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Montmorillonite catalysts for ethylene hydration

Published online by Cambridge University Press:  09 July 2018

M. P. Atkins ,
D. J. H. Smith  and
D. J. Westlake
M. P. Atkins
Affiliation:
BP Research Centre, Chertsey Road, Sunbury-on-Thames, Middlesex TW16 7LN
D. J. H. Smith
Affiliation:
BP Research Centre, Chertsey Road, Sunbury-on-Thames, Middlesex TW16 7LN
D. J. Westlake
Affiliation:
BP Research Centre, Chertsey Road, Sunbury-on-Thames, Middlesex TW16 7LN
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Abstract

Ion-exchanged montmorillonites behave as solid acid catalysts and are effective and selective catalysts for the hydration of ethylene. The reaction proceeds predominantly in the interlamellar environment of the clay catalyst. Ethylene conversions were found to be markedly dependent on the choice of exchangeable cation, with Al being the best of those examined.

Type
Research Article
Information
Clay Minerals , Volume 18 , Issue 4 , December 1983 , pp. 423 - 429
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1983

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References

Adams, J.M., Clement, D.E. & Graham, S.H. (1983) Synthesis of methyl-t-butyl ether from methane and isobutene using a clay catalyst. Clays Clay Miner. 30, 129–134.Google Scholar
Annabi-Bergaya, F., Cruz, M.I., Gatineau, L. & Fripiat, J.J. (1981) Adsorption of alcohols by smectites: IV. Models. Clay Miner. 16, 115–122.CrossRefGoogle Scholar
Ballantine, J.A., Davies, M.E., Purnell, J.H., Rayanakorn, M., Thomas, J.M. & Williams, K.J. (1981) Chemical conversions using sheet silicates: Facile ester synthesis by direct addition of acids and alkenes. J. C. S. Chem. Comm. 8–9.Google Scholar
Bylina, A., Adams, J.M., Graham, S.H. & Thomas, J.M. (1980) Chemical conversions using sheet silicates: Simple method for producing methyl-t-butyl ether. J. C. S. Chem. Comm. 1003–1004.Google Scholar
Edelman, C.H. & Favejee, J.C.L. (1940) On the crystal structure of montmorillonite and halloysite. Z. Krist. A102, 417–431.Google Scholar
Hofmann, U., Endell, K. & Wilm, D. (1933) Kristalstruktur und Quellung von Montmorillonit. Z. Krist. 86, 340–348.Google Scholar
Thomas, J.M. (1982) Sheet silicate intercalates: New agents for unusual chemical conversions. Pp. 55–99 in: Intercalation Chemistry (Whittingham, M. S. & Jacobson, A. J., editors). Academic Press, New York.CrossRefGoogle Scholar
Trim, D.L. (1983) Catalyst design for reduced coking (Review). App. Catalysis 5, 263–290.Google Scholar