Skip to main content Accessibility help

We use cookies to distinguish you from other users and to provide you with a better experience on our websites. Close this message to accept cookies or find out how to manage your cookie settings.

Close cookie message
×
Hostname: page-component-586b7cd67f-dsjbd Total loading time: 0 Render date: 2024-11-28T03:14:37.875Z Has data issue: false hasContentIssue false

12 - Raman Spectroscopy

Field Measurements

from Part II - Terrestrial Field and Airborne Applications

Published online by Cambridge University Press:  15 November 2019

By
Pablo Sobron ,
Anupam Misra ,
Fernando Rull  and
Antonio Sansano
Edited by
Janice L. Bishop ,
James F. Bell III  and
Jeffrey E. Moersch
Janice L. Bishop
Affiliation:
SETI Institute, California
James F. Bell III
Affiliation:
Arizona State University
Jeffrey E. Moersch
Affiliation:
University of Tennessee, Knoxville
Get access

Summary

Stand-off Raman spectroscopy is emerging as a critical new tool for planetary exploration. Mounted on a rover, a stand-off Raman system can be used to rapidly identify areas of interest for subsequent, synergistic investigations with other stand-off or close-up (arm-mounted) instruments; survey broad areas and perform reconnaissance tasks from a fixed location; and increase the efficiency of mission operations where targets of interest are in areas that are too hard to access for a rover. Not surprisingly, NASA’s next Mars mission will fly a stand-off Raman system as part of the SuperCam instrument package. This chapter reviews two stand-off Raman systems that paved the way for the development of new technologies and instrument architectures for robotic stand-off planetary exploration using Raman spectroscopy, including the SuperCam instrument suite.

Keywords

Raman spectroscopystand-offMarsmissionsupercam
Type
Chapter
Information
Remote Compositional Analysis
Techniques for Understanding Spectroscopy, Mineralogy, and Geochemistry of Planetary Surfaces
 , pp. 274 - 286
Publisher: Cambridge University Press
Print publication year: 2019

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Acosta-Maeda, T.E., Misra, A.K., Muzangwa, L.G., et al. (2016) Remote Raman measurements of minerals, organics, and inorganics at 430 m range. Applied Optics, 55, 10283–10289.CrossRefGoogle ScholarPubMed
Angel, S.M., Gomer, N.R., Sharma, S.K., & McKay, C. (2012) Remote Raman spectroscopy for planetary exploration: A review. Applied Spectroscopy, 66, 137–150.CrossRefGoogle ScholarPubMed
Beegle, L.W., Bhartia, R., DeFlores, L., et al. (2014) SHERLOC: Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals, an investigation for 2020. 45th Lunar Planet. Sci. Conf., 178, Abstract #2835.Google Scholar
Beegle, L., Bhartia, R., White, M., et al. (2015) SHERLOC: Scanning Habitable Environments with Raman and Luminescence for Organics and Chemicals. Proceedings of the 2015 IEEE Aerospace Conference, 1–11.CrossRefGoogle Scholar
Bremer, M.T. & Dantus, M. (2014) Detecting micro-particles of explosives at ten meters using selective stimulated Raman scattering. CLEO: 2014, JTh2A.5.Google Scholar
Bykov, S.V., Mao, M., Gares, K.L., & Asher, S.A. (2015) Compact solid-state 213 nm laser enables standoff deep ultraviolet Raman spectrometer: Measurements of nitrate photochemistry. Applied Spectroscopy, 69, 895–901.Google Scholar
Canny, J. (1986) A computational approach to edge detection. IEEE Transactions on Pattern Analysis and Machine Intelligence, PAMI-8, 679–698.Google Scholar
Dantus, M. (2014) Single-beam stimulated Raman scattering for sub-microgram standoff detection of explosives. Frontiers in Optics 2014, LW5I.1.Google Scholar
Dogariu, A.E.D.D.J.P. & Gauthier, D. (2013) Standoff explosive detection and hyperspectral imaging using coherent anti-Stokes Raman spectroscopy. Frontiers in Optics 2013, LTh4G.4.CrossRefGoogle Scholar
Fulton, J. (2011) Remote detection of explosives using Raman spectroscopy. Proceedings of SPIE 8018, Chemical, Biological, Radiological, Nuclear, and Explosives (CBRNE) Sensing, XII, 80181A, DOI:10.1117/12.887101.Google Scholar
Furić, K. & Volovšek, V. (2010) Water ice at low temperatures and pressures: New Raman results. Journal of Molecular Structure, 976, 174–180.CrossRefGoogle Scholar
Gaft, M. & Nagli, L. (2008) UV gated Raman spectroscopy for standoff detection of explosives. Optical Materials, 30, 1739–1746.Google Scholar
Gasda, P.J., Acosta-Maeda, T.E., Lucey, P.G., Misra, A.K., Sharma, S.K., & Taylor, G.J. (2015) Next generation laser-based standoff spectroscopy techniques for Mars exploration. Applied Spectroscopy, 69, 173–192.CrossRefGoogle ScholarPubMed
González, R.C., Woods, R.R.E., & Eddins, S.L. (2004) Digital image processing using Matlab. Dorling Kindersley, London.Google Scholar
Hansen, G.B. & McCord, T.B. (2004) Amorphous and crystalline ice on the Galilean satellites: A balance between thermal and radiolytic processes. Journal of Geophysical Research, 109, E01012.CrossRefGoogle Scholar
Hokr, B.H., Bixler, J.N., Noojin, G.D., et al. (2014) Single-shot stand-off chemical identification of powders using random Raman lasing. Proceedings of the National Academy of Sciences of the USA, 111, 12320–12324.Google Scholar
Hopkins, A.J., Cooper, J.L., Profeta, L.T., & Ford, A.R. (2016) Portable Deep-Ultraviolet (DUV) Raman for standoff detection. Applied Spectroscopy, 70, 861–873.Google Scholar
Hutchinson, I.B., Ingley, R., Edwards, H.G.M., et al. (2014) Raman spectroscopy on Mars: Identification of geological and bio-geological signatures in martian analogues using miniaturized Raman spectrometers. Philosophical Transactions of the Royal Society of London A: Mathematical, Physical and Engineering Sciences, 372, DOI:10.1098/rsta.2014.0204.Google Scholar
Izake, E.L., Cletus, B., Olds, W., Sundarajoo, S., Fredericks, P.M., & Jaatinen, E. (2012) Deep Raman spectroscopy for the non-invasive standoff detection of concealed chemical threat agents. Talanta, 94, 342–347.CrossRefGoogle Scholar
Lin, Q., Niu, G., Wang, Q., Yu, Q., & Duan, Y. (2013) Combined laser-induced breakdown with Raman spectroscopy: Historical technology development and recent applications. Applied Spectroscopy Reviews, 48, 487–508.CrossRefGoogle Scholar
Loeffen, P.W., Maskall, G., Bonthron, S., Bloomfield, M., Tombling, C., & Matousek, P. (2011) Spatially offset Raman spectroscopy (SORS) for liquid screening. Proceedings of SPIE 8189 Optics and Photonics for Counterterrorism and Crime Fighting VII, 81890C.CrossRefGoogle Scholar
Maurice, S., Wiens, R.C., Le Mouélic, S., et al. (2015) The SuperCam instrument for the Mars 2020 rover. European Planetary Science Congress Abstracts, 10, EPSC2015-185.Google Scholar
Misra, A.K., Sharma, S.K., Acosta, T.E., & Bates, D.E. (2011) Compact remote Raman and LIBS system for detection of minerals, water, ices, and atmospheric gases for planetary exploration. Proceedings of the SPIE 8032, Next-Generation Spectroscopic Technologies IV, 80320Q.Google Scholar
Misra, A.K., Sharma, S.K., Acosta, T.E., Porter, J.N., & Bates, D.E. (2012) Single-pulse standoff Raman detection of chemicals from 120 m distance during daytime. Applied Spectroscopy, 66, 1279–1285.CrossRefGoogle ScholarPubMed
Moros, J. & Laserna, J.J. (2011) New Raman-Laser-Induced Breakdown Spectroscopy identity of explosives using parametric data fusion on an integrated sensing platform. Analytical Chemistry, 83, 6275–6285.CrossRefGoogle Scholar
Moros, J., Lorenzo, J.A., & Laserna, J.J. (2011) Standoff detection of explosives: Critical comparison for ensuing options on Raman spectroscopy–LIBS sensor fusion. Analytical and Bioanalytical Chemistry, 400, 3353–3365.CrossRefGoogle ScholarPubMed
Pettersson, A., Wallin, S., Östmark, H., et al. (2010) Explosives standoff detection using Raman spectroscopy: From bulk towards trace detection. Proceedings of SPIE, Detection and Sensing of Mines, Explosive Objects, and Obscured Targets, XV, 76641K, DOI:10.1117/12.852544.Google Scholar
Rull, F., Sansano, A., Sobron, P., & Amase, T. (2010) In-situ Raman-LIBS analysis of regolithes during AMASE 2008 and 2009 expeditions. 41st Lunar Planet. Sci. Conf., Abstract #2731.Google Scholar
Rull, F., Vegas, A., Sansano, A., & Sobron, P. (2011) Analysis of Arctic ices by remote Raman spectroscopy. Spectrochimica Acta A: Molecular and Biomolecular Spectroscopy, 80, 148–155.CrossRefGoogle ScholarPubMed
Scaffidi, J.P., Gregas, M.K., Lauly, B., Carter, J.C., Angel, S.M., & Vo-Dinh, T. (2010) Trace molecular detection via surface-enhanced Raman scattering and surface-enhanced resonance Raman scattering at a distance of 15 meters. Applied Spectroscopy, 64, 485–492.CrossRefGoogle Scholar
Sharma, S.K., Misra, A.K., Lucey, P.G., Angel, S.M., & McKay, C.P. (2006) Remote pulsed Raman spectroscopy of inorganic and organic materials to a radial distance of 100 meters. Applied Spectroscopy, 60, 871–876.CrossRefGoogle Scholar
Sharma, S.K., Misra, A.K., Lucey, P.G., & Lentz, R.C.F. (2009) A combined remote Raman and LIBS instrument for characterizing minerals with 532 nm laser excitation. Spectrochimica Acta A: Molecular and Biomolecular Spectroscopy, 73, 468–476.Google Scholar
Sharma, S.K., Misra, A.K., Clegg, S.M., et al. (2011) Remote-Raman spectroscopic study of minerals under supercritical CO2 relevant to Venus exploration. Spectrochimica Acta A: Molecular and Biomolecular Spectroscopy, 80, 75–81.CrossRefGoogle ScholarPubMed
Skulinova, M., Lefebvre, C., Sobron, P., et al. (2014) Time-resolved stand-off UV-Raman spectroscopy for planetary exploration. Planetary and Space Science, 92, 88–100.CrossRefGoogle Scholar
Sobron, P., Sanz, A., Thompson, C., Cabrol, N., & Team, P.L.L.P. (2014) In-situ lake bio-geochemistry using laser Raman spectroscopy and optrode sensing. 11th International GeoRaman Conference, Abstract #5027.Google Scholar
Sobron, P., Andersen, D.T., & Pollard, W.H. (2016) In-situ exploration of habitable environments and biosignatures in Arctic cold springs and Antarctic paleolakes. Conference on Biosignature Preservation and Detection in Mars Analog Environments, Abstract #1912.Google Scholar
Steele, A., Amundsen, H.E.F., Fogel, M., et al. (2011) The Arctic Mars Analogue Svalbard Expedition (AMASE) 2010. 42nd Lunar Planet. Sci. Conf., Abstract #1588.Google Scholar
Vítek, P., Edwards, H.G.M., Jehlička, J., et al. (2010) Microbial colonization of halite from the hyper-arid Atacama Desert studied by Raman spectroscopy. Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 368, 3205–3221.Google Scholar
Wei, J., Wang, A., Lambert, J.L., et al. (2015) Autonomous soil analysis by the Mars Micro-beam Raman Spectrometer (MMRS) on-board a rover in the Atacama Desert: A terrestrial test for planetary exploration. Journal of Raman Spectroscopy, 46, 810–821.Google Scholar
Zachhuber, B., Gasser, C., Chrysostom, E.t.H., & Lendl, B. (2011) Stand-off spatial offset Raman spectroscopy for the detection of concealed content in distant objects. Analytical Chemistry, 83, 9438–9442.CrossRefGoogle ScholarPubMed

Save book to Kindle

To save this book to your Kindle, first ensure [email protected] is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Available formats
×

Save book to Dropbox

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Dropbox.

Available formats
×

Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

Available formats
×