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5 - High Gravity Fields

Published online by Cambridge University Press:  12 May 2020

Laurence R. Weatherley
Affiliation:
University of Kansas
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Summary

High gravity fields are exploited in a range of processes involving liquid–liquid dispersions. The accelerative forces achieved acting on dispersed drops can be several thousand-fold that of gravity. The benefits of the presence of the high gravity field include short residence times, efficient separations, less material hold-up, and reduction of equipment size. The development of spinning disk contactors for intensified liquid–liquid contacting is described, with discussion of the hydrodynamic phenomena which underpin the enhancements in mass transfer and reaction. A number of variants are described, including impinging jet contactors, parallel spinning tube contactors, and annular centrifugal contactors. Theoretical analysis of the fluid mechanics in spinning disk contactors and parallel spinning disk contactors is presented, with good comparison to experimental observation. The role of Taylor–Couette flows in spinning tube contactors is briefly discussed. Possibilities for intensifying the performance of tubular membrane contactors using high gravity fields are discussed, together with scope for conducting enantiomeric separations by application of high gravity.

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Publisher: Cambridge University Press
Print publication year: 2020

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References

Arnott, I. (1993). Solvent extraction of fermentation products using electrostatic and centrifugal fields. Ph.D. thesis, Heriot Watt University.Google Scholar
Arnott, I. A. and Weatherley, L. R. (1994a). Hydraulic studies in a combined field liquid–liquid contactor. Proceeding of EXTRACTION 94, Edinburgh, UK, October 1994. Institution of Chemical Engineers Symposium Series, London.Google Scholar
Arnott, I. A. and Weatherley, L. R. (1994b). Entrainment studies in a combined field liquid–liquid extractor. Proceedings of the Fourth IChemE Irish Research Symposium, Dublin, March 1994, 17-30, The Institution of Chemical Engineers, London.Google Scholar
Boiarkina, I., Pedron, S., and Patterson, D. A. (2011). An experimental and modelling investigation of the effect of the flow regime on the photocatalytic degradation of methylene blue on a thin film coated ultraviolet irradiated spinning disc reactor. Applied Catalysis B: Environmental, 110, 1424.CrossRefGoogle Scholar
Boodhoo, K. V. K. and Jachuck, R. J. (2000a). Process intensification: spinning disk reactor for styrene pol. Applied Thermal Engineering, 20, 11271146.Google Scholar
Boodhoo, K. V. K. and Jachuck, R. J. (2000b). Process intensification: spinning disk reactor for condensation polymerization. Green Chemistry, 2, 235244.Google Scholar
Boodhoo, K. V. K., Dunk, W. A. E., Vicevic, M. et al. (2006). Classical cationic polymerization of styrene in a spinning disc reactor using silica-supported BF3 catalyst. Journal of Applied Polymer Science, 101, 819.Google Scholar
Bowe, M. J., Oruh, S. N., and Singh, J. (1985). UK patent application GB 2,155,803A.Google Scholar
Chandrasekhar, S. (1962). The stability of spiral flow between rotating cylinders. Proceedings of the Royal Society A, 265(1321), 188197.Google Scholar
Coles, D. J. (1965). Transition in circular Couette flow. Journal of Fluid Mechanics, 21, 385425.Google Scholar
Dehkordi, A. M. (2002a). Liquid–liquid extraction with chemical reaction in an impinging jets reactor. AIChE Journal, 48(10), 22302239.Google Scholar
Dehkordi, A. M. (2002b). A novel two-impinging-jets reactor for copper extraction and stripping processes. Chemical Engineering Journal, 87(2), 227238.Google Scholar
Feng, X., Tang, K., Zhang, P., and Yin, S. (2016). Experimental and model studies on continuous separation of 2-phenylpropionic acid enantiomers by enantioselective liquid–liquid extraction in centrifugal contactor separators. Chirality, 28, 235244.Google Scholar
Holl, R. (2003). Reactor design: adding some spin. The Chemical Engineer, 742, 3234.Google Scholar
Holl, R. A. (2006). Methods of operating surface reactors and reactors employing such methods, US Patent 7,125,527 B2.Google Scholar
Holl, R.A. (2010). Spinning tube in tube reactors and their methods of operation, US Patent 7,780,927 B2.Google Scholar
Jachuck, R. J. and Scalley, M. J. (2003). Process technology for continuous production of nano-micron size particles. AICHE Spring National Meeting. Safety and Sustainability: Core Issues Shaping Tomorrow, New Orleans, Louisiana, USA.Google Scholar
Jammoal, Y. and Lee, J. M. G. (2015). Drop velocity in a rotating liquid–liquid system. Chemical Engineering Research and Design, 104, 638646.Google Scholar
Judd, S., Qiblawey, H., Al-Marri, M., et al. (2014). The size and performance of offshore produced water oil-removal technologies for reinjection. Separation and Purification Technology, 134, 241246.Google Scholar
Kadam, B. D., Joshi, J. B., Koganti, S. B., and Patil, R. N. (2008). Hydrodynamic and mass transfer characteristics of annular centrifugal extractors. Chemical Engineering Research and Design, 86(3), 233244.Google Scholar
Kadam, B. D., Joshi, J. B., Koganti, S. B., and Patil, R. N. (2009). Dispersed phase hold-up, effective interfacial area and Sauter mean drop diameter in annular centrifugal extractors. Chemical Engineering Research and Design, 87(10), 13791389.Google Scholar
Leveson, P., Dunk, W. A. E., and Jachuck, R. J. (2003). Numerical investigation of kinetics of free-radical polymerization on spinning disk reactor. Journal of Applied Polymer Science, 90, 693699.Google Scholar
Martínez, A. N. M., van Eeten, K. M. P., Schouten, J. C., and van der Schaaf, J. (2017). Micromixing in a rotor–stator spinning disc reactor Industrial and Engineering Chemistry Research, 56, 1345413460.CrossRefGoogle Scholar
Meeuwse, M., van der Schaaf, J., and Schouten, J. C. (2010). Mass transfer in a rotor–stator spinning disk reactor with cofeeding of gas and liquid. Industrial and Engineering Chemistry Research, 49, 16051610.Google Scholar
Meikrantz, D. H., Macaluso, L. L., and Flim, W. D. (2002). A new annular centrifugal contactor for pharmaceutical processes. Chemical Engineering Communications, 189, 16291639.CrossRefGoogle Scholar
Millar, M. K. and Weatherley, L. R. (1989) Whole broth extraction in an electrically enhanced liquid/liquid contact system. Chemical Engineering Research and Design, 67, 227231.Google Scholar
Moser, K. W., Raguin, L. G., Harris, A., et al. (2000).Visualization of Taylor–Couette and spiral Poiseuille flows using a snapshot FLASH spatial tagging sequence. Magnetic Resonance Imaging, 18, 199207.CrossRefGoogle ScholarPubMed
Motin, A., Tarabara, V. V., and Bénard, A. (2015). Numerical investigation of the performance and hydrodynamics of a rotating tubular membrane used for liquid–liquid separation. Journal of Membrane Science, 473, 245255.Google Scholar
Nemri, M., Climent, E., Charton, S., Lanoëa, J., and Ode, D. (2013). Experimental and numerical investigation on mixing and axial dispersion in Taylor–Couette flow patterns. Chemical Engineering Research and Design, 91, 23462354.Google Scholar
Oxley, P., Brechtelsbauer, C., Ricard, F., Lewis, N., and Ramshaw, C. (2000). Evaluation of spinning disk reactor technology for the manufacture of pharmaceuticals. Industrial Engineering Chemistry Research, 39, 21752182.CrossRefGoogle Scholar
Petera, J. and Weatherley, L. R. (2001). Modeling of mass transfer from falling droplets. Chemical Engineering Science, 56, 49294947.Google Scholar
Poncet, S., Chauve, M. P., and Schiestel, R. (2005). Batchelor versus Stewartson flow structures in a rotor–stator cavity with throughflow. Physics of Fluids, 17, 075110075115.Google Scholar
Qiu, Z., Petera, J., and Weatherley, L. R. (2012). Biodiesel production using an intensified spinning disc reactor. Chemical Engineering Journal, 210, 597609.Google Scholar
Ramshaw, C. (2004). The spinning disc reactor. In Stankiewicz, A. and Moulijn, J. A., eds., Re-engineering the Chemical Processing Plant Process Intensification. Marcel Dekker.Google Scholar
Svarovsky, L. (1991). Solid–Liquid Separation, 3rd ed. Oxford: Butterworth Heinemann.Google Scholar
Syed, A. and Fruh, W. (2003). Modelling of mixing in a Taylor-Couette reactor with axial flow. Journal of Chemical Technology and Biotechnology, 78, 227235.Google Scholar
Tai, C. Y., Tai, C. T., and Liu, H. S. (2006). Synthesis of submicron barium carbonate using a high gravity technique. Chemical Engineering Science, 61, 74797486.Google Scholar
Tamhane, T. V., Jyeshtharaj, B., Joshi, J. B., et al. (2012). Axial mixing in annular centrifugal extractors. Chemical Engineering Journal, 207 –208, 462472.Google Scholar
Tamhane, T. V., Joshi, J. B., and Patil, R. N. (2014). Performance of annular centrifugal extractors: CFD simulation of flow pattern, axial mixing and extraction with chemical reaction. Chemical Engineering Science, 110, 134143.Google Scholar
Taylor, G. I. (1923). Stability of a viscous liquid contained between two rotating cylinders. Philosophical Transactions of the Royal Society A, 223(605–615), 289343.Google Scholar
Treybal, R. E. (1955). Liquid–Liquid Extraction. New York: McGraw Hill.Google Scholar
Vedantam, S. and Joshi, J. B. (2006). Annular centrifugal contactors: a review. Chemical Engineering Research and Design, 84(7), 522542.Google Scholar
Vedantam, S., Wardle, K. E., Tamhane, T. V., Ranade, V. V., and Joshi, J. B. (2012). CFD simulation of annular centrifugal extractors. International Journal of Chemical Engineering, Article ID 759397.Google Scholar
Visscher, F., van der Schaaf, J., de Croon, M. H. J. M., and Schouten, J. C. (2012). Liquid–liquid mass transfer in a rotor–stator spinning disc reactor. Chemical Engineering Journal, 185 /186, 267273.Google Scholar
Visscher, F., Nijhuis, R. T. R., de Croon, M. H. J. M., van der Schaaf, J., and Schouten, J. C. (2013). Liquid–liquid flow in an impeller–stator spinning disc reactor. Chemical Engineering and Processing, 71, 107114.CrossRefGoogle Scholar
Zhang, P., Feng, X., Tang, K., and Weifeng, X. W. (2016). Study on enantioseparation of α-cyclopentyl-mandelic acid enantiomers using continuous liquid–liquid extraction in centrifugal contactor separators: Experiments and modeling. Chemical Engineering and Processing, 107, 168176.Google Scholar

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