Post-asymptotic giant branch stars (post-AGB) in binary systems, with typical orbital periods between $\sim\!100$ to $\sim$1 000 days, result from a poorly understood interaction that terminates their precursory AGB phase. The majority of these binaries display a photospheric anomaly called ‘chemical depletion’, thought to arise from an interaction between the circumbinary disc and the post-AGB star, leading to the reaccretion of pure gas onto the star, devoid of refractory elements due to dust formation. In this paper, we focus on a subset of chemically peculiar binary post-AGBs in the Galaxy and the Magellanic Clouds (MCs). Our detailed stellar parameter and chemical abundance analysis utilising high-resolution optical spectra from VLT+UVES revealed that our targets span a $T_{\rm eff}$ of 4 900–7 250 K and [Fe/H] of −0.5 - −1.57 dex. Interestingly, these targets exhibit a carbon ([C/Fe] ranging from 0.5 - 1.0 dex, dependant on metallicity) and s-process enrichment ($\textrm{[s/Fe]}\,\geq\!1$dex) contrary to the commonly observed chemical depletion pattern. Using spectral energy distribution (SED) fitting and period–luminosity–colour (PLC) relation methods, we determine the luminosity of the targets (2 700–8 300 $\rm L_{\odot}$), which enables confirmation of their evolutionary phase and estimation of initial masses (as a function of metallicity) (1–2.5 $\textrm{M}_{\odot}$). In conjunction with predictions from dedicated ATON stellar evolutionary models, our results indicate a predominant intrinsic enrichment of carbon and s-process elements in our binary post-AGB targets. We qualitatively rule out extrinsic enrichment and inherited s-process enrichment from the host galaxy as plausible explanations for the observed overabundances. Our chemically peculiar subset of intrinsic carbon and s-process enriched binary post-AGBs also hints at potential variation in the efficiency of chemical depletion between stars with C-rich and O-rich circumbinary disc chemistries. However, critical observational studies of circumbinary disc chemistry, along with specific condensation temperature estimates in C-rich environments, are necessary to address gaps in our current understanding of disc-binary interactions inducing chemical depletion in binary post-AGB systems.

The mobility of lighter species on the surface of interstellar dust grains plays a crucial role in forming simple through complex molecules. Carbon monoxide is one of the most abundant molecules, its surface diffusion on the grain surface is essential to forming many molecules. Recent laboratory experiments found a diverse range of diffusion barriers for CO on the grain surface, their use can significantly impact the abundance of several molecules. The impact of different diffusion barriers of CO, in the astrochemical models, is studied to understand its effect on the abundance of solid CO and the species for which it is a reactant partner. A gas-grain network is used for three different physical conditions; cold core and warm-up models with slow and fast heating rates. Two different ratios (0.3 and 0.5) between diffusion and desorption barrier are utilised for all the species. For each physical condition and ratio, six different models are run by varying diffusion barriers of CO. Solid CO abundance for the models with the lowest diffusion barrier yields less than 0.1% of water ice for cold clouds and a maximum of 0.4% for slow and fast warm-up models. Also, solid $\textrm{CO}_2$ in dense clouds is significantly overproduced ( ${\sim}140\%$ of water). The abundance of H2CO and $\textrm{CH}_3\textrm{OH}$ showed an opposite trend, and HCOOH, $\textrm{CH}_3\textrm{CHO}$ , $\textrm{NH}_2\textrm{CO}$ , and $\textrm{CH}_3\textrm{COCH}_3$ are produced in lower quantities for models with low diffusion barriers for CO. Considerable variation in abundance is observed between models with the high and low diffusion barrier. Models with higher diffusion barriers provide a relatively better agreement with the observed abundances when compared with the models having lower diffusion barriers.

The cosmic origin of fluorine is still under debate. Asymptotic giant branch (AGB) stars are among the few suggested candidates to efficiently synthesis F in our Galaxy, however their relative contribution is not clear. In this paper, we briefly review the theoretical studies from stellar yield models of the F synthesis and chemical equilibrium models of the F-containing molecules in the outflow around AGB stars. Previous detections of the F-bearing species towards AGB and post-AGB stars are also highlighted. We suggest that high-resolution ALMA observations of the AlF, one of the two main carriers of F in the outflow of AGB stars, can provide a reliable tracer of the F-budget in AGB stars. This will be helpful to quantify the role of AGB stars in the Galactic F budget.

On August 17, 2017, the LIGO/VIRGO collaboration detected the first gravitational wave signal coming from the merger of two neutron stars. This groundbreaking discovery, referred to as GW170817, revealed to us how heavy elements, such as gold and platinum, are synthesized through a mechanism known as rapid neutron capture (r-process). In order to fully understand these signals, we need to simulate the resulting accretion disk around a black hole, and its outflows. This task requires efficient computing codes that include general relativity magnetohydrodynamics (GRMHD), neutrino physics, and a model for matter at high densities. We present the implementation of a tabulated equation of state that takes care of matter at high densities and a neutrino leakage scheme that considers the impact of neutrinos into HARM3D, a GRMHD parallelized code. We also apply the tools to a magnetized torus.

Determining the shape of the stellar initial mass function (IMF) and whether it is constant or varies in space and time is the Holy Grail of modern astrophysics, with profound implications for all theories of star and galaxy formation. On a theoretical ground, the extreme conditions for star formation (SF) encountered in the most powerful starbursts in the Universe are expected to favour the formation of massive stars. Direct methods of IMF determination, however, cannot probe such systems, because of the severe dust obscuration affecting their starlight. The next best option is to observe CNO bearing molecules in the interstellar medium at millimetre/ submillimetre wavelengths, which, in principle, provides the best indirect evidence for IMF variations. In this contribution, we present our recent findings on this issue. First, we reassess the roles of different types of stars in the production of CNO isotopes. Then, we calibrate a proprietary chemical evolution code using Milky Way data from the literature, and extend it to discuss extragalactic data. We show that, though significant uncertainties still hamper our knowledge of the evolution of CNO isotopes in galaxies, compelling evidence for an IMF skewed towards high-mass stars can be found for galaxy-wide starbursts. In particular, we analyse a sample of submillimetre galaxies observed by us with the Atacama Large Millimetre Array at the peak of the SF activity of the Universe, for which we measure 13C/18O⋍1. This isotope ratio is especially sensitive to IMF variations, and is little affected by observational uncertainties. At the end, ongoing developments of our work are briefly outlined.

The chemical evolution of the Universe is governed by the nucleosynthesis contribution from stars, which in turn is determined primarily by the initial stellar mass. The heaviest elements are primarily produced through neutron capture nucleosynthesis. Two main neutron capture processes identified are the slow and rapid neutron capture processes (s and r processes, respectively). The sites of the r and s-process are discussed, along with recent progress and their associated uncertainties. This review is mostly focused on the s-process which occurs in low and intermediate-mass stars which have masses up to about 8 solar masses (M⊙). We also discuss the intermediate-neutron capture process (or i-process), which may occur in AGB stars, accreting white dwarfs, and massive stars. The contribution of the i-process to the chemical evolution of elements in galaxies is as yet uncertain.

We explore the circumstellar effects on the Li and Ca abundances determination in a complete sample of massive Galactic AGB stars. The Li abundance is an indicator of the hot bottom burning (HBB) activation, while the total Ca abundance could be affected by overproduction of the short-lived radionuclide 41Ca by the s-process. Li abundances were previously studied with hydrostatic models, while Ca abundances are determined here for the first time. The pseudo-dynamical abundances of Li and Ca are very similar to the hydrostatic ones, indicating that circumstellar effects are almost negligible. The new Li abundances confirm the (super-)Li-rich character of the sample Li-detected stars, supporting the HBB activation in massive Galactic AGB stars. Most sample stars display nearly solar Ca abundances that are consistent with predictions from the s-process nucleosynthesis models. A minority of the sample stars show a significant Ca depletion. Possible reasons for their (unexpected) low Ca content are given.

Using abundances from the available largest, homogeneous sample of high resolution Barium (Ba) star spectra we calculated the ratios of different hs-like to ls-like elemental ratios and compared to different AGB nucleosynthesis models. The Ba star data show an incontestable increase of the hs-type/ls-type element ratio (for example, [Ce/Y]) with decreasing metallicity. This trend in the Ba star observations is predicted by low mass, non-rotating AGB models where 13C is the main neutron source and is in agreement with Kepler asteroseismology observations.

This talk presented and discussed some recent results obtained from a photometric and spectroscopic optical follow-up survey of bright classical novæ. The survey concerned the role of those objects in Galactic chemical evolution, with particular attention to the production of lithium.

Next-generation 21cm observations will enable imaging of reionization on very large scales. These images will contain more astrophysical and cosmological information than the power spectrum, and hence providing an alternative way to constrain the contribution of different reionizing sources populations to cosmic reionization. Using Convolutional Neural Networks, we present a simple network architecture that is sufficient to discriminate between Galaxy-dominated versus AGN-dominated models, even in the presence of simulated noise from different experiments such as the HERA and SKA.

Recently the search for the oldest stars have started to focus on the Bulge region. The Galactic bulge hosts extremely old stars, with ages compatible with the ages of the oldest halo stars. The data coming from these recent observations present new chemical signatures and therefore provide complementary constraints to those already found in the halo. So, the study of the oldest bulge stars can improve dramatically the constraints on the nature of first stars and how they polluted the pristine ISM of our Galaxy. We present our first results regarding the light elements (CNO) and the neutron capture elements. Our findings in the oldest bulge stars support the scenario where the first stellar generations have been fast rotators.

We investigate here the effect of the selection function on the metallicity distribution function (MDF) as well as on the vertical metallicity gradient by studying similar lines-of-sight using four different spectroscopic surveys (APOGEE, LAMOST, RAVE and Gaia-ESO) which have different targeting strategies and therefore different selection functions. We create mock fields for each survey using two stellar population synthesis models, GALAXIA and TRILEGAL. The effects of the selection function are studied in detail by applying the selection function to the two models and comparing the MDF as well as vertical metallicity gradients of the selected sources with that of the underlying sample. We find a negligible selection function effect on the MDF as well as on the vertical metallicity gradients for APOGEE, RAVE and LAMOST, and estimate a mean vertical metallicity gradient of -0.241±0.028 dex kpc−1.

One of the ways to obtain a detailed 3D ISM map is by gathering interstellar (IS) absorption data toward widely distributed background target stars at known distances (line-of-sight/LOS data). The radial and angular evolution of the LOS measurements allow the inference of the ISM spatial distribution. For a better spatial resolution, one needs a large number of the LOS data. It requires building fast tools to measure IS absorption. One of the tools is a global analysis that fit two different diffuse interstellar bands (DIBs) simultaneously. We derived the equivalent width (EW) ratio of the two DIBs recorded in each spectrum of target stars. The ratio variability can be used to study IS environmental conditions or to detect DIB family.

S stars are s-process and C-enriched (0.5<C/O<1) red giants. Their abundances can be determined thanks to a new grid of MARCS model atmospheres covering their whole parameter range. Detailed abundance determinations in intrinsic S stars (TP-AGB) and extrinsic S stars (binary masqueraders) can provide strong constraints on the s-process nucleosynthesis: in particular, the s-process temperature can be determined using zirconium and niobium abundances, independently of stellar evolution models. Synthetic spectra of dwarf S stars have been computed and will be sought for in spectroscopic survey data, constraining their luminosity thanks to Gaia parallaxes.

The understanding of the chemical evolution of the Galaxy relies on the stellar chemical composition. Accurate atmospheric parameters is a prerequisite of determination of accurate chemical abundances. For late type stars with known distance, surface gravity (log g) can be calculated from well-known relation between stellar mass, Teff, and absolute bolometric magnitude. This method weakly depends on model atmospheres, and provides reliable log g. However, accurate distances are available for limited number of stars. Another way to determine log g for cool stars is based on ionisation equilibrium, i.e. consistent abundances from lines of neutral and ionised species. In this study we determine atmospheric parameters moving step-by-step from well-studied nearby dwarfs to ultra-metal poor (UMP) giants. In each sample, we select stars with the most reliable Teff based on photometry and the distance-based log g, and compare with spectroscopic gravity calculated taking into account deviations from local thermodinamic equilibrium (LTE). After that, we apply spectroscopic method of log g determination to other stars of the sample with unknown distances.

Almost all stars in the Milky Way, including the Sun, will end their lives as white dwarfs. Their relatively peaceful transition off of the main sequence implies that most of their planetary systems will survive engulfment during the deaths of their host stars. These remnant planetary systems remain detectable for many Gyr through the occasional metal-contamination of the white dwarf photospheres by tidally disrupted planetesimals. Spectral analysis of these “metal-polluted” white dwarfs therefore provides a direct method for measuring the chemical compositions of extrasolar material. Here we present our sample of 230 cool white dwarfs with metal-rich photospheres, explore the diverse range of compositions of the accreted matter, and discuss two extreme systems which have respectively accreted planetesimals consistent with crust-like and core-like planetary material.

In this work, one intends to computationally simulate and investigate, via thermochemical calculations, how the chemical environment influences some molecular properties, such as IR spectra and absorption cross section, of individual species embedded in the solid phase employing the Polarized Continuum Model (PCM) approach. The trial molecules used here to check these effects are CO, CO2 and H2O. The solid phase (bulk ice) is simulated using different dielectric constant values representing different types of astrophysical ice at PCM approach. The effect of temperature is also investigated since it is known it affects the dielectric constant of the solvent medium.

Fostered by the possibilities of multi-dimensional computational modeling, in particular the advent of three-dimensional (3D) simulations, our understanding of the neutrino-driven explosion mechanism of core-collapse supernovae (SNe) has experienced remarkable progress over the past decade. First self-consistent, first-principle models have shown successful explosions in 3D, and even failed cases may be cured by moderate changes of the microphysics inside the neutron star (NS), better grid resolution, or more detailed progenitor conditions at the onset of core collapse, in particular large-scale perturbations in the convective Si and O burning shells. 3D simulations have also achieved to follow neutrino-driven explosions continuously from the initiation of the blast wave, through the shock breakout from the progenitor surface, into the radioactively powered evolution of the SN, and towards the free expansion phase of the emerging remnant. Here we present results from such simulations, which form the basis for direct comparisons with observations of SNe and SN remnants in order to derive constraints on the still disputed explosion mechanism. It is shown that predictions based on hydrodynamic instabilities and mixing processes associated with neutrino-driven explosions yield good agreement with measured NS kicks, light-curve properties of SN 1987A and asymmetries of iron and 44Ti distributions observed in SN 1987A and Cassiopeia A.

We perform hydrodynamic supernova (SN) simulations in spherical symmetry for progenitor models with solar metallicity across the stellar mass range from 9.0 to 120 M⊙ to explore the progenitor-explosion and progenitor-remnant connections based on the neutrino-driven mechanism. We use an approximative treatment of neutrino transport and replace the high-density interior of the neutron star (NS) by an inner boundary condition based on an analytic proto-NS core-cooling model, whose free parameters are chosen to reproduce the observables of SN 1987A and the Crab SN for theoretical models of their progenitor stars.

Judging the fate of a massive star, either a neutron star (NS) or a black hole (BH), solely by its structure prior to collapse has been ambiguous. Our work and previous attempts find a non-monotonic variation of successful and failed supernovae with zero-age main-sequence mass. We identify two parameters based on the “critical luminosity” concept for neutrino-driven explosions, which in combination allows for a clear separation of exploding and non-exploding cases.

Continuing our simulations beyond shock break-out, we are able to determine nucleosynthesis, light curves, explosion energies, and remnant masses. The resulting NS initial mass function has a mean gravitational mass near 1.4 M⊙. The average BH mass is about 9 M⊙ if only the helium core implodes, and 14 M⊙ if the entire pre-SN star collapses. Only ~10% of SNe come from stars over 20 M⊙, and some of these are Type Ib or Ic.