To characterize the evolution of dioctahedral interstratified clay minerals in the Golden Cross epithermal deposit, New Zealand, hydrothermally altered volcanic rocks containing the sequence smectite through illite-smectite (I-S) to muscovite were examined by optical microscopy, X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission and analytical electron microscopies (TEM/AEM).

XRD analyses of 30 oriented clay samples show a broad deposit-wide trend of increasing illite content in I-S with increasing depth and proximity to the central vein system. Six representative samples were selected for SEM/TEM study on the basis of petrographic observations and XRD estimates of I-S interstratification. Ca and Na are the dominant interlayer cations in smectite, but as the proportion of illite layers in I-S increases, so does the K content and (IVAl + VIAl)/Si ratio. Layers and packets tend to flatten and form larger arrays, reducing the amount of pore space. Smectite coexists with (R = 1) I-S, rather than being (R = 0) I-S where R is the Reichweite parameter. The highest alteration rank samples contain discrete packets of mica to ∼300 Å thick, but a limited chemical and structural gap exists between illite, which is intermediate in composition between common illite and muscovite, and illite-rich I-S. Selected-area electron diffraction (SAED) patterns of mica show that the 1M polytype dominates, rather than the common 2M1 polytype.

Petrographic, SEM, and TEM data imply that all phyllosilicates formed via neoformation directly from fluids. Relatively mature I-S and micas form simultaneously, without progressing through the series of transformations that are commonly assumed to characterize diagenetic sequences during burial metamorphism in mud-dominated basins. Although the overall distribution of clay minerals is consistent with temperature as a controlling variable, local heterogeneities in the distribution of clay minerals were controlled by water/rock ratio, which varied widely owing to different rock types and fracture control.

The interaction of the Palaeo-Pacific and Palaeo-Asian Oceans is an enigmatic issue as their temporal and spatial features are controversial. To address this issue, we present a systematic study of large volumes of early Permian volcanic rocks and intrusions developed in the East Tianshan. The represented samples of basaltic andesites and rhyolites yield zircon crystallization ages of 285.1 ± 5.9 Ma and 275.3 ± 1.8 Ma, respectively. The basalts have normal mid-ocean ridge basalt (N-MORB) and arc-related geochemical signatures with high TiO2 contents, negative Rb, Th, U, Nb and Ta anomalies and positive Eu anomalies. Basaltic andesites and andesites have arc-related geochemical characteristics with moderate TiO2 contents and relatively negative Nb, Ta and Ti anomalies, together with slightly negative to positive Eu anomalies. The rhyolites show an affinity with A2-type granite with high SiO2, K2O + Na2O, Fe/Mg, Ga, Zr, Nb, Y, HFSE, REE and Y/Nb levels (>1.2). These geochemical data suggest that the rocks formed in a supra-subduction zone. The presence of high ϵNd(t) values of +4.6 to +8.2 and low (87Sr/86Sr)i (0.70342–0.70591) values indicates that the volcanic rocks originated from a depleted mantle. We propose that oblique subduction with slabs breaking off gave rise to transtension and to the emplacement of large volumes of mantle-derived melts in the early Permian in the East Tianshan, serving as an important record of the subduction zone of the Palaeo-Pacific Ocean.

The Tertiary basin of Feres consists of sedimentary rocks, andesitic-rhyolitic volcanic rocks of K-rich calc-alkaline affinities, rocks with calc-alkaline and shoshonitic affinities and volcaniclastic fall and flow deposits. Volcanic and volcaniclastic rocks have variable concentrations of LIL elements (Ba, Sr, Rb, Th) and HFS elements (Zr, V) due to their mode of origin. The pyroclastic flows frequently show more or less intense devitrification, vapour-phase crystallization and, in some cases, evidence of fumarolic activity, as is indicated by the presence of scapolite. The volcanic and volcaniclastic rocks display various types of alteration including formation of zeolites (clinoptilolite, heulandite, mordenite, and laumontite) and smectite, as well as hydrothermal alteration (development of silicic, argillic, sericitic and propylitic zones) associated with polymetallic mineralization. The behaviour of chemical elements during alteration varies. Some are immobile and their distribution is controlled by the conditions prevailing during parent-rock formation and emplacement, but others, such as Ba and Sr, are mobile and selectively fractionate in zeolite extra-framework sites. The formation of zeolite from alteration of volcanic glass is accompanied by an increase in Mg and Al content, and a decrease in Si and Na content, whereas Ca is not affected by alteration. In certain pyroclastic flows, there is a significant difference in K-content between incipient glass and altered rock, due to K-feldspar formation during devitrification and vapour-phase crystallization.

In the Ordovician Snowdon Volcanic Group caldera quartz-magnetite-hematite-pyrite assemblages occur in a breccia vein in rhyolitic tuff and vein swarms in basalt. The veins developed pre-cleavage. Elevated levels of tin and tungsten in the veins, and of fluorine in the wall rocks, suggest a magmatic contribution to the mineralising fluids. The chemistry of the veins differs from that of the base-metal sulphide veins found elsewhere in the caldera.

The volcanic rocks of the Şarkışla area in northeastern central Anatolia are associated with volcaniclastics, turbiditic limestones and pelagic-hemipelagic shales of Upper Cretaceous-Palaeocene age. A preliminary geochemical study was undertaken to constrain local tectonic models, and due to the variable altered nature of the volcanics, determine the lithological composition and magma type. Chemically the volcanics are an andesite-dominated suite of calc-alkali lavas, probably developed adjacent to an active continental margin in a local (ensialic back-arc?) basinal area. The volcanic activity was probably related to a postulated magmatic arc just south of the area during the early Tertiary.

Dacitic andesitic calc-alkaline lavas and their pyroclastic rocks of Upper Cretaceous age are widespread in the Ordu area, eastern Black Sea Coast of Turkey. Ca-bentonite and Ca/Nabentonite deposits with significant economic potential formed in the broader region. The mineralogy and geochemistry of these deposits were studied by X-ray diffraction (XRD), scanning electron microscopy (SEM) and chemical analyses. The parent rocks (PR) and bentonite samples were analysed for the major and trace element contents, including rare-earth elements, to understand the effect of differential alterations on element mobility. The bentonites contain mainly di-octahedral Ca-montmorillonite with minor amounts of illite, quartz, calcite, dolomite and feldspar. Primary K-feldspar and plagioclase phenocrysts were altered in the bentonite horizons, and were completely leached at greater depth. For this reason, the higher quality bentonites are found at deeper zones. Bentonite horizons are characterized by relatively high loss on ignition (LOI: 9.8–20.8%) and MgO content (3–5%) and low K2O (<0.5%) and Na2O (<2%) contents compared with the least altered parent rocks. Silicon, Ca, Mg, Mn and P are markedly enriched whereas Fe, Na, K and Ti are depleted in the bentonite samples. The chondrite-normalized rare earth element (REE) patterns show identical trends characterized by strong light rare earth element (LREE) enrichment in both the PR and bentonite samples. The LREE contents are higher than those of their heavy counterparts (HREE) in the samples. Alteration of the PR to bentonite is associated with intense chemical leaching and subsequent removal of K and Na in open-system conditions.

K–Ar and 40Ar/39Ar ages have been measured on nine mafic volcanic rocks younger than 1 myr from the Snake River Plain (Idaho), Mount Adams (Washington), and Crater Lake (Oregon). The K–Ar ages were calculated from Ar measurements made by isotope dilution and K2O measurements by flame photometry. The 40Ar/39Ar ages are incremental-heating experiments using a low-blank resistance-heated furnace. The results indicate that high-quality ages can be measured on young, mafic volcanic rocks using either the K–Ar or the 40Ar/39Ar technique. The precision of an 40Ar/39Ar plateau age generally is better than the precision of a K–Ar age because the plateau age is calculated by pooling the ages of several gas increments. The precision of a plateau age generally is better than the precision of an isotope correlation (isochron) age for the same sample. For one sample the intercept of the isochron yielded an 40Ar/36Ar value significantly different from the atmospheric value of 295.5. Recalculation of increment ages using the isochron intercept for the composition of nonradiogenic Ar in the sample resulted in much better agreement of ages for this sample. The results of this study also indicate that, given suitable material and modern equipment, precise K–Ar and 40Ar/39Ar ages can be measured on volcanic rocks as young as the latest Pleistocene, and perhaps even the Holocene.

Little Cumbrae and south Bute are the closest outliers of Early Carboniferous Clyde Plateau volcanic rocks to those forming the plateau itself, and the only ones with the potential to reveal how the volcanic succession of the plateau becomes attenuated westward beneath the Firth of Clyde. Closest links are to the Renfrewshire Hills Block of the plateau proper, where the Clyde Plateau Volcanic Formation attains its greatest thickness and widest extent.

Basal lavas in both outliers can be correlated to the lower part of the Strathgryfe Member of the Clyde Plateau Volcanic Formation (Viséan, Holkerian), which rests disconformably on the Clyde Sandstone Formation (Tournaisian, Chadian). Relative to the Renfrewshire Hills Block, this implies intervening overlap of three older members of the Clyde Plateau Formation and overstep of a varied sedimentary foundation. Higher lavas and pyroclastic accumulations in south Bute are correlative to the Misty Law Trachytic Member and upper part of the Strathgryfe Member. Thin lavas that cap the Renfrewshire Hills Block on its eastern flank probably never accumulated as far west as the present Firth of Clyde.

Southwestward from the Renfrewshire Hills, the Clyde Plateau lavas lose about two thirds of their 1000-m thickness in 25–30 km – a rate of thinning that implies they may extend no farther than the Sound of Bute or northeastern Arran.

An alteration zone at the base of a Carboniferous lava flow on the island of Bute resembles modern and ancient weathering profiles, but it is ‘upside down’ in the sense that alteration is most intense at the base and decreases upwards. Values for a Chemical Index of Alteration (CIA) increase from fresh lava and corestones downwards to fine-grained structureless material. The altered material is Mg- and Cu-rich, possibly as a result of migration of these elements from underlying sediments. Rare earth elements (REE) display considerable and systematic mobility and fractionation. In general heavy rare earth elements (HREE) are concentrated during alteration, whereas the light rare earth elements (LREE) are lost. Mobility of the REE appears to be related to atomic weight, with La (the lightest REE) being the most depleted through to Lu, which is the most concentrated REE in the highly altered material. Similar systematic fractionation is shown by some weathering profiles developed on mafic igneous rocks. Movement of water into the volcanic rocks was probably driven by a steep thermal gradient between the hot lava and its sedimentary substrate.

Middle Neoproterozoic igneous rocks are widespread in South China, but their petrogenesis and tectonic implications are still highly controversial. The Guangfeng middle Neoproterozoic volcano-sedimentary succession was developed on a rare Sibaoan metamorphic basement (the Tianli Schists) in the southeastern Yangtze Block, South China. This paper reports geochronological, geochemical and Nd isotopic data for the volcanic rocks in this succession. The volcanic rocks consist of alkaline basalts, andesites and peraluminous rhyolites. SHRIMP U–Pb zircon age determinations indicate that they were erupted at 827±14 Ma, coeval with a widespread episode of anorogenic magmatism in South China. Despite showing Nb–Ta depletion relative to La and Th, the alkaline basalts are characterized by highly positive ɛNd(T) values (+3.1 to +6.0), relatively high TiO2 and Nb contents and high Zr/Y and super-chondritic Nb/Ta ratios, suggesting their derivation from a slab melt-metasomatized subcontinental lithospheric mantle source in an intracontinental rifting setting. The andesites have significantly negative ɛNd(T) values (−9.3 to −11.1) and a wide range of SiO2 contents (57.6–65.6%). They were likely generated by the mixing of fractionated basaltic melts with felsic melts derived from the Archaean metasedimentary rocks in the middle to lower crust. The rhyolites are highly siliceous and peraluminous. They are characterized by depletion in Nb, Ta, Sr, P and Ti and relatively high ɛNd(T) values (−3.0 to −4.8), broadly similar to those of the adjacent c. 820 Ma peraluminous granitoids derived from the Mesoproterozoic to earliest Neoproterozoic sedimentary source at relatively shallow levels. We conclude that the Guangfeng volcanic suite is a magmatic response of variant levels of continental lithosphere (including lithospheric mantle and the lower-middle to upper crust) to the middle Neoproterozoic intracontinental rifting possibly caused by mantle plume activity.

Size distribution data obtained from detailed field study of bubbles and amethyst-geodes in the basaltic lava flows of the Serra Geral Formation (Ametista do Sul, Rio Grande do Sul, Brazil) are used in cooling and vesiculation models to infer the origin and the formation processes of the geodic cavities. Coupled field observations and modelling results emphasize that (1) the formation of geodes in the studied lava flow can be explained, qualitatively and quantitatively, by the exsolution of magmatic gas from the supersaturated melt with no need for external surface water supply; (2) the vertically elongated habits of the geodes result from higher cooling rate of the magma in contact with the accumulating bubbles; and (3) the abnormal metre-sized geodes with their branching habits result not only from the diffusive/decompressive bubble growth but also from the coalescence of inwards-progressing tubular cavities.

Fisher Massif consists of Mesoproterozoic (c. 1300 Ma) lower amphibolite-facies metavolcanic rocks and associated metasediments, intruded by a variety of subvolcanic and plutonic bodies (gabbro to granite). It differs in both composition and metamorphic grade from the rest of the northern Prince Charles Mountains, which were metamorphosed to granulite facies about 1000 m.y. ago. The metavolcanic rocks consist mainly of basalt, but basaltic andesite, andesite, and more felsic rocks (dacite, rhyodacite, and rhyolite) are also common. Most of the basaltic rocks have compositions similar to low-K island arc tholeiites, but some are relatively Nb-rich and more akin to P-MORB. Intermediate to felsic medium to high-K volcanic rocks, which appear to postdate the basaltic succession, have calc-alkaline affinities and probably include a significant crustal component. On the present data, an active continental margin with associated island arc was the most likely tectonic setting for generation of the Fisher Massif volcanic rocks.

Mount Willing in the Prince Charles Mountains (East Antarctica) is part of the Fisher Volcano–plutonic complex which formed as part of the global-scale Grenvillian mobile belt system. Mount Willing is composed of four rock complexes: 1) a metamorphic sequence, 2) gabbro intrusions, 3) deformed felsic intrusives, and 4) abundant post-metamorphic dykes and veins. Three rock types constitute the metamorphic sequence: amphibole–biotite felsic plagiogneiss, mafic to intermediate biotite–amphibole schist, and biotite paragneiss. The bulk composition of the mafic schists classifies them as tholeiitic basalts, and rarely as basaltic andesites or andesites. Index mg ranges widely from 47 to 71. Concentrations of TiO2, P2O5, and high-field strength elements are high in some rocks. These rocks are thought to have been derived from enriched (subcontinental) mantle sources. Sm–Nd and U–Pb isotopic data indicate a series of Mesoproterozoic thermal events between 1100 and 1300 Ma. In particular, these events occurred at 1289 ± 10 Ma (volcanic activity), at 1177 ± 16 Ma (tonalite intrusion), at 1112.7 ± 2.4 and at 1009 ± 54 Ma (amphibolite facies metamorphic events). Rb–Sr systematics also indicates a thermal overprint at 636 ± 13 Ma. Mafic schists show low initial 877Sr/86Sr ratios between 0.7024 and 0.7030. Felsic rocks show higher Sri values between 0.7037 and 0.7061. Basaltic andesite metavolcanic and plutonic rocks form a calc-alkaline evolutionary trend, and probably originated from subduction-modified mantle sources in a convergent plate margin environment. An oceanic basin may have existed in central Prince Charles Mountains about 1300 Ma ago and was closed as a result of continental collision around 1000 to 800 Ma.

Ordovician metamorphic rocks of the Casco Bay Group are exposed in an approximately 170 km long NE-trending belt (Liberty-Orrington belt) in southern and south-central Maine. Geochemical analysis of rocks within the Spring Point Formation (469±3 Ma) of the Casco Bay Group indicate that it is an assemblage of metamorphosed bimodal volcanic rocks. The mafic rocks (originally basalts) have trace element and Nd isotopic characteristics consistent with derivation from a mantle source enriched by a crustal and/or subduction component. The felsic rocks (originally rhyolites and dacites) were likely generated through partial melting of continental crust in response to intrusion of the mafic magma. Relatively low initial εNd values for both the mafic (−1.3 to +0.6) and felsic (−4.1 to −3.8) rocks suggest interactions with Gander zone continental crust and support a correlation between the Casco Bay Group and the Bathurst Supergroup in the Miramichi belt of New Brunswick. This correlation suggests that elements of the Early to Middle Ordovician Tetagouche-Exploits back-arc basin can be traced well into southern Maine. A possible tectonic model for the evolution of the Casco Bay Group involves the initiation of arc volcanism in Early Ordovician time along the Gander continental margin on the eastern side of the Iapetus Ocean basin. Slab rollback and trenchward migration of arc magmatism initiated crustal thinning and rifting of the volcanic arc around 470 Ma and resulted in the eruption of the Spring Point volcanic rocks in a back-arc tectonic setting.