We consider a system of degenerate parabolic equations modelling a thin film, consisting of two layers of immiscible Newtonian liquids, ona solid horizontal substrate. In addition, the model includes the presence of insoluble surfactants onboth the free liquid-liquid and liquid-air interfaces,and the presence of both attractive and repulsive van der Waals forcesin terms of the heights of the two layers. We show that this system formally satisfies a Lyapunov structure,and a second energy inequality controlling the Laplacianof the liquid heights.We introduce a fully practical finite element approximation of this nonlinear degenerate parabolic system, that satisfies discrete analoguesof these energy inequalities. Finally, we prove convergence of this approximation,and hence existence of a solutionto this nonlinear degenerate parabolic system.