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“Reference waters” in French laboratories involved in tritiummonitoring: how tritium-free are they?

Published online by Cambridge University Press:  21 March 2014

E. Fourré ,
P. Jean-Baptiste ,
A. Dapoigny ,
E. Ansoborlo  and
N. Baglan
E. Fourré*
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
P. Jean-Baptiste
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
A. Dapoigny
Affiliation:
Laboratoire des Sciences du Climat et de l’Environnement, UMR 8212 CEA-CNRS-UVSQ/IPSL, CEN Saclay, 91191 Gif-sur-Yvette, France.
E. Ansoborlo
Affiliation:
CETAMA, CEA/DEN/DCRP, Marcoule, 30207 Bagnols-sur-Cèze, France.
N. Baglan
Affiliation:
CEA/DAM/DIF, 91297 Arpajon, France.
*
a[email protected]
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Abstract

This paper presents a comprehensive survey of the tritium content of “reference waters”in real working conditions by French laboratories involved in environmental monitoring.Reference waters are virtually tritium-free waters used to determine blanks for theanalytical system and to check for any contamination. It is therefore crucial to be sureof the low tritium content of these waters as this can limit the sensitivity and accuracyof the measurements. Water from the commercial brand “Abatilles” is widely used in Frenchlaboratories and nine samples were analyzed in this study. Three samples from other deepaquifers were also included. The results all range from 0.004 ± 0.004 Bq/kg to 0.175 ± 0.011 Bq/kg, well below the 0.5Bq/kg advised by the French Safety Authority. The spread of the results can mainly beattributed to contamination through plastic during bottle storage. As expected, twosamples from demineralized tap water showed higher tritium activities (0.3–0.35 Bq/kg).Both waters are suitable as reference water for routine monitoring (DL of about 10 Bq/kg)but should be used with caution for activities in the Bq/kg range.

Keywords

tritiumenvironmental monitoringlow dosesgroundwatersmass spectrometry
Type
Article
Information
Radioprotection , Volume 49 , Issue 2 , April 2014 , pp. 143 - 145
Copyright
© EDP Sciences, 2014

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References

ASN (2010) Livre Blanc du Tritium, Autorité de Sûreté Nucléaire, available from http://www.asn.fr.
Baglan, N., Ansoborlo, E., Cossonnet, C., Fouhal, L., Deniau, I., Mokili, M., Henry, A., Fourré, E., Olivier, A. (2010) Métrologie du tritium dans différentes matrices: cas du tritium organiquement lié, Radioprotection 45 (3), 369-390. Google Scholar
Clarke, W.B., Jenkins, W.J., Top, Z. (1976) Determination of tritium by mass-spectrometric measurement of He-3, Appl. Radiat. Isotopes 27, 515-522. Google Scholar
Jean-Baptiste, P., Mantisi, F., Dapoigny, A., Stievenard, M. (1992) Design and performance of a mass spectrometric facility for measuring helium isotopes in natural waters and for low-level tritium determination by the 3He ingrowth method, Appl. Radiat. Isotopes 43, 881-891. Google ScholarPubMed
Jean-Baptiste, P., Fourré, E., Dapoigny, A., Baumier, D., Baglan, N., Alanic, G. (2010) 3He mass spectrometry for very low-level measurement of organic tritium in environmental samples, J. Environ. Rad. 101, 185-190. Google Scholar