We study, under mild conditions, the weak approximation constructed from a standard Poisson process for a class of Gaussian processes, and establish its sample path moderate deviations. The techniques consist of a good asymptotic exponential approximation in moderate deviations, the Besov–Lèvy modulus embedding, and an exponential martingale technique. Moreover, our results are applied to the weak approximations associated with the moving average of Brownian motion, fractional Brownian motion, and an Ornstein–Uhlenbeck process.