Old stellar populations in our Galaxy provide fossil records of the metal enrichment in the first few billion years of the cosmic history. Growing elemental abundance data of individual stars combined with stellar ages and kinematics allow us to make constraints on characteristic properties of the metal-enrichment sources in the early Universe, such as the first stars. In order to interpret observed chemical abundances in the oldest stellar populations in terms of metal-enrichment sources, stellar and supernova yield models are crucial. In this article, we review how we can interpret observed chemical abundances in old stars in terms of the nature of metal enrichment sources. We discuss the limitations and the prospects of empirically constraining supernova yield models based on a large sample of extremely metal-poor stars. At the same time, we emphasize the importance of hunting old stars beyond the Solar neighborhood, which can be achieved with the next-generation multi-object spectrographs at large telescopes.

Radial Velocity Experiment (RAVE) observed ~500,000 southern sky stars between 2003 and 2013 in the infra-red calcium triplet (CaII) spectral region. In this study we extended the analysis of RAVE very metal-poor stars ([Fe/H] < −2) presented by Fulbright et al. (2010). We employed a novel method for identifying the metal-poor stars and developed a tool for modeling CaII lines where we also modeled the background noise to avoid systematical biases in the equivalent width (EW) measurements. Final metallicity values were derived with a flexible calibration approach using only 2MASS photometric data and EW measurements obtained from the RAVE spectra.

Very few abundance analyses of individual stars in metal-poor globular clusters in the galactic bulge are available. The main purpose of this study is to derive abundances in individual stars of such clusters, in order to establish their abundance pattern, trying to characterize the oldest bulge stellar populations.

The abundance derivation of heavy r-elements may provide a better understanding of the r-process, and the determination of several reference r-elements should allow a better determination of the star's age. The spatial ultraviolet (UV) region presents a large number of lines of heavy elements, and in some cases such as Bi, Pt, Au, detectable lines are only available in the UV. The extreme “r-process star” CS 31082-001 ([Fe/H] = −2.9) was observed in the spatial UV in order to determine abundances of the heavy elements, using STIS on board HST.

The chemical abundances of the very metal poor double-enhanced stars are excellent information to set new constraints on models of neutron-capture processes at low metallicity. There have been many theoretical studies of s-process nucleosynthesis in low-mass AGB stars. Using the parametric approach based on the radiative s-process nucleosynthesis model, we calculate the following five parameters for a series of metal-poor stars. They are: the mass fraction of 13C pocket q, the overlap factor r, the neutron exposure per interpulse Δτ, and the component coefficients that correspond to relative contribution from the s-process and the r-process. We find that the mass fraction of 13C pocket q deduced for the Pb stars is comparable to the overlap factor r, which is about 10 times larger than normal AGB model; q ~ 0.05; and the neutron exposure per interpulse Δτ for all Pb stars are about 10 times smaller than the ST case (Δτ ~ 7.0mb−1). Although the two fundamental parameters Δτ and q obtained for the Pb stars are very different from the AGB stellar model, the results of the larger value of q and the smaller value of Δτ can also explain the abundance distribution of the Pb stars. This suggest that the q change to larger than that of normal AGB model. Then, this factor will result in the descent of the density of 13C in the nuclear synthesis region directly. So, the neutron exposure Δτ will also decrease to the same extent. Although the neutron number density in the larger initial mass AGB stars (m > 3M⊙) is high, the neutron irradiation time is shorter, obviously the neutron exposure per interpulse in the AGB stars should be smaller. It is noteworthy that the total amount of 13C in metal poor condition is close to the ST case, which is consistent with the primary nature of the neutron source.