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Loess–paleosol carbonate clumped isotope record of late Pleistocene–Holocene climate change in the Palouse region, Washington State, USA

Published online by Cambridge University Press:  05 July 2018

Alex R. Lechler*
Affiliation:
Department of Geosciences, Pacific Lutheran University, Tacoma, Washington 98447, USA
Katharine W. Huntington
Affiliation:
Department of Earth and Space Sciences, University of Washington, Seattle, Washington 98195, USA
Daniel O. Breecker
Affiliation:
Department of Geological Sciences, Jackson School of Geosciences, University of Texas at Austin, Austin, Texas 78712, USA
Mark R. Sweeney
Affiliation:
Department of Sustainability and Environment, University of South Dakota, Vermillion, South Dakota 57069, USA
Andrew J. Schauer
Affiliation:
Department of Earth and Space Sciences, University of Washington, Seattle, Washington 98195, USA
*
*Corresponding author at: Department of Geosciences, Pacific Lutheran University, Rieke 158, Tacoma, Washington 98447, USA. E-mail address: [email protected] (A.R. Lechler).

Abstract

The Channeled Scabland–Palouse region of the Pacific Northwest (PNW) of the United States preserves geomorphic and pedosedimentary records that inform understanding of late Pleistocene–Holocene paleoclimate change in a region proximal to the last glacial period Cordilleran Ice Sheet. We present a clumped (Δ47) and conventional (δ18O, δ13C) isotopic study of Palouse loess–paleosol carbonates in combination with carbonate radiocarbon (14C) dating to provide new measures of regional late–last glacial (~31–20 cal ka BP) and Holocene soil conditions. Average clumped isotope temperatures (T(Δ47)) for last glacial Palouse loess–paleosol carbonates (9±4°C) are significantly lower than those for Holocene-aged carbonates (T(Δ47)=18±2°C) in study sections. Calculated soil water δ18OVSMOW values (−16±2‰) for last glacial carbonates are also offset relative to those for Holocene-aged samples (−11±1‰), whereas calculated soil CO2 δ13CVPDB values are similar for the Holocene (−16.9±0.2‰) and late–last glacial (−16.7±1.1‰) periods. Together, these paleoclimate metrics indicate late–last glacial conditions of pedogenic carbonate formation in the C3 grassland soils of the Palouse were measurably colder (9±5°C) than during the Holocene and potentially reflect a more arid last glacial paleoclimate across the Palouse, findings in agreement with previous proxy studies and climate model simulations for the region.

Type
Research Article
Copyright
Copyright © University of Washington. Published by Cambridge University Press, 2018 

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