Book contents
- Frontmatter
- Contents
- Preface
- 1 Introduction
- 2 Two-faced maps
- 3 Fullerenes as tilings of surfaces
- 4 Polycycles
- 5 Polycycles with given boundary
- 6 Symmetries of polycycles
- 7 Elementary polycycles
- 8 Applications of elementary decompositions to (r, q)-polycycles
- 9 Strictly face-regular spheres and tori
- 10 Parabolic weakly face-regular spheres
- 11 General properties of 3-valent face-regular maps
- 12 Spheres and tori that are aRi
- 13 Frank-Kasper spheres and tori
- 14 Spheres and tori that are bR1
- 15 Spheres and tori that are bR2
- 16 Spheres and tori that are bR3
- 17 Spheres and tori that are bR4
- 18 Spheres and tori that are bRj for j ≥ 5
- 19 Icosahedral fulleroids
- References
- Index
5 - Polycycles with given boundary
Published online by Cambridge University Press: 06 July 2010
- Frontmatter
- Contents
- Preface
- 1 Introduction
- 2 Two-faced maps
- 3 Fullerenes as tilings of surfaces
- 4 Polycycles
- 5 Polycycles with given boundary
- 6 Symmetries of polycycles
- 7 Elementary polycycles
- 8 Applications of elementary decompositions to (r, q)-polycycles
- 9 Strictly face-regular spheres and tori
- 10 Parabolic weakly face-regular spheres
- 11 General properties of 3-valent face-regular maps
- 12 Spheres and tori that are aRi
- 13 Frank-Kasper spheres and tori
- 14 Spheres and tori that are bR1
- 15 Spheres and tori that are bR2
- 16 Spheres and tori that are bR3
- 17 Spheres and tori that are bR4
- 18 Spheres and tori that are bRj for j ≥ 5
- 19 Icosahedral fulleroids
- References
- Index
Summary
The (r, q)-boundary sequence of a finite (r, q)-polycycle P is the sequence b(P) of numbers enumerating, up to a cyclic shift or reversal, the consecutive degrees of vertices incident to the exterior face. For earlier applications of this (and other) codes, see.
Given an (r, q)-boundary sequence b, a plane graph P is called a (r, q)-filling of b if P is an (r, q)-polycycle such that b = b(P).
In this chapter we consider the unicity of those (r, q)-fillings and algorithms used for their computations.
The problem of uniqueness of (r, q)-fillings
By inspecting the list of (r, q)-polycycles for (r, q) = (3, 3), (3, 4), or (4, 3) in Section 4.2, we find that the (r, q)-boundary sequence of an (r, q)-polycycle determines it uniquely. We expect that for any other pair (r, q) this is not so
We show that the value r = 3, 4 are the only ones, such that the (r, 3)-boundary sequence always defines its (r, 3)-filling uniquely. Note that an (r, q)-polycycle, which is not an unique filling of its boundary, is, necessarily, a helicene. Some examples of non-uniqueness of (r, 3)-fillings are cases of boundaries b, admitting an (r, 3)-filling P with the symmetry group of b being larger than the symmetry group of P, implying the existence of several different (r, 3)-fillings.
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- Geometry of Chemical GraphsPolycycles and Two-faced Maps, pp. 56 - 63Publisher: Cambridge University PressPrint publication year: 2008