The complementary radio navigation system based on the Very Low Frequency signals produced by lightning is an alternative to today's Global Navigation Satellite Systems. The system operates on different principles and uses different radio frequency bands. The signals have higher availability in problematic places. The analyses based on the historical data of Word Wide Lightning Location Network demonstrated the good availability of the service, sufficient number of lightning strokes and good geometry calculated for a 10-second time window for positioning based on the Time of Arrival principle. The geometry was evaluated with the help of the Geometric Dilution of Precision coefficient. The Geometric Dilution of Precision median for the reception of the lightning signal from a range of 10,000 km moves around one except at the southern polar regions and the probability of the service availability exceeds 80%.