An application of radiocarbon (14C) in atmospheric chemistry is reviewed. 14C produced by cosmic neutrons immediately forms 14CO, which reacts with hydroxyl radicals (OH) to 14CO2. By this the distribution and seasonality (the lifetime of 14CO is ∼1 month) of the pivotal atmospheric oxidant OH can be established. 14CO measurement is a complex but unique application which benefitted enormously from the realization of AMS, bearing in mind that 14CO abundance is of the order of merely 10 molecules per cm3 not only provides 14CO an independent measure for the OH based self-cleansing capacity of the troposphere, but also enabled detection of 14C production due to high energy solar protons in 1989. Although its production takes place throughout the atmosphere and does not have the character of a point source, transport processes in the atmosphere affect the distribution of 14CO. Vertical mixing in the troposphere renders gradients in its production rate less critical, but considerable meridional gradients exist. One question has remained open, namely confirmation of calculated 14C production by direct measurement. A new sampling method is proposed. The conclusions are a guide to future work on 14CO in relation to OH and atmospheric transport.

Postglacial emergence curves are used to infer mantle rheology, delimit ice extent, and test models of the solid Earth response to changing ice and water loads. Such curves are rarely produced by direct dating of land emergence; rather, most rely on the presence of radiocarbon-datable organic material and inferences made between the age of sedimentary deposits and landforms indicative of former sea level. Here, we demonstrate a new approach, 10Be dating, to determine rates of postglacial land emergence in two different settings. In southern Greenland (Narsarsuaq/Igaliku), we date directly the exposure, as relative sea level fell, of gravel beaches and rocky outcrops allowing determination of rapid, post–Younger Dryas emergence. In western Greenland (Kangerlussuaq), we constrain Holocene isostatic response by dating the sequential stripping of terrace sediment driven by land-surface uplift, relative sea-level fall, and resulting fluvial incision. The technique we employ provides high temporal and elevation resolution important for quantifying rapid emergence immediately after deglaciation and less rapid uplift during the middle Holocene. 10Be-constrained emergence curves can improve knowledge of relative sea-level change by dating land emergence along rocky coasts, at elevations and locations where radiocarbon-datable sediments are not present, and without the lag time needed for organic material to accumulate.

The presence of glacial sediments across the Rauer Group indicates that the East Antarctic ice sheet formerly covered the entire archipelago and has since retreated at least 15 km from its maximum extent. The degree of weathering of these glacial sediments suggests that ice retreat from this maximum position occurred sometime during the latter half of the last glacial cycle. Following this phase of retreat, the ice sheet margin has not expanded more than ∼ 1 km seaward of its present position. This pattern of ice sheet change matches that recorded in Vestfold Hills, providing further evidence that the diminutive Marine Isotope Stage 2 ice sheet advance in the nearby Larsemann Hills may have been influenced by local factors rather than a regional ice-sheet response to climate and sea-level change.

The statistical distributions of cosmogenic nuclide measurements from moraine boulders contain previously unused information on moraine ages, and they help determine whether moraine degradation or inheritance is more important on individual moraines. Here, we present a method for extracting this information by fitting geomorphic process models to observed exposure ages from single moraines. We also apply this method to 94 10Be apparent exposure ages from 11 moraines reported in four published studies. Our models represent 10Be accumulation in boulders that are exhumed over time by slope processes (moraine degradation), and the delivery of boulders with preexisting 10Be inventories to moraines (inheritance). For now, we neglect boulder erosion and snow cover, which are likely second-order processes. Given a highly scattered data set, we establish which model yields the better fit to the data, and estimate the age of the moraine from the better model fit. The process represented by the better-fitting model is probably responsible for most of the scatter among the apparent ages. Our methods should help resolve controversies in exposure dating; we reexamine the conclusions from two published studies based on our model fits.

Cosmogenic 10Be and 26Al measurements from bedrock exposures in East Antarctica provide indications of how long the rock surface has been free from glacial cover. Samples from the crests of Zakharoff Ridge and Mount Harding, two typical nunataks in the Grove Mountains, show minimum 10Be ages of 2.00 ± 0.22 and 2.30 ± 0.26 Ma, respectively. These ages suggest that the crests were above the ice sheet at least since the Plio–Pleistocene boundary. Adopting a ‘reasonable’ erosion rate of 5–10 cm Ma-1 increases the exposure ages of these two samples to extend into the mid-Pliocene. The bedrock exposure ages steadily decrease with decreasing elevation on the two nunataks, which indicates ~200 m decrease of the ice sheet in the Grove Mountains since mid-Pliocene time. Seven higher elevation samples exhibit a simple exposure history, which indicates that the ice sheet in the Grove Mountains decreased only ~100 m over a period as long as 1–2 Ma. This suggests that the East Antarctic Ice Sheet (EAIS) was relatively stable during the Pliocene warm interval. Five lower elevation samples suggest a complex exposure history, and indicate that the maximum subsequent increase of the EAIS was only 100 m higher than the present ice surface. Considering the uncertainties, their total initial exposure and subsequent burial time could be later than mid-Pliocene, which may not conflict with the stable mid-Pliocene scenario.