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An ICR Study of an Association Reaction at Low Pressure

Published online by Cambridge University Press:  14 August 2015

M.J. Mcewan ,
V. G. Anicich ,
W.T. Huntress Jr. ,
P. R. Kemperer  and
M. T. Bowers
M.J. Mcewan
Affiliation:
Jet Propulsion Lab., 4800 Oak Grove Dr., Pasadena, CA 91103
V. G. Anicich
Affiliation:
Jet Propulsion Lab., 4800 Oak Grove Dr., Pasadena, CA 91103
W.T. Huntress Jr.
Affiliation:
Jet Propulsion Lab., 4800 Oak Grove Dr., Pasadena, CA 91103
P. R. Kemperer
Affiliation:
Chemistry Dept., Univ. of California, Santa Barbara, CA 93106
M. T. Bowers
Affiliation:
Chemistry Dept., Univ. of California, Santa Barbara, CA 93106

Abstract

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An ICR investigation of the association reaction

CH3+ + HCN CH3.HCN+

has shown the reaction follows second order kinetics over the pressure range 1 × 10-6 to 3 × 10-4 Torr with a rate coefficient of 2 × 10-10 cm3s-1. These results can be interpreted in terms of a saturated 3-body or radiative association mechanism.

Type
Research Article
Information
Symposium - International Astronomical Union , Volume 87: Interstellar Molecules , 1980 , pp. 305 - 306
Copyright
Copyright © Reidel 1980 

References

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