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4 - Periodicity and atomic properties

Published online by Cambridge University Press:  14 January 2010

Derek W. Smith
Affiliation:
University of Waikato, New Zealand
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Summary

The Periodic Table

In 1922, the English-born (and New Zealand-educated) chemist J. W. Mellor published the first of 16 volumes which constituted his Comprehensive Treatise on Inorganic and Theoretical Chemistry — perhaps the greatest single-handed effort in the whole of the chemical literature. In explaining the arrangement of his material, he wrote: ‘We now flatter ourselves that the Periodic Law has given inorganic chemistry a scheme of classification which enables the facts to be arranged and grouped in a scientific manner. The appearance of order imparted by that guide is superficial and illusory. Allowing for certain lacunae in the knowledge of the scarcer elements, prior to the appearance of that Law, the arrangements employed by the earlier chemists were just as satisfactory and in some cases, indeed, more satisfactory than those based on the Periodic Law. The arrangement of the subject matter of inorganic chemistry according to the periodic scheme is justified solely by expediency and convention. It has a tendency to make teachers over-emphasise unimportant and remote analogies, and to underestimate important and crucial differences.’

These views were certainly worthy of respect in 1922; Mellor, who was already well known as an author, probably knew as much factual inorganic chemistry as anyone alive.

Type
Chapter
Information
Inorganic Substances
A Prelude to the Study of Descriptive Inorganic Chemistry
, pp. 108 - 137
Publisher: Cambridge University Press
Print publication year: 1990

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