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Published online by Cambridge University Press: 28 February 2022
Position probabilities play a privileged role in the interpretation of quantum mechanics. The quantum wave function (usually designated “Ψ(r)’) cannot itself represent a physical quantity, because it is complex valued. Its square — |Ψ(r)|2 — however, is real; and it is |Ψ(r)|2 which is the fundamental interpreted quantity of the theory. Schrödinger, who originated wave mechanics, interpreted |Ψ(r)|2 as the density of a charged particle; but this suggestion was inadequate. A principal reason is that, for most physical systems, |Ψ(r)|2 spreads out in time, whereas particles themselves do not. Schrödinger's interpretation was replaced by Born who introduced probabilities into quantum mechanics. Born urged that |Ψ(r)|2 represents not the density of the system in space, but rather a probability density. This is almost universally how quantum mechanics is taught today: |Ψ(r)|2 gives the probability that a system in state Ψ(r) is located at r.