Book contents
- Frontmatter
- Contents
- Preface to the First Edition
- Preface to the Second Edition
- 1 The geometry of the crystalline state
- 2 The scattering of X-rays
- 3 Diffraction from a crystal
- 4 The Fourier transform
- 5 Experimental collection of diffraction data
- 6 The factors affecting X-ray intensities
- 7 The determination of space groups
- 8 The determination of crystal structures
- 9 Accuracy and refinement processes
- Physical constants and tables
- Appendices
- Solutions to Problems
- References
- Bibliography
- Index
1 - The geometry of the crystalline state
Published online by Cambridge University Press: 11 January 2010
- Frontmatter
- Contents
- Preface to the First Edition
- Preface to the Second Edition
- 1 The geometry of the crystalline state
- 2 The scattering of X-rays
- 3 Diffraction from a crystal
- 4 The Fourier transform
- 5 Experimental collection of diffraction data
- 6 The factors affecting X-ray intensities
- 7 The determination of space groups
- 8 The determination of crystal structures
- 9 Accuracy and refinement processes
- Physical constants and tables
- Appendices
- Solutions to Problems
- References
- Bibliography
- Index
Summary
The general features of crystals
Materials in the crystalline state are commonplace and they play an important part in everyday life. The household chemicals salt, sugar and washing soda; the industrial materials, corundum and germanium; and the precious stones, diamonds and emeralds, are all examples of such materials.
A superficial examination of crystals reveals many of their interesting characteristics. The most obvious feature is the presence of facets and well-formed crystals are found to be completely bounded by flat surfaces – flat to a degree of precision capable of giving high-quality plane-mirror images. Planarity of this perfection is not common in nature. It may be seen in the surface of a still liquid but we could scarcely envisage that gravitation is instrumental in moulding flat crystal faces simultaneously in a variety of directions.
It can easily be verified that the significance of planar surfaces is not confined to the exterior morphology but is also inherent in the interior structure of a crystal. Crystals frequently cleave along preferred directions and, even when a crystal is crudely fractured, it can be seen through a microscope that the apparently rough, broken region is actually a myriad of small plane surfaces.
Another feature which may be readily observed is that the crystals of a given material tend to be alike – all needles or all plates for example – which implies that the chemical nature of the material plays an important role in determining the crystal habit.
- Type
- Chapter
- Information
- An Introduction to X-ray Crystallography , pp. 1 - 31Publisher: Cambridge University PressPrint publication year: 1997