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A simple approach to the identification of trioctahedral smectites by X-ray diffraction

Published online by Cambridge University Press:  09 July 2018

G. E. Christidis  and
E. Koutsopoulou
G. E. Christidis*
Affiliation:
Technical University of Crete, Department of Mineral Resources Engineering, 73100 Chania, Greece
E. Koutsopoulou
Affiliation:
University of Patras, Department of Geology, 26500 Rio, Patras, Greece
*
*E-mail: [email protected]
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Abstract

A new method for identifying the trioctahedral smectites saponite, stevensite and hectorite is proposed in this study. The method is based on differences in the X-ray diffraction (XRD) patterns of the three smectites after (a) heating at 500°C for 90 min and (b) glycerol solvation of the Cs-forms of the smectites for 20 h. After heating at 500°C, well below the dehydroxylation temperature of the three smectites, saponite and hectorite re-expand upon ethylene glycol (EG) solvation, whereas stevensite layers remain collapsed. Saponite forms one-layer and hectorite two-layer complexes after Cs-saturation and glycerol solvation. Cs-stevensite displays a gradual increase in d001 with increasing solvation time in glycerol vapours and forms two-layer glycerol complexes with prolonged solvation. Except for the individual Mg-smectites, the proposed method may be used to identify compositional heterogeneity that may exist in the smectites. Furthermore, it should be useful in identifying the individual trioctahedral Mg-smectites when present in mixtures, and in detecting interstratified layers of different Mg-trioctahedral smectites. Application of the method revealed that the SYnL-1 laponite (CMS Source Clay Project) is not homogeneous but consists of hectorite, stevensite and possibly mixed-layer hectorite/stevensite layers.

Keywords

saponitestevensitehectoritemixed-layer hectorite/stevensiteXRDidentificationheatingCs-saturationglycerol solvation
Type
Research Article
Information
Clay Minerals , Volume 48 , Issue 5 , December 2013 , pp. 687 - 696
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2013

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References

Aggarwal, V., Li, H. & Teppen, B.J. (2006) Triazine adsorption by saponite and beidellite clay minerals. Environmental Toxicology and Chemistry, 25, 392–399.Google Scholar
Alberti, A. & Brigatti, M.F. (1985) Crystal chemical differences in Al-rich smectites as shown by multivariate analysis of variance and discriminant analysis. Clays and Clay Minerals, 33, 546–558.Google Scholar
Benhammou, A., Tanouti, B., Nibou, L., Yaacoubi, A. & Bonnet, J.-P. (2009) Mineralogical and physicochemical investigation of Mg-smectite from Jbel Ghassoul, Morocco. Clays and Clay Minerals, 57, 264–270.Google Scholar
Brigatti, M.F. & Poppi, L. (1981) A mathematical model to distinguish the members of the dioctahedral smectite series. Clay Minerals, 16, 81–89.Google Scholar
Brindley, G.W. (1966) Ethylene glycol and glycerol complexes of smectites and vermiculites. Clay Minerals, 6, 237–259.CrossRefGoogle Scholar
Brindley, G.W. (1984) Order-disorder in clay mineral structures. Pp. 125–196 in: Crystal Structures of Clay Minerals and their X-ray Identification (G.W. Brindley & G. Brown, editors). Monograph 5, Mineralogical Society, London.Google Scholar
Brindley, G.W., Bish, D.L. & Wan, H-M. (1977) The nature of kerolite; its relation to talc and stevensite. Mineralogical Magazine, 41, 443–452.Google Scholar
Christidis, G.E. (2004) A new method for determination of layer charge and charge distribution of smectites. International workshop “Current knowledge on the layer charge of clay minerals”, September 18–19, Smolenice Castle, Slovakia, 12 pp.Google Scholar
Christidis, G.E. (2006) Genesis and compositional heterogeneity of smectites. Part III. Alteration of basic pyroclastic rocks. A case study from the Troodos Ophiolite Complex, Cyprus. American Mineralogist, 91, 685–701.Google Scholar
Christidis, G.E. (2011) Industrial Clays. Pp. 341–414 in: Advances in the Characterization of Industrial Minerals (G.E. Christidis editor). EMU Notes in Mineralogy, 9, European Mineralogical Union, Mineralogical Society of Great Britain and Ireland.Google Scholar
Christidis, G. & Dunham, A.C. (1993) Compositional variations in smectites derived from intermediate volcanic rocks. A case study from Milos Island, Greece. Clay Minerals, 28, 255–273.Google Scholar
Christidis, G. & Dunham, A.C. (1997) Compositional variations in smectites. Part II: Alteration of acidic precursors. A case study from Milos Island, Greece. Clay Minerals, 32, 255–273.Google Scholar
Christidis, G.E. & Eberl, D.D. (2003) Determination of layer charge of smectites. Clays and Clay Minerals, 51, 644–655.Google Scholar
Christidis, G.E. & Mitsis, I. (2006) A new Ni-rich stevensite from the ophiolite complex of Othrys, central Greece. Clays and Clay Minerals, 54, 653–666.Google Scholar
Cuevas, J., de la Villa, R.V., Ramirez, S, Petit, S., Meunier, A. & Leguey, S. (2003) Chemistry of Mg smectites in lacustrine sediments from the Vicalvaro sepiolite deposit, Madrid, Neogene Basin (Spain). Clays and Clay Minerals, 51, 457–472.CrossRefGoogle Scholar
Decarreau, A., Colin, F., Herbillon, A., Manceau, A., Nahon, D., Paquet, H., Trauth-Badeaud, D. & Trescases, J.J. (1987) Domain segregation in Ni-Fe- Mg-smectites. Clays and Clay Minerals 35, 1–10.CrossRefGoogle Scholar
Drits, V.A., Lindgreen, H., Salyn, A.L., Ylagan, R. & McCarty, D.K. (1998) Semi quantitative determination of trans-vacant and cis-vacant 2:1 layers in illites and illite-smectites by thermal analysis and Xray diffraction. American Mineralogist, 83, 1188–1198.CrossRefGoogle Scholar
Elton, N.J., Hooper, J.J. & Holyer, V.A.D. (1997) An occurrence of stevensite and kerolite in the Devonian Crousa gabbro at Dean Quarry, The Lizard, Cornwall, England. Clay Minerals, 32, 241–25.Google Scholar
Goodman, B.A., Nadeau, P.H. & Chadwick, J. (1988) Evidence for the multiphase nature of bentonites from Mossbauer and EPR spectroscopy. Clay Minerals 23, 147–159.CrossRefGoogle Scholar
Greene-Kelly, R. (1953) The identification of montmorillonoids in clays. Journal of Soil Science, 4, 233–237.Google Scholar
Grim, R.E. & Kulbicki, G. (1961) Montmorillonite: Hightemperature reactions and classification. American Mineralogist, 46, 1329–1369.Google Scholar
Guggenheim, S. & Koster van Groos, A.F. (2001). Baseline studies of the Clay Minerals Society Source YS: Thermal Analysis. Clays and Clay Minerals 49, 433–443.Google Scholar
Güven, N. (1988) Smectite. Pp 497–559 in: Hydrous Phyllosilicates (Bailey, S.W., editor). Reviews in Mineralogy, 19. Mineralogical Society of America.Google Scholar
Iwasaki, T. & Watanabe, T. (1988) Distribution of Ca and Na ions in dioctahedral smectites and interstratified dioctahedral mica/smectites. Clays and Clay Minerals. 36, 73–82.Google Scholar
Jones, B.F. & Weir, A.H. (1983) Clay minerals of Lake Albert, an alkaline, saline lake. Clays and Clay Minerals, 31, 161–172.Google Scholar
Lagaly, G. (1994) Layer charge determination by alkylammonium ions. Pp. 2–46 in: Layer charge characteristics of 2:1 silicate clay minerals (Mermut, A.R., editor). CMS Workshop lectures, 6. The Clay Minerals Society, Boulder Colorado, USA.Google Scholar
Lagaly, G. & Weiss, A. (1975) The layer charge of smectitic layer silicates. Proceedings International Clay Conference Mexico, 157–172.Google Scholar
Leguey, S., Martin-Rubi, J.A., Casas, J., Marta, J., Cuevas, J., Alvarez, A. & Medina, J.A. (1995) Diagenetic evolution and mineral fabric in sepiolitic materials from the Vicalvaro deposit (Madrid Basin). Pp. 383–392 in: Clays Controlling the Environment (Churchman, G.J., Fitzpatrick, R.W. & Eggleton, R.A., editors). Proceedings of the 10th International Clay Conference, Adelaide, Australia, 1993. CSIRO Publishing, Melbourne, Australia.Google Scholar
Lim, C.H. & Jackson, M.L. (1986) Expandable phyllosilicate reactions with lithium on heating. Clays and Clay Minerals, 34, 346–352.Google Scholar
Liu, C., Li, H., Teppen, B.J., Johnston, C.T. & Boyd, S.A. (2009) Mechanisms associated with the high adsorption of dibenzo-p-dioxin from water by smectite clays. Environmental Science and Technology, 43, 2777–2783.Google ScholarPubMed
MacEwan, D.A.C. & Wilson, M.J. (1984) Interlayer and intercalation complexes of clay minerals. Pp 197–248 in: Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. & Brown, G., editors). Monograph 5, Mineralogical Society, London.CrossRefGoogle Scholar
Makri, P. (2001) Determination of Crystallite Thickness in Industrial Clays with X-ray diffraction. Unpublished Diploma Thesis, Technical University of Crete, Greece (in Greek).Google Scholar
Manceau, A., Calas, G. & Decarreau, A. (1985) Nickelbearing clay minerals: I. Optical spectroscopic study of nickel crystal chemistry. Clay Minerals, 20, 367–387.CrossRefGoogle Scholar
Moore, D.M. & Reynolds, R.C. Jr. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. 2nd edition, Oxford University Press, New York.Google Scholar
Newman, A.C.D. & Brown, G. (1987) The chemical constitution of clays. Pp 1–128 in: Chemistry of Clays and Clay Minerals (Newman, A.C.D, editor). Mineralogical Society, London.Google Scholar
Patterson, E. & Swaffield, R. (1987) Thermal Analysis. Pp. 99–132 in: A Handbook of Determinative Methods in Clay Mineralogy (Wilson, M.J., editor). Blackie & Son Limited, Glasgow, UK.Google Scholar
Post, J.L. (1984) Saponite from near Ballarat, California. Clay Minerals, 32, 147–153.Google Scholar
Rana, K., Boyd, S.A., Teppen, B.J., Li, H., Liu, C. & Johnston, C.T. (2009) Probing the microscopic hydrophobicity of smectite surfaces. A vibrational spectroscopic study of dibenzo-p-dioxin sorption to smectite. Physical Chemistry Chemical Physics, 11, 2976–2985.Google Scholar
Reynolds, R.C. Jr. & Reynolds, R.C. III. (1996) Newmod-for-Windows. The calculation of onedimensional X-ray diffraction patterns of mixed layered clay minerals. 8 Brook Road, Hanover, New Hampshire.Google Scholar
Schultz, L.G. (1969) Lithium and potassium adsorption, dehydroxylation temperature and structural water content of aluminous smectites. Clays and Clay Minerals, 17, 115–149.CrossRefGoogle Scholar
Shimoda, S. (1971) Mineralogical studies of a species of stevensite from the Obori Mine, Yamagata prefecture, Japan. Clay Minerals, 9, 185–192.Google Scholar
Stul, M.S. & Mortier, W.J. (1974) The heterogeneity of the charge density in montmorillonites. Clays and Clay Minerals, 22, 391–396.Google Scholar
Suquet, H., de la Calle, C. & Pezerat, H. (1975) Swelling and structural organization of saponite. Clays and Clay Minerals, 23, 1–9.CrossRefGoogle Scholar
Talibudeen, O. & Goulding, K.W.T. (1983) Charge heterogeneity in smectites. Clays and Clay Minerals, 31, 37–42.CrossRefGoogle Scholar
Tettenhorst, R. & Johns, W.D. (1966) Interstratification in montmorillonite. Clays and Clay Minerals, 15, 85–93.Google Scholar
Walker, G.F. (1961) Vermiculite minerals. Pp. 297–324 in: The X-ray Identification and Crystal Structures of Clay Minerals (Brown, G., editor). Mineralogical Society, London.Google Scholar
Wolters, F., Lagaly, G., Kahr, G., Nüesch, R. & Emmerich, K. (2009) A comprehensive characterization of dioctahedral smectites. Clays and Clay Minerals, 57, 115–133.Google Scholar