Hostname: page-component-6bf8c574d5-h6jzd Total loading time: 0.001 Render date: 2025-02-21T13:45:07.947Z Has data issue: false hasContentIssue false
  • English
  • Français

Quantitative Extraction of Dissolved Inorganic Carbon (as CO2) and Water by Vacuum Distillation from Sediments of the Unsaturated Zone for Carbon Isotope Analysis (13C and 14C)

Published online by Cambridge University Press:  18 July 2016

I Carmi ,
J Kronfeld ,
Y Yechieli ,
D Yakir ,
M Stiller  and
E Boaretto
I Carmi*
Affiliation:
Department of Geophysics and Planetary Science, Tel-Aviv University, 61390 Tel-Aviv, Israel Geological Survey of Israel, 95001 Jerusalem, Israel
J Kronfeld
Affiliation:
Department of Geophysics and Planetary Science, Tel-Aviv University, 61390 Tel-Aviv, Israel
Y Yechieli
Affiliation:
Geological Survey of Israel, 95001 Jerusalem, Israel
D Yakir
Affiliation:
Department of Environmental Science and Energy Research, Weizmann Institute of Science, 76100 Rehovot, Israel
M Stiller
Affiliation:
Geological Survey of Israel, 95001 Jerusalem, Israel
E Boaretto
Affiliation:
Radiocarbon Dating and Cosmogenic Isotopes Laboratory, Kimmel Center for Archaeological Science Weizmann Institute of Science, 76100 Rehovot, Israel
*
Corresponding author. Email: [email protected].
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Vacuum distillation is shown to be useful for the quantitative extraction of dissolved inorganic carbon (as CO2) and water from sediments of the unsaturated zone in the Coastal Aquifer of Israel. Several tests of vacuum extractions from tap water and sediments are presented, including standard addition, which show that the distillation procedure is quantitative, with minimal or no carbon isotope fractionation. The optimal temperature of the sediment during the extraction was also defined. Examples of vacuum extractions of sediments are shown.

Type
Articles
Information
Radiocarbon , Volume 49 , Issue 1 , 2007 , pp. 83 - 94
Copyright
Copyright © 2007 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Böttcher, G, Brumsack, H-J, Heinrichs, H, Pohlmann, M. 1997. A new high-pressure squeezing technique for pore fluid extraction from terrestrial soils. Water, Air and Soil Pollution 94(3–4):289–96.CrossRefGoogle Scholar
Bruce, D, Friedman, GM, Kaufman, A, Yechieli, Y. 2001. Spatial variations of radiocarbon in the coastal aquifer of Israel—indicators of open and closed systems. Radiocarbon 43(2B):783–91.Google Scholar
Davidson, GR, Hardin, EL, Bassett, RL. 1995. Extraction of 14C from pore water in unsaturated rock using vacuum distillation. Radiocarbon 37(3):861–74.CrossRefGoogle Scholar
Edmunds, WH, Bath, A. 1976. Centrifuge extraction and chemical analysis of interstitial waters. Environmental Science and Technology 10(5):467–72.CrossRefGoogle Scholar
Kinniburgh, DG, Miles, DL. 1983. Extraction and chemical analysis of interstitial water from soils and rocks. Environmental Science and Technology 17(6):362–8.CrossRefGoogle Scholar
Stumm, W, Morgan, JJ. 1995. Aquatic Chemistry: Chemical Equilibria and Rates in Natural Waters. 3rd edition. New York: Wiley-Interscience. 1040 p.Google Scholar