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ART. 146 - On the Relative Densities of Hydrogen and Oxygen. (Preliminary Notice)

Published online by Cambridge University Press:  05 July 2011

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Summary

The appearance of Professor Cooke's important memoir upon the atomic weights of hydrogen and oxygen induces me to communicate to the Royal Society a notice of the results that I have obtained with respect to the relative densities of these gases. My motive for undertaking this investigation, planned in 1882, was the same as that which animated Professor Cooke, namely, the desire to examine whether the relative atomic weights of the two bodies really deviated from the simple ratio 1 : 16, demanded by Prout's Law. For this purpose a knowledge of the densities is not of itself sufficient; but it appeared to me that the other factor involved, viz., the relative atomic volumes of the two gases, could be measured with great accuracy by eudiometric methods, and I was aware that Mr Scott had in view a redetermination of this number, since in great part carried out. If both investigations are conducted with gases under the normal atmospheric conditions as to temperature and pressure, any small departures from the laws of Boyle and Charles will be practically without influence upon the final number representing the ratio of atomic weights.

In weighing the gas the procedure of Regnault was adopted, the working globe being compensated by a similar closed globe of the same external volume, made of the same kind of glass, and of nearly the same weight.

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Scientific Papers , pp. 37 - 43
Publisher: Cambridge University Press
Print publication year: 2009
First published in: 1902

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