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Poisoning-induced exchange of steady states in a catalytic chemical reactor

Published online by Cambridge University Press:  17 February 2009

D. D. Do  and
R. H. Weiland
D. D. Do
Affiliation:
Department of Chemical Engineering†, University of Queensland, St. Lucia 4067
R. H. Weiland
Affiliation:
Department of Chemical Engineering†, University of Queensland, St. Lucia 4067
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Abstract

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Slow catalyst poisoning can result in the sudden failure of a chemical reactor operating isothermally with substrate-inhibited kinetics. At failure, a satisfactory steady state is exchanged for one of low conversion. The method of matched asymptotic expansions is used to give a detailed description of the exchange process in the phase plane. The structure of the jump is ascertained by separate asymptotic expansions across two adjoining transition regions in which the independent variables contain unknown shifts.

Type
Research Article
Information
The ANZIAM Journal , Volume 22 , Issue 2 , October 1980 , pp. 237 - 253
Copyright
Copyright © Australian Mathematical Society 1980

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