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Effect of Adjuvant on Foliar Absorption and Activity of Clethodim and Polar Degradation Products of Clethodim

Published online by Cambridge University Press:  12 June 2017

David C. Bridges
Affiliation:
Dep. Agron., Univ. Georgia, Griffin, GA 30223-1797
Albert E. Smith
Affiliation:
Dep. Agron., Univ. Georgia, Griffin, GA 30223-1797
Linford N. Falb
Affiliation:
Dep. Agron., Univ. Georgia, Griffin, GA 30223-1797

Abstract

Research was conducted to determine foliar absorption of 14C-clethodim and its polar degradation products with five adjuvants and to compare the relative herbicidal activity of clethodim and its polar degradation products. Differential 14C-clethodim and 14C-polar degradation products absorption occurred among the five adjuvants. Adjuvants that mediated rapid foliar absorption of clethodim did not always mediate rapid foliar uptake of polar degradation products. Herbicidal activity of clethodim exceeded activity of polar degradation products regardless of time of day of application or whether adjuvant was used. Inclusion of adjuvant was required for herbicidal activity of polar degradation products. Clethodim activity declined when applied at 0800 h EDT compared to applications at 2000 h EDT. To maximize herbicidal activity of clethodim, adjuvants should be selected that mediate rapid foliar absorption of both clethodim and the polar degradation products of clethodim and that minimize photodegradation of clethodim.

Type
Physiology, Chemistry, and Biochemistry
Copyright
Copyright © 1992 by the Weed Science Society of America 

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References

Literature Cited

1. Anonymous. 1990. DASH SPRAY TANK ADJUVANT, Material safety data sheet. Pages 158159 in MSDS Reference for Crop Protection Chemicals. 3rd ed. John Wiley & Sons and C&P Press, New York and Paris.Google Scholar
2. Bridges, D. C. 1989. Adjuvant and pH effects on sethoxydim and clethodim activity on rhizome johnsongrass. Weed Technol. 3:615620.Google Scholar
3. Campbell, J. R. and Penner, D. 1985. Abiotic transformation of sethoxydim. Weed Sci. 33:435439.CrossRefGoogle Scholar
4. Falb, L. N., Bridges, D. C., and Smith, A. E. Jr. 1990. Effects of pH and adjuvants on clethodim photodegradation. J. Agric. and Food Chem. 38:875878.Google Scholar
5. Falb, L. N., Bridges, D. C., and Smith, A. E. Jr. 1991. Determination of acid and photocatalysis products of clethodim herbicide by liquid chromatography. J. Off. Anal. Chem. (In press).Google Scholar
6. Focke, M., and Lichtenthaler, H. K. 1987. Inhibition of the acetyl-CoA carboxylase of barley chloroplasts by cycloxydim and sethoxydim. Z. Naturforsch. 42C:13611363.CrossRefGoogle Scholar
7. Gillespie, G. R., Skrzypczak, G. A., and Nalewaja, J. D. 1988. Absorption and translocation of CGA-82725 with additives. Weed Sci. 36:282285.CrossRefGoogle Scholar
8. Harrison, S. K., Wax, L. M., and Bode, L. E. 1986. Influence of adjuvants and application variables on postemergence weed control with bentazon and sethoxydim. Weed Sci. 34:462466,Google Scholar
9. Hartzler, R. G. and Foy, C. L. 1983. Efficacy of three postemergence grass herbicides for soybeans. Weed Sci. 31:557561.Google Scholar
10. Harwood, J. L. 1988. The site of action of some selective graminaceous herbicides is identified as acetyl-CoA carboxylase. Trends Biochem. Sci. 13:330331.Google Scholar
11. Kells, J. J. and Wanamarta, G. 1987. Effect of adjuvant and spray volume on quackgrass control with selective postemergence herbicides. Weed Technol. 1:129132.CrossRefGoogle Scholar
12. Kobek, K., Focke, M., Lichtenthaler, H. K., Retzlaff, G., and Wurzer, B. 1988. Inhibition of fatty acid biosynthesis in isolated chloroplasts by cycloxydim and other cyclohexane-1,3-diones. Physiol. Plant. 72:492498.Google Scholar
13. Penner, D. 1989. The impact of adjuvants on herbicide antagonism. Weed Technol. 3:227231.Google Scholar
14. Rendina, A. R., and Felts, J. M. 1988. Cyclohexanedione herbicides are selective and potent inhibitors of acetyl-CoA carboxylase from grasses. Plant Physiol. 86:983986.Google Scholar
15. Zorner, P., Hazen, J., Evans, R., Gourd, D., and Fitzgerald, T. 1989. The influence of DASH adjuvant in limiting photodegradation of sethoxydim on leaf surfaces. Abstr. Weed Sci. Soc. Am. 29:188.Google Scholar