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IX.—The Synthesis of 8-Phenyl-7H-Benz[de]anthracene*

Published online by Cambridge University Press:  14 February 2012

Neil Campbell  and
Jamieson Walker
Neil Campbell
Affiliation:
Department of Chemistry, University of Edinburgh.
Jamieson Walker
Affiliation:
Department of Chemistry, University of Edinburgh.
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Extract

2-Benzylidene-2,3-dihydrophenalen-i-one with ethyl acetoacetate and sodium ethoxide yields four products depending on the concentration of the alkali. One of these, ethyl 7a,8,9,10-tetrahydro-10-oxo-8- phenyl-7H-benz[de]-anthracene-9-carboxylate has been converted into 8-phenyl-7H-benz[de]anthracene and its reduction with sodium borohydride or hydrogen in the presence of platinum oxide or Raney nickel presents points of interest.

Type
Research Article
Information
Proceedings of the Royal Society of Edinburgh Section A: Mathematics , Volume 69 , Issue 2 , 1971 , pp. 132 - 138
Copyright
Copyright © Royal Society of Edinburgh 1971

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References

References to Literature

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