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Electrolysis through Precipitation Films. Part I
Published online by Cambridge University Press: 15 September 2014
Extract
In a paper on the aluminium anode by one of us, in conjunction with Inglis, it was pointed out that if the suggested theory of the aluminium anode is correct, a precipitation film of aluminium hydroxide should dimmish the conductivity of salt solutions to very different extents depending upon the ions present, and that, e.g., the diminution in the case of potassium chloride might be expected to be slight, in the case of potassium bromide somewhat greater, and in the case of potassium sulphate to be very considerable. Preliminary experiments to measure these differences directly were not successful, almost certainly, as was stated at the time, because of the difficulty of freeing the precipitation membrane from the concomitant soluble impurities.
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- Copyright © Royal Society of Edinburgh 1906
References
page 447 note * Taylor, and Inglis, , Phil. Mag., March 1903.Google Scholar
page 447 note † Tammann, , Zeit. f. Physikal. Chem., vi. p. 237, 1890.Google Scholar
page 447 note ‡ Morse, , Amer. Chem. Journal, xxix. p. 173, 1903.Google Scholar
page 452 note * It should be noted that a cell marked A in one table is not necessarily the same as cell A in another table. The cells frequently broke at the brass joints, and new parts were fitted on.
page 461 note * Kohlrausch und Holborn, Leitvermögen, p. 151, 1898.