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Radiocarbon dating of the Church of St. Margaret of Antioch in Kopčany (Slovakia): International consortium results

Published online by Cambridge University Press:  05 December 2024

Pavel P Povinec Open the ORCID record for Pavel P Povinec [Opens in a new window] ,
Ivan Kontuľ ,
Alexander Cherkinsky Open the ORCID record for Alexander Cherkinsky [Opens in a new window] ,
Irka Hajdas Open the ORCID record for Irka Hajdas [Opens in a new window] ,
Yao Gu ,
A J Timothy Jull ,
Tomáš Lupták ,
Mihály Molnár Open the ORCID record for Mihály Molnár [Opens in a new window] ,
Peter Steier Open the ORCID record for Peter Steier [Opens in a new window]  and
Ivo Svetlik Open the ORCID record for Ivo Svetlik [Opens in a new window]
Pavel P Povinec*
Affiliation:
Faculty of Mathematics, Physics and Informatics, Comenius University, Bratislava, Slovakia
Ivan Kontuľ
Affiliation:
Faculty of Mathematics, Physics and Informatics, Comenius University, Bratislava, Slovakia
Alexander Cherkinsky
Affiliation:
Center for Applied Isotope Studies, University of Georgia, Athens, GA, USA
Irka Hajdas
Affiliation:
Laboratory of Ion Beam Physics, ETH Zurich, Switzerland
Yao Gu
Affiliation:
Laboratory of Ion Beam Physics, ETH Zurich, Switzerland Laboratory of AMS Dating and the Environment, School of Geography and Ocean Science, Nanjing University, Nanjing 210023, China
A J Timothy Jull
Affiliation:
Department of Geosciences, University of Arizona, Tucson, AZ, USA INTERACT Centre, Institute for Nuclear Research, Debrecen, Hungary
Tomáš Lupták
Affiliation:
Restauro, s.r.o., Bratislava, Slovakia
Mihály Molnár
Affiliation:
INTERACT Centre, Institute for Nuclear Research, Debrecen, Hungary
Peter Steier
Affiliation:
VERA Laboratory, Isotope Physics, Faculty of Physics, University of Vienna, Vienna, Austria
Ivo Svetlik
Affiliation:
Nuclear Physics Institute, Czech Academy of Sciences, Prague, Czech Republic
*
Corresponding author: Pavel P Povinec; Email: [email protected]
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Abstract

An international consortium of radiocarbon laboratories has established the origin of the Church of St. Margaret of Antioch in Kopčany (Slovakia), because its age was not well known from previous investigations. In total, 13 samples of charcoal, wood, mortar, and plaster were analyzed. The 14C results obtained from the different laboratories, as well as between the different sample types, were in good agreement. Resulting the final 14C calibrated age of the Church, based on dating a single piece of a wooden levelling rod is 774–884 AD (95.4% confidence level), which is in very good agreement with Bayesian modeling result based on dating of wood, charcoal and mortar samples (788–884 AD, 95.4% confidence level). The probability distribution from OxCal calibration shows that 79% of the probability distribution lies in the period before 863 AD, implying that the Church could have been constructed before the arrival of Constantine (St. Cyril) and St. Methodius to Great Moravia. If we take as the terminus post quem the documented date of consecration of the church in Nitrava (828 AD), the Bayesian modeling suggests the age of the Church in the range of 837–884 AD (95.4% confidence level). Although the 14C results have very good precision, the specific plateau shape of the calibration curve in this period caused a wide range of the calibrated age. The Church represents, together with the St. George’s Rotunda in Nitrianska Blatnica, probably the oldest standing purpose-built Christian church in the eastern part of Central Europe.

Keywords

accelerator mass spectrometrycharcoalKopčanymortarplasterradiocarbon datingSt. Margaret Church of Antiochwood
Type
Research Article
Information
Radiocarbon , Volume 67 , Issue 1 , February 2025 , pp. 135 - 154
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Copyright
© The Author(s), 2024. Published by Cambridge University Press on behalf of University of Arizona

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References

Anonymous (870) Libellus de conversione Bagoariorum et Carantanorum. In Lukačka J (ed), Sources of Slovak History and Slovaks II (1999). Bratislava, 139–144. In Slovak.Google Scholar
Bahýl, V, Fleischeer, P, Krišťák, Ľ, Mészáros, T, Pastierovič, M and Štafura, A (2013) Is Kopčany church from Great Moravia time? Results of dendrochronological studies. Proceedings of Interdisciplinary Scientific Research for Protection of the Cultural Heritage. Bratislava: SNM, 151–162. In Slovak.Google Scholar
Baxa, P (2000) Forsetzung der Untersuchung im Interieur der St. Margitkirche in Kopčany. AVANT in 1991 21. In Slovak.Google Scholar
Baxa, P, Ferus, V, Glaser-Opitzová, R and Katkinová, J (2004) Great Moravia church in Kostoľany. Pamiatky a múzeá 4, 65.Google Scholar
Baxa, P, Ferus, V, Glaser-Opitzová, R and Katkinová, J (2005) Great Moravia graves at the Church of St. Margaret Antioch in Kopčany. Pamiatky a múzeá 3, 48–50.Google Scholar
Baxa, P, Ferus, V and Glaser-Opitzová, R (2015) New knowledge about the Church of St. Margaret Antioch in Kopčany. Skalica: Záhorské múzeum. In Slovak.Google Scholar
Bayliss, A (2007) Bayesian buildings: an introduction for the numerically challenged. Vernacular Architecture 28, 76–87.Google Scholar
Bayliss, A (2009) Rolling out revolution: Using radiocarbon dating in archaeology. Radiocarbon 51, 123–147.CrossRefGoogle Scholar
Bayliss, A (2015) Quality in Bayesian chronological models in archaeology. World Archaeology 47(4), 677–700.CrossRefGoogle Scholar
Botek, A (2007) Church of St. Margaret Antioch in Kopčany. Pamiatky a múzeá 4, 41–45. In Slovak.Google Scholar
Botek, A (2010) Church of St. Margaret Antioch in Kopčany – stages of the development and the methodology of restoration. Ochrana pamiatok 22, 29–51. In Slovak.Google Scholar
Botek, A (2013) Findings of remains of the vaulting of the church nave in Kopčany. Pamiatky a múzeá 2, 38–41. In Slovak.Google Scholar
Botek, A, Erdély, R and Vachová, B (2015a) Methodology versions of the presentation of value layers and finds from the interior of the Church of St. Margaret of Antioch in Kopčany. Archaeologia Historica 40, 661–681. In Slovak.CrossRefGoogle Scholar
Botek, A, Erdély, R and Vachová, B (2015b) Church of St. Margaret Antioch in Kopčany. Skalica: Záhorské múzeum. In Slovak.Google Scholar
Bronk Ramsey, C (2009) Bayesian analysis of radiocarbon dates. Radiocarbon 51, 337–360.CrossRefGoogle Scholar
Bronk Ramsey, C (2017) Methods for summarizing radiocarbon datasets. Radiocarbon 59, 1809–1833.CrossRefGoogle Scholar
Bronk Ramsey, C (2020) OxCal program for radiocarbon calibration. https://c14.arch.ox.ac.uk/oxcal.html.Google Scholar
Daugbjerg, TS, Lindroos, A, Heinemeier, J, Ringbom, Å, Barrett, G, Michalska, D, Hajdas, I, Raja, R and Olsen, J (2021) A field guide to mortar sampling for radiocarbon dating. Archaeometry 63, 1121–1141.CrossRefGoogle Scholar
Dee, MW and Bronk Ramsey, C (2014) High-precision Bayesian modeling of samples susceptible to inbuilt age. Radiocarbon 56, 83–94.CrossRefGoogle Scholar
Drahošová, V and Vančo, M (1996) Investigation of the Church of St. Margaret Antioch in Kopčany. AVANS 1994, 46.Google Scholar
Goldberg, E (2006) Struggle for empire: Kingship and conflict under Louis the German, 817-876. Ithaca: Cornell University Press.Google Scholar
Gupta, SK and Polach, HA (1985) Radiocarbon Dating Practices at ANU. Canberra: ANU.Google Scholar
Hajdas, I (2008) The radiocarbon dating method and its applications in Quaternary studies. E & G Quaternary Science Journal 57, 2–24.CrossRefGoogle Scholar
Hajdas, I, Maurer, M and Röttig, MB (2020) Development of 14C dating of mortars at ETH Zurich. Radiocarbon 62, 591–600.CrossRefGoogle Scholar
Homza, M (2018) A few words about the identity of the Slavs, yesterday, today and tomorrow. Studia Slavica et Balcanica Petropolitana 23, 3–41.Google Scholar
Jull, AJT, Burr, GS, Beck, JW, Hodgins, GWL, Biddulph, DL, Gann, J, Hatheway, AL, Lange, TE and Lifton, NA (2006) Application of accelerator mass spectrometry to environmental and paleoclimate studies at the University of Arizona. In Povinec, PP, editor. Analysis of Environmental Radionuclides. Amsterdam: Elsevier, 3–23.Google Scholar
Jull, AJT, Burr, GS, Beck, JW, Hodgins, GWL, Biddulph, DL, McHargue, LR and Lange, TE (2008) Accelerator mass spectrometry of long-lived light radionuclides. In Povinec, P, editor. Analysis of Environmental Radionuclides. Amsterdam: Elsevier, 241–262.CrossRefGoogle Scholar
Kekeši, M (2014) Restoration research and restoration in the interior of the Church of St. Margaret of Antioch in Kopčany. Proceedings of Lectures 13th International Seminar on Restoration, Tatranská Lomnica. https://zborniky.restauro.sk/2014.html. In Slovak.Google Scholar
Kontuľ, I, Ješkovský, M, Kaizer, J, Šivo, A, Richtáriková, M, Povinec, PP, Čech, P, Steier, P and Golser, R (2017) Radiocarbon concentration in tree-ring samples collected in the southwest Slovakia (1974-2013). Applied Radiation and Isotopes 126, 58–60.CrossRefGoogle ScholarPubMed
Kouřil, P (2014) Great Moravia and Beginnings of Christianity. Brno: Czech Academy of Sciences.Google Scholar
Lange, TE, Nordby, JA, Murphy, PLO, Hodgins, GWL and Pearson, CL (2019) A detailed investigation of pretreatment protocols for high precision radiocarbon measurements of annual tree-rings. Nuclear Instruments and Methods B 455, 230–233.CrossRefGoogle Scholar
Lupták, T (2021) Documentation of the restoration of the Church of St. Margaret of Antioch in Kopčany 2020-2021. KPU Trnava Archive. In Slovak.Google Scholar
Lupták, T (2022) Completion of the reconstruction of the Church of St. Margaret Antioch in Kopčany. https://www.kopcany.sk’ projekty. In Slovak.Google Scholar
Molnár, M, Janovics, R, Major, I, Orsovszki, J, Gönczi, R, Veres, M, Leonard, AG, Castle, SM, Lange, TE, Wacker, L, Hajdas, I and Jull, AJT (2013a) Status report of the new AMS 14C sample preparation lab of the Hertelendi Laboratory of Environmental Studies (Debrecen, Hungary). Radiocarbon 55, 665–676.CrossRefGoogle Scholar
Molnár, M, Rinyu, L, Veres, M, Seiler, M, Wacker, L and Synal, H-A (2013b) EnvironMICADAS: a mini 14C-AMS with enhanced gas ion source interface in the Hertelendi Laboratory of Environmental Studies (HEKAL), Hungary. Radiocarbon 55, 338–344.CrossRefGoogle Scholar
Orsovszki, G and Rinyu, L (2015) Flame-sealed tube graphitization using zinc as the sole reduction agent: precision improvement of Environ MICADAS 14C measurements on graphite targets. Radiocarbon 57, 979–990.CrossRefGoogle Scholar
Povinec, PP, Masarik, J, Ješkovský, M, Kaizer, J, Šivo, A, Breier, R, Pánik, J, Staníček, J, Richtáriková, M, Zahoran, M and Zeman, J (2015) Development of the accelerator mass spectrometry technology at the Comenius University in Bratislava. Nuclear Instruments and Methods in Physics Research B 361, 87–94.CrossRefGoogle Scholar
Povinec, PP, Cherkinsky, A, Dorica, J, Hajdas, I, Jull, AJT, Kontuľ, I, Molnár, M, Svetlik, I, Wild, EM (2021) Radiocarbon dating of St. George’s Rotunda in Nitrianska Blatnica (Slovakia): International consortium results. Radiocarbon 63, 953–976.CrossRefGoogle Scholar
Povinec, PP, Kontuľ, I, Ješkovský, M, Kaizer, J, Kvasniak, J, Pánik, J, and Zeman, J (2024) Development and applications of accelerator mass spectrometry methods for measurement of 14C, 10Be and 26Al in the CENTA laboratory. Journal of Radioanalytical and Nuclear Chemistry 333, 3497–3509. https://doi.org/10.1007/s10967-023-09294-5.CrossRefGoogle Scholar
Puškár, J and Mýtnik, V (2006) Church of St. Margaret of Antioch in Kopčany. Restoration Research and Proposal for Restoration. KPU Trnava Archive. In Slovak.Google Scholar
Puškár, J and Mýtnik, V (2009) Church of St. Margaret Antioch in Kopčany. Restoration Research and Proposal for Restoration. KPU Trnava Archive. In Slovak.Google Scholar
Reimer, PJ et al. (2020) IntCal20 Northern Hemisphere radiocarbon age calibration curve (0–55 cal kBP) and Marine13 radiocarbon age calibration curves 0–50,000 years cal BP. Radiocarbon 62, 725–757.CrossRefGoogle Scholar
Rinyu, L, Molnár, M, Major, I, Nagy, T, Veres, M, Kimák, Á, Wacker, L and Synal, H-A (2013) Optimization of sealed tube graphitization method for environmental 14C studies using MICADAS. Nuclear Instruments and Methods in Physics Research B 294, 270–275.CrossRefGoogle Scholar
Rinyu, L, Orsovszki, G, Futó, I, Veres, M and Molnár, M (2015) Application of zinc sealed tube graphitization on sub-milligram samples using Environ MICADAS. Nuclear Instruments and Methods in Physics Research B 361, 406–413.CrossRefGoogle Scholar
Ruff, M, Szidat, S, Gäggeler, H, Suter, M, Synal, HA, Wacker, L (2010) Gaseous radiocarbon measurements of small samples. Nuclear Instruments and Methods in Physics Research B 268, 790–794.CrossRefGoogle Scholar
Sabadošová, E and Havlík, M (1998) Report on the Results of Archaeological Research. PÚ-Bratislava. In Slovak.Google Scholar
Sabadošová, E, Havlík, M (1999) Report on the Results of Architectural Research l995-l998, Church of St. Margaret Antioch in Kopčany. KPU Trnava Archive. In Slovak.Google Scholar
Sabadošová, E and Havlík, M (2008) Art-historical research of the southern and western facades of the nave of the church with the evaluation of restoration findings during the removal of plaster, October-November 2008. KPU Trnava Archive. In Slovak.Google Scholar
Schneider, RJ, McNihol, AP, Nadeau, MJ and Reden, KF (1995) Measurements of the Oxalic Acid II/Oxalic Acid I ratio as a quality control parameter at NOSAMS. Radiocarbon 37(2), 693–696.CrossRefGoogle Scholar
Spiesz, A and Caplovic, D (2006) Illustrated Slovak History: A Struggle for Sovereignty in Central Europe. Wauconda: Bolchazy-Carducci Publishers.Google Scholar
Steier, P, Dellinger, F, Kutschera, W, Priller, A, Rom, W and Wild, EM (2004) Pushing the precision limit of 14C AMS. Radiocarbon 46, 5–16.CrossRefGoogle Scholar
Stuiver, M and Polach, H (1977) Reporting of 14C data. Radiocarbon 19, 355–363.CrossRefGoogle Scholar
Stuiver, M and Reimer, PJ (1993) Extended 14C data base and revised Calib 3.0 14C age calibration program. Radiocarbon 35, 215–230.CrossRefGoogle Scholar
Terry, JM and Gallagher, RL (2017) Encountering the History of Missions. Grand Rapids: Baker Academic.Google Scholar
Urbanová, P, Boaretto, E and Artioli, G (2020) The state-of-the-art dating techniques applied to ancient mortars and binders: A review. Radiocarbon 62, 503–525.CrossRefGoogle Scholar
Vogel, JS, Southon, JR, Nelson, DE, Brown, TA (1984) Performance of accelerator mass spectrometry. Nuclear Instruments and Methods in Physics Research B 5, 289–293.CrossRefGoogle Scholar
Wild, EM, Neugebauer-Maresch, C, Einwögerer, T, Stadler, P, Steier, P and Brock, F (2008) 14C dating of the Upper Paleolithic site at Krems-Hundssteig in Lower Austria. Radiocarbon 50, 1–10.CrossRefGoogle Scholar