7 - Quantum size effects in small metal particles

Summary

Small metal particles

General properties

Small clusters of atoms of metallic elements have very unusual physical properties. These objects are not as small as molecules and some of their properties are reminiscent of those of bulk metals. At the same time the electron spectrum is discrete and this has many intriguing consequences. Systems of small metal particles are under very intensive study, and some of their characteristics have various technical applications. However, the physical properties of the metal clusters are no less interesting than possible applications because to describe them one needs modern quantum statistical theories analogous to those developed in nuclear physics. Moreover, some approaches invented studying the metal particles have their applications in nuclear physics and problems of quantum chaos. A complete account of experimental and theoretical results can be found in the review by Halperin (1986). An impression of the state of the art of both the experimental and the theoretical work can be gained from the proceedings of the Fourth International Meeting on Small Particles and Inorganic Clusters (Chapon, Gillet, and Henry (1989)). Some aspects of small particle physics are considered in recent reviews by Staveren, Brom, and de Jongh (1991) and Nagaev (1992).

Following the main idea of this book in this section I want to discuss several important steps in the theoretical understanding of the systems of small metal particles; then in the following sections of this chapter I present results obtained by the supersymmetry technique.