L. and Wen, Q., 2015 Transport and exchange behavior of ions in bentonite during electroosmotic consolidation Clays and Clay Minerals 63 395–403.CrossRefGoogle Scholar
Zhang, M.-K. and Zheng, S.-A., 2007 Competitive adsorption of Cd, Cu, Hg and Pb by agricultural soils of the Changjiang and Zhujiang deltas in China Journal of Zhejiang University Science A 8 1808–1815.CrossRefGoogle Scholar
Zou, W. Han, R. Chen, Z. Jinghua, Z. and Shi, J., 2006a Kinetic study of adsorption of Cu(II) and Pb(II) from aqueous solutions using manganese oxide coated zeolite in batch mode Colloids and Surfaces A: Physicochemical and Engineering Aspects 279 238–246.CrossRefGoogle Scholar
Zou, W. Han, R. Chen, Z. Shi, J. and Liu, H., 2006b Characterization and properties of manganese oxide coated zeolite as adsorbent for removal of copper(II) and lead(II) ions from solution Journal of Chemical & Engineering Data 51 534–541.CrossRefGoogle Scholar
Zou, W. Zhao, L. and Han, R., 2009 Removal of uranium (VI) by fixed bed ion-exchange column using natural zeolite coated with manganese oxide Chinese Journal of Chemical Engineering 17 585–593.CrossRefGoogle Scholar