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On the destruction of kaolinite and gibbsite by phenylphosphonic, phenylphosphinic and phenylarsonic acids: evidence for the formation of new Al compounds

Published online by Cambridge University Press:  09 July 2018

J. E. F. C. Gardolinski ,
G. Lagaly  and
M. Czank
J. E. F. C. Gardolinski*
Affiliation:
Institute of Inorganic Chemistry, University of Kiel, D-24098 Kiel, Germany
G. Lagaly
Affiliation:
Institute of Inorganic Chemistry, University of Kiel, D-24098 Kiel, Germany
M. Czank
Affiliation:
Institute of Geosciences, Department of Mineralogy, University of Kiel, D-24098 Kiel, Germany
*
*E-mail: [email protected]
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Abstract

Kaolinite and synthetic γ-Al(OH)3 (gibbsite or hydrargillite) were reacted with phenylphosphonic, phenylphosphinic and 2-nitrophenol-4-arsonic acids. The products were studied by powder X-ray diffraction, transmission electron microscopy/selected area electron diffraction/ energy dispersive X-ray/Fourier transform infrared and simultaneous thermogravimetric/differential thermal analysis. The acids were not intercalated but, instead, easily destroyed the structure of the minerals. Lamellar Al phenylphosphonate and aluminium phenylphosphinate and phenylarsonate with polymeric linear-chain structures were formed from kaolinite. The reaction between gibbsite and the same acids yielded almost identical products. No evidence of formation of grafted kaolinite derivatives after the reaction with phenylphosphonic acid was found.

Keywords

aluminiumgibbsitegraftingkaolinitephenylarsonatephenylphosphinatephenylphosphonate
Type
Research Article
Information
Clay Minerals , Volume 39 , Issue 4 , December 2004 , pp. 391 - 404
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2004

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