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10 - Future opportunities and challenges of electrospinning

Published online by Cambridge University Press:  05 July 2014

Frank K. Ko
Affiliation:
University of British Columbia, Vancouver
Yuqin Wan
Affiliation:
University of British Columbia, Vancouver
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Summary

Future of nanotechnology

In 2000, Roco et al. [1] estimated that there would be two million nanotechnology workers worldwide (800 000 in the United States) and the product value would reach $1 trillion, of which $800 billion would be in the United States, by 2015, with a 25% rate growth. The initial estimation for the quasi-exponential growth in the nanotechnology workforce and the product value held up to 2008, as shown in Fig.10.1. The market is doubling every three years as a result of the successive introduction of new products, and new generations of nanotechnology products are expected to enter the market within the next few years [1]. So the estimated value of 2015 for both workforce and product value would have been realized as the 25% growth rate is expected to continue.

Nanotechnology is evolving toward new scientific and engineering challenges in areas such as assembly of nanosystems, nanobiotechnology and nanobiomedicine, development of advanced tools, environmental preservation and protection, and pursuit of societal implication studies. Key areas of emphasis in nanotechnology [1] over the next decade are as follows.

  • Integration of knowledge at the nanoscale and of nanocomponents in nanosystems with deterministic and complex behavior, aiming toward creating fundamentally new products.

  • Better control of molecular self-assembly, quantum behavior, creation of new molecules, and interaction of nanostructures with external fields in order to build materials, devices and systems by modeling and computational design.

  • Understanding of biological processes and of nanobio interfaces with abiotic materials, and their biomedical and health/safety applications, and nanotechnology solutions for sustainable natural resources and nanomanufacturing.

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Publisher: Cambridge University Press
Print publication year: 2014

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References

Roco, M. C., Mirkin, C. A., and Hersam, M. C., Nanotechnology Research Directions for Societal Needs in 2020. Wtec, 2011.CrossRefGoogle Scholar
Smalley, R., “Future global energy prosperity: the terawatt challenge,” MRS Bulletin, vol. 30(6), pp. 412–424, 2005.CrossRefGoogle Scholar
Kim, Y. S., et al., “Electrospun bimetallic nanowires of PtRh and PtRu with compositional variation for methanol electrooxidation,” Electrochemistry Communications, vol. 10(7), pp. 1016–1019, 2008.CrossRefGoogle Scholar
Schechner, P., et al., “Silver-plated electrospun fibrous anode for glucose alkaline fuel cells,” Journal of the Electrochemical Society, vol. 154(9), pp. B942–B948, 2007.CrossRefGoogle Scholar
Kim, H. J., et al., “Highly improved oxygen reduction performance over Pt/C-dispersed nanowire network catalysts,” Electrochemistry Communications, vol. 12(1), pp. 32–35, 2010.CrossRefGoogle Scholar
Li, M., et al., “Electrospinning-derived carbon fibrous mats improving the performance of commercial Pt/C for methanol oxidation,” Journal of Power Sources, vol. 191(2), pp. 351–356, 2009.CrossRefGoogle Scholar
Park, J.-H., et al., “Effects of electrospun polyacrylonitrile-based carbon nanofibers as catalyst support in PEMFC,” Journal of Applied Electrochemistry, vol. 39(8), pp. 1229–1236, 2009.CrossRefGoogle Scholar
Choi, S. W., et al., “Nafion-impregnated electrospun polyvinylidene fluoride composite membranes for direct methanol fuel cells,” Journal of Power Sources, vol. 180(1), pp. 167–171, 2008.CrossRefGoogle Scholar
Kim, J. R., et al., “Electrospun PVdF-based fibrous polymer electrolytes for lithium ion polymer batteries,” Electrochimica Acta, vol. 50(1), pp. 69–75, 2004.CrossRefGoogle Scholar
Subramania, A., and Devi, S. L., “Polyaniline nanofibers by surfactant-assisted dilute polymerization for supercapacitor applications,” Polymers for Advanced Technologies, vol. 19(7), pp. 725–727, 2008.CrossRefGoogle Scholar
Kim, C., et al., “Characteristics of supercapacitor electrodes of PBI-based carbon nanofiber web prepared by electrospinning,” Electrochimica Acta, vol. 50(2–3), pp. 877–881, 2004.CrossRefGoogle Scholar
Song, M. Y., et al., “Electrospun TiO2 electrodes for dye-sensitized solar cells,” Nanotechnology, vol. 15(12), pp. 1861–1865, 2004.CrossRefGoogle Scholar
Hu, G., et al., “Anatase TiO 2 nanoparticles/carbon nanotubes nanofibers: preparation, characterization and photocatalytic properties,” Journal of Materials Science, vol. 42(17), pp. 7162–7170, 2007.CrossRefGoogle Scholar
Aryal, S., et al., “Multi-walled carbon nanotubes/TiO2 composite nanofiber by electrospinning,” Materials Science and Engineering: C, vol. 28(1), pp. 75–79, 2008.CrossRefGoogle Scholar
Fujihara, K., et al., “Spray deposition of electrospun TiO2 nanorods for dye-sensitized solar cell,” Nanotechnology, vol. 18(36), p. 365709, 2007.CrossRefGoogle Scholar
Song, M. Y., et al., “Enhancement of the photocurrent generation in dye-sensitized solar cell based on electrospun TiO2 electrode by surface treatment,” Synthetic Metals, vol. 155(3), pp. 635–638, 2005.CrossRefGoogle Scholar
Schaefer, K., et al., Nano-Fibres for Filter Materials, in Multifunctional Barriers for Flexible Structure. Berlin, Heidelberg: Springer, p. 125–138, 2007.Google Scholar
Andreev, G., et al., “Nanotechnology-derived materials: potential risk in preparation and use,” Russian Journal of General Chemistry, vol. 79(9), pp. 1974–1981, 2009.CrossRefGoogle Scholar
Li, H.-W., et al., “Removal and retention of viral aerosols by a novel alumina nanofiber filter,” Journal of Aerosol Science, vol. 40(1), pp. 65–71, 2009.CrossRefGoogle Scholar
Lala, N., et al., “Fabrication of nanofibers with antimicrobial functionality used as filters: protection against bacterial contaminants,” Biotechnology and Bioengineering, vol. 97(6), pp. 1357–1365, 2007.CrossRefGoogle ScholarPubMed
Xia, Y., “Nanomaterials at work in biomedical research,” Nature Materials, vol. 7(10), pp. 758–760, 2008.CrossRefGoogle ScholarPubMed
Shin, Y. M., et al., “Electrospinning: a whipping fluid jet generates submicron polymer fibers,” Applied Physics Letters, vol. 78(8), pp. 1149–1151, 2001.CrossRefGoogle Scholar
Spivak, A. F., Dzenis, Y. A., and Reneker, D. H., “A model of steady state jet in the electrospinning process,” Mechanics Research Communications, vol. 27(1), pp. 37–42, 2000.CrossRefGoogle Scholar
Spivak, A. F., and Dzenis, Y. A., “Asymptotic decay of radius of a weakly conductive viscous jet in an external electric field,” Applied Physics Letters, vol. 73(21), pp. 3067–3069, 1998.CrossRefGoogle Scholar
Shin, Y. M., et al., “Experimental characterization of electrospinning: the electrically forced jet and instabilities,” Polymer, vol. 42(25), pp. 09955–09967, 2001.CrossRefGoogle Scholar
Hohman, M. M., et al., “Electrospinning and electrically forced jets. I. Stability theory,” Physics of Fluids, vol. 13(8), pp. 2201–2220, 2001.CrossRefGoogle Scholar
Wan, Y. Q., Guo, Q., and Pan, N., “Thermo-electro-hydrodynamic model for electrospinning process,” International Journal of Nonlinear Sciences and Numerical Simulation, vol. 5(1), pp. 5–8, 2004.CrossRefGoogle Scholar
He, J. H., Wan, Y. Q., and Yu, J. Y., “Allometric scaling and instability in electrospinning,” International Journal of Nonlinear Sciences and Numerical Simulation, vol. 5, pp. 243–252, 2004.CrossRefGoogle Scholar
Deitzel, J., et al., Generation of Polymer Nanofibers Through Electrospinning, Army Research Lab Aberdeen Proving Ground Md., 1999.Google Scholar
Salem, D. R., “Electrospinning of nanofibers and the charge injection methods, in Nanofibers and Nanotechnology in Textiles,” Brown, P. J. and Stevens, K., Ed., Cambridge, England: Woodhead Publishing Limited, 2007.Google Scholar
Yamashita, Y., et al., “Establishment of nanofiber preparation technique by electrospinning,” Sen'i Gakkaishi, vol. 64(1), pp. 24–28, 2008.CrossRefGoogle Scholar
Varabhas, J. S., Chase, G. G., and Reneker, D. H., “Electrospun nanofibers from a porous hollow tube,” Polymer, vol. 49(19), pp. 4226–4229, 2008.CrossRefGoogle Scholar
Varesano, A., Carletto, R. A., and Mazzuchetti, G., “Experimental investigations on the multi-jet electrospinning process,” Journal of Materials Processing Technology, vol. 209(11), pp. 5178–5185, 2009.CrossRefGoogle Scholar
Theron, S. A., et al., “Multiple jets in electrospinning: experiment and modeling.” Polymer, vol. 46(9), pp. 2889–2899, 2005.CrossRefGoogle Scholar
Yang, Y., et al. Electrospun Uniform Fibres with a Special Regular Hexagon Distributed Multi-needles System. IOP Publishing, 2008.Google Scholar
Tomaszewski, W., and Szadkowski, M., “Investigation of electrospinning with the use of a multi-jet electrospinning head,” Fibres & Textiles in Eastern Europe 2005, vol. 13(4), pp. 22–26, 2005.Google Scholar
Kim, G., Cho, Y.-S., and Kim, W. D., “Stability analysis for multi-jets electrospinning process modified with a cylindrical electrode,” European Polymer Journal, vol. 42(9), pp. 2031–2038, 2006.CrossRefGoogle Scholar
Varesano, A., et al., “Multi-jet nozzle electrospinning on textile substrates: observations on process and nanofibre mat deposition,” Polymer International, vol. 59(12), pp. 1606–1615, 2010.CrossRefGoogle Scholar
Dosunmu, O. O., et al., “Electrospinning of polymer nanofibers from mulitple jets on a porous tubular surface,” Nanotechnology, vol. 17, p. 1123, 2006.CrossRefGoogle Scholar
Lu, B., et al., “Superhigh-throughput needleless electrospinning using a rotary cone as spinneret,” Small, vol. 6(15), pp. 1612–1616, 2010.CrossRefGoogle ScholarPubMed
Wang, X., et al., “Needleless electrospinning of nanofibers with a conical wire coil,” Polymer Engineering & Science, vol. 49(8), pp. 1582–1586, 2009.CrossRefGoogle Scholar
Yarin, A. L., and Zussman, E., “Upward needleless electrospinning of multiple nanofibers,” Polymer, vol. 45, p. 2977, 2004.CrossRefGoogle Scholar
Lukas, D., Sarkar, A., and Pokorny, P., “Self-organization of jets in electrospinning from free liquid surface: a generalized approach,” Journal of Applied Physics, vol. 103(8), p. 084309–7, 2008.CrossRefGoogle Scholar
Liu, Y., and He, J., “Bubble electrospinning for mass production of nanofibers,” International Journal of Nonlinear Sciences and Numerical Simulation, vol. 8(3), p. 393, 2007.CrossRefGoogle Scholar
Petrik, S., and Maly, M.. Production Nozzle-Less Electrospinning Nanofiber Technology, in 2009 Fall MRS Symposium. Boston, MA, 2009.Google Scholar
Wu, D., et al., “High throughput tip-less electrospinning via a circular cylindrical electrode,” Journal of Nanoscience and Nanotechnology, vol. 10(7), pp. 4221–4226, 2010.CrossRefGoogle Scholar
Kessick, R., Fenn, J., and Tepper, G., “The use of AC potentials in electrospraying and electrospinning processes,” Polymer, vol. 45(9), pp. 2981–2984, 2004.CrossRefGoogle Scholar
Sarkar, S., Deevi, S., and Tepper, G., “Biased AC electrospinning of aligned polymer nanofibers,” Macromolecular Rapid Communications, vol. 28(9), pp. 1034–1039, 2007.CrossRefGoogle Scholar
Buttafoco, L., et al., “Electrospinning of collagen and elastin for tissue engineering applications,” Biomaterials, vol. 27(5), pp. 724–734, 2006.CrossRefGoogle ScholarPubMed
Stankus, J. J., Guan, J., and Wagner, W. R., “Fabrication of biodegradable elastomeric scaffolds with sub-micron morphologies,” Journal of Biomedical Materials Research Part A, vol. 70A(4), pp. 603–614, 2004.CrossRefGoogle Scholar
Deitzel, J. M., et al., “The effect of processing variables on the morphology of electrospun nanofibers and textiles,” Polymer, vol. 42(1), pp. 261–272, 2001.CrossRefGoogle Scholar
Wu, Y., et al., “Controlling stability of the electrospun fiber by magnetic field,” Chaos, Solitons and Fractals, vol. 32(1), pp. 5–7, 2007.CrossRefGoogle Scholar
Yang, D., et al., “Fabrication of aligned fibrous arrays by magnetic electrospinning,” Advanced Materials, vol. 19(21), pp. 3702–3706, 2007.CrossRefGoogle Scholar
Matthews, J., et al., “Electrospinning of collagen nanofibers,” Biomacromolecules, vol. 3(2), pp. 232–238, 2002.CrossRefGoogle ScholarPubMed
Katta, P., et al., “Continuous electrospinning of aligned polymer nanofibers onto a wire drum collector,” Nano Letters, vol. 4(11), pp. 2215–2218, 2004.CrossRefGoogle Scholar
Li, D., Wang, Y., and Xia, Y., “Electrospinning of polymeric and ceramic nanofibers as uniaxially aligned arrays,” Nano Letters, vol. 3(8), pp. 1167–1171, 2003.CrossRefGoogle Scholar
Zhang, Q., et al., “Electrospun carbon nanotube composite nanofibres with uniaxially aligned arrays,” Nanotechnology, vol. 18(115611), p. 115611, 2007.CrossRefGoogle Scholar
Teo, W. E., and Ramakrishna, S., “Electrospun fibre bundle made of aligned nanofibres over two fixed points,” Nanotechnology, vol. 16(9), p. 1878, 2005.CrossRefGoogle Scholar
Theron, A., et al., “Electrostatic field-assisted alignment of electrospun nanofibres,” Nanotechnology, vol. 12(3), p. 384, 2001.CrossRefGoogle Scholar
Foedinger, R., et al., “High strength nanomaterials fiber for lightweight composite missile cases,” in 230th ACS National Meeting. Washington, DC, USA, 2005.Google Scholar
Smit, E., Buttner, U., and Sanderson, R. D., “Continuous yarns from electrospun fibers,” Polymer, vol. 46(8), pp. 2419–2423, 2005.CrossRefGoogle Scholar
Khil, M.-S., et al., “Novel fabricated matrix via electrospinning for tissue engineering,” Journal of Biomedical Materials Research, vol. 72B(1), pp. 117–124, 2005.CrossRefGoogle Scholar
Teo, W.-E., et al., “A dynamic liquid support system for continuous electrospun yarn fabrication,” Polymer, vol. 48(12), pp. 3400–3405, 2007.CrossRefGoogle Scholar
Wan, Y. Q., et al., “Electrospinning of high molecule PEO solution,” Journal of Applied Polymer Science, vol. 103(6), pp. 3840–3843, 2007.CrossRefGoogle Scholar
Wan, Y. Q., He, J. H., and Yu, J. Y., “Carbon nanotube-reinforced polyacrylonitrile nanofibers by vibration-electrospinning,” Polymer International, vol. 56(11), pp. 1367–1370, 2007.CrossRefGoogle Scholar

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