5 - Element transport

Summary

The theory of element transport is a way of representing the spatial changes in geochemical properties in various contexts, such as movement in the ocean or mantle, the migration of geological fluids or magmatic liquids within a rock matrix, or the attainment of chemical and isotopic equilibrium among minerals within the same rock, etc. It is, in fact, a set of rather complex theories involving some heavy-going mathematics, which we can only touch lightly upon in this book.

The essential concepts forming the core of this theory are those of conservation, flux, sources, and sinks. A conservative property is additive and can only be altered by addition or subtraction at the system boundaries or by the presence of sources and sinks. Mass or number of moles are conservative properties; concentration is not: if a mole of salt is added to a solution already containing one mole, the resulting solution will contain two moles, regardless of how the salt is added. In contrast, two solutions of one mole per liter combine to form two liters of a solution at one mole per liter. A flux is a quantity of something (mass, moles, energy, etc.) crossing a unit surface per unit time. The most familiar of these fluxes is volume flow, which is quite simply the velocity υ(in cubic meters per square meter per second).