Hostname: page-component-78c5997874-g7gxr Total loading time: 0 Render date: 2024-11-03T01:26:26.431Z Has data issue: false hasContentIssue false
  • English
  • Français

Preliminary Results for the Extraction and Measurement of Cosmogenic in Situ 14C from Quartz

Published online by Cambridge University Press:  18 July 2016

P Naysmith ,
G T Cook ,
W M Phillips ,
N A Lifton  and
R Anderson
P Naysmith*
Affiliation:
Scottish Universities Environmental Research Centre, East Kilbride G75 0QF, Scotland.
G T Cook
Affiliation:
Scottish Universities Environmental Research Centre, East Kilbride G75 0QF, Scotland.
W M Phillips
Affiliation:
School of Geosciences, University of Edinburgh, Edinburgh EH8 9XP, Scotland.
N A Lifton
Affiliation:
Geosciences Department, University of Arizona, Tucson, Arizona 85721, USA.
R Anderson
Affiliation:
Scottish Universities Environmental Research Centre, East Kilbride G75 0QF, Scotland.
*
Corresponding author. Email: [email protected].
Rights & Permissions [Opens in a new window]

Abstract

Core share and HTML view are not available for this content. However, as you have access to this content, a full PDF is available via the ‘Save PDF’ action button.

Radiocarbon is produced within minerals at the earth's surface (in situ production) by a number of spallation reactions. Its relatively short half-life of 5730 yr provides us with a unique cosmogenic nuclide tool for the measurement of rapid erosion rates (>10−3 cm yr−1) and events occurring over the past 25 kyr. At SUERC, we have designed and built a vacuum system to extract 14C from quartz which is based on a system developed at the University of Arizona. This system uses resistance heating of samples to a temperature of approximately 1100° in the presence of lithium metaborate (LiBO2) to dissolve the quartz and liberate any carbon present. During extraction, the carbon is oxidized to CO2 in an O2 atmosphere so that it may be collected cryogenically. The CO2 is subsequently purified and converted to graphite for accelerator mass spectrometry (AMS) measurement. One of the biggest problems in measuring in situ 14C is establishing a low and reproducible system blank and efficient extraction of the in situ 14C component. Here, we present initial data for 14C-free CO2, derived from geological carbonate and added to the vacuum system to determine the system blank. Shielded quartz samples (which should be 14C free) and a surface quartz sample routinely analyzed at the University of Arizona were also analyzed at SUERC, and the data compared with values derived from the University of Arizona system.

Type
Articles
Information
Radiocarbon , Volume 46 , Issue 1: Proceedings of the 18th International Radiocarbon Conference (Part 1 of 2), Conference Editors: Nancy Beavan Athfield, Rodger J Sparks , 2004 , pp. 201 - 206
Copyright
Copyright © 2004 by the Arizona Board of Regents on behalf of the University of Arizona 

References

Donahue, DJ, Linick, TW, Jull, AJT. 1990. Isotope-ratio and background corrections for accelerator mass spectrometry radiocarbon measurements. Radiocarbon 32(2):135–42Google Scholar
Gosse, JC, Phillips, FM. 2001. Terrestrial in situ cosmogenic nuclides: theory and application. Quaternary Science Reviews 20:1475–560.Google Scholar
Lifton, NA. 1997. A New Extraction Technique and Production Rate Estimate for In Situ Cosmogenic 14 C in Quartz [PhD dissertation] . Tucson: University of Arizona.Google Scholar
Lifton, NA, Jull, AJT, Quade, J. 2001. A new extraction technique and production rate estimate for in situ cosmogenic 14C in quartz. Geochimica et Cosmochimica Acta 65:1953–69.CrossRefGoogle Scholar
Lal, D. 1991. Cosmic ray labeling of erosion surfaces: in situ nuclide production rates and erosion models. Earth and Planetary Science Letters 104:424–39.Google Scholar
Slota, PJ Jr, Jull, AJT, Linick, TW, Toolin, LJ. (1987). Preparation of small samples for 14C accelerator targets by catalytic reduction of CO. Radiocarbon 29(2):303–6.Google Scholar