Crystal Field Handbook

doi:10.1017/CBO9780511524295

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Edited by D. J. Newman, University of Southampton, Betty Ng, Environment Agency, Wales

Publisher:: Cambridge University Press
Online publication date:: December 2009
Print publication year:: 2000
Online ISBN:: 9780511524295
DOI:: https://doi.org/10.1017/CBO9780511524295

Subjects:: Physics and Astronomy, Condensed Matter Physics, Nanoscience and Mesoscopic Physics, Engineering, Materials Science

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This book, first published in 2000, is based on the modern conceptual understanding of crystal fields. It provides readers with clear instructions and a set of computer programs for the phenomenological analysis of energy spectra of magnetic ions in solids. The text clarifies several issues that have historically produced confusion in this area, particularly the effects of covalency and ligand polarization on the energy spectra of magnetic ions. Readers are shown how to employ a hierarchy of parametrized models to extract as much information as possible from observed lanthanide and actinide spectra. This book of crystal field theory describes all of the available phenomenological models, together with the conceptual and computational tools necessary for their use. It will be of particular interest to graduate students and researchers working in the development of opto-electronic systems and magnetic materials.

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Crystal Field Handbook

This Book has been cited by the following publications. This list is generated based on data provided by Crossref.

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Contents

Frontmatter
pp i-vi

Contents
pp vii-viii

List of contributors
pp ix-x

Preface
pp xi-xii

Introduction
pp 1-5

1 - Crystal field splitting mechanisms
pp 6-25

2 - Empirical crystal fields
pp 26-42

3 - Fitting crystal field parameters
pp 43-64

4 - Lanthanide and actinide optical spectra
pp 65-82

5 - Superposition model
pp 83-119

6 - Effects of electron correlation on crystal field splittings
pp 120-139

7 - Ground state splittings in S-state ions
pp 140-159

8 - Invariants and moments
pp 160-175

9 - Semiclassical model
pp 176-189

10 - Transition intensities
pp 190-226

Appendix 1 - Point symmetry
pp 227-238

Appendix 2 - QBASIC programs
pp 239-253

Appendix 3 - Accessible program packages
pp 254-258

Appendix 4 - Computer package CST
pp 259-268

Bibliography
pp 269-286

Index
pp 287-290

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Crystal Field Handbook

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