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8 - MASS SPECTROMETRY

Published online by Cambridge University Press:  03 May 2010

A. M. Pollard
Affiliation:
University of Oxford
C. M Batt
Affiliation:
University of Bradford
B. Stern
Affiliation:
University of Bradford
S. M. M. Young
Affiliation:
Tufts University, Massachusetts
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Summary

Mass spectrometry is perhaps the ultimate analytical tool – it involves counting the individual ions, and thus it is the most sensitive detection system possible. After an introduction to the basic components of a mass spectrometer (ion source, separation device for charged ions, and ion detector), we review the various types of spectrometer (single focusing, double focusing, quadrupole). We then introduce the systematics relevant to the study of light isotopes (hydrogen, carbon, nitrogen), and outline the role that these isotopes now play in environmental research. Our attention then turns to the quite different systematics relevant to heavy isotope research (lead and strontium). Highlighted applications of isotope archaeology include palaeodietary research from light stable isotopes on human bones and teeth, “provenancing” humans from light stable isotopes and also heavy isotopes in bone and teeth, and the use of lead isotopes to track the circulation of metal artifacts. There are several excellent texts of isotopes in geochemistry and the environmental sciences, including Faure (1986) and Hoefs (1997).

Separation of ions by electric and magnetic fields

Mass spectrometry in chemistry is widely used as a tool for organic structural analysis, where precise measurement of the mass of the sample and of its fragmentation products is of prime importance. In many ways, however, mass spectrometry is also the ultimate tool as a detector for a wide range of techniques of inorganic chemical analysis, since it allows the counting of individual ions, giving what should be the best possible analytical sensitivity.

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Chapter
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Publisher: Cambridge University Press
Print publication year: 2007

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  • MASS SPECTROMETRY
  • A. M. Pollard, University of Oxford, C. M Batt, University of Bradford, B. Stern, University of Bradford, S. M. M. Young, Tufts University, Massachusetts
  • Book: Analytical Chemistry in Archaeology
  • Online publication: 03 May 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511607431.009
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  • MASS SPECTROMETRY
  • A. M. Pollard, University of Oxford, C. M Batt, University of Bradford, B. Stern, University of Bradford, S. M. M. Young, Tufts University, Massachusetts
  • Book: Analytical Chemistry in Archaeology
  • Online publication: 03 May 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511607431.009
Available formats
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Save book to Google Drive

To save content items to your account, please confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your account. Find out more about saving content to Google Drive.

  • MASS SPECTROMETRY
  • A. M. Pollard, University of Oxford, C. M Batt, University of Bradford, B. Stern, University of Bradford, S. M. M. Young, Tufts University, Massachusetts
  • Book: Analytical Chemistry in Archaeology
  • Online publication: 03 May 2010
  • Chapter DOI: https://doi.org/10.1017/CBO9780511607431.009
Available formats
×