Published online by Cambridge University Press: 14 August 2015
This review summarises current knowledge of the chemical composition of PopI WR stars, concentrating on work carried out in this area since the last IAU, No. 49, symposium devoted to this stellar class (Bappu & Sahade 1973). Earlier reviews of this topic are found in Gebbie & Thomas (1968). The dichotomy of the WR stars into the WN and WC sequences (Beals 1934) has generally been qualitatively interpreted as arising because of gross differences in the C and N abundances: WN stars which exhibit emission lines of predominantly He and N ions with little evidence for C, being inferred as C-poor objects, whilst WC stars, showing predominantly He and C lines and virtually no evidence for N being inferred as N-poor. In both sequences the visible spectra show little or no evidence for hydrogen. However, although the WR stars have been acknowledged as a class for over a century now, progress has been very slow in putting quantitative determinations of their physical and chemical properties on a firm basis, with the bulk of work in this area being conducted during the past decade. The chemical nature of the WR stars has always been a matter of considerable uncertainty, controversy and, quite often, passionate disagreement, arising from uncertainties in the interpretation of the, often ambiguous, observational material available, as well as from disagreements as to the reliability of the use of comparatively simple analytical models employed to date. Recent results strongly suggest that the WR stars are chemically evolved objects, with low H/He ratios and quite different C/N ratios in the WN and WC sequences, with some measure of agreement in these results with the chemistries predicted to arise at various stages of evolutionary theory for hot massive stars which, by one means or another, have shed much of their atmospheric material during their evolution. My purpose in this review is to summarise the investigations and results that lead to the above conclusions. §2 deals with an assessment of the atmospheric H/He ratio in both WN and WC stars: a parameter of fundamental importance in addressing their evolutionary status, as well as providing a base species with which to compare other derived chemical abundances. §3 briefly deals with the models generally employed and gives recent results for He, C and N abundances derived from both visible and UV line analyses. §4 summarises recent results from stellar evolutionary theory and in §5 compares these with those derived from observation, assessing the significance of these new results and their implications for the evolutionary status of the WR stars. Some areas for further advancement are identified.