Preface

Summary

Photodissociation of small polyatomic molecules is an ideal field for investigating molecular dynamics at a high level of precision. The last decade has seen an explosion of many new experimental methods which permit the study of bond fission on the basis of single quantum states. Experiments with three lasers — one to prepare the parent molecule in a particular vibrational-rotational state in the electronic ground state, one to excite the molecule into the continuum, and finally a third laser to probe the products — are quite usual today. State-specific chemistry finally has become reality. The understanding of such highly resolved measurements demands theoretical descriptions which go far beyond simple models.

Although the theory of photodissociation has not yet reached the level of sophistication of experiment, major advances have been made in recent years by many research groups. This concerns the calculation of accurate multi-dimensional potential energy surfaces for excited electronic states and the dynamical treatment of the nuclear motion on these surfaces. The exact quantum mechanical modelling of the dissociation of a triatomic molecule is nowadays practicable without severe technical problems. Moreover, simple but nevertheless realistic models have been developed and compared against exact calculations which are very useful for understanding the interrelation between the potential and the nuclear dynamics on one hand and the experimental observables on the other hand.

The aim of this book is to provide an overview of the theoretical methods for treating photodissociation processes in small polyatomic molecules and the achievements in merging ab initio calculations and detailed experiments. It is primarily written for graduate students starting research in molecular physics.