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IX.—The Synthesis of 8-Bromo-3-methoxyfluoranthene.*

Published online by Cambridge University Press:  14 February 2012

Neil Campbell
Affiliation:
Department of Chemistry, University of Edinburgh.
Naim M. Hasan
Affiliation:
Department of Chemistry, University of Edinburgh.

Summary

A second method for the synthesis of 8-bromo-3-methoxyfluoranthene from 2-bromo-7-methoxyfluorene is described. The autoxidation of fluorene derivatives including the 9-carboxylic acids and of related compounds, particularly 4-α-cyanobenzyl-7−oxo-7H-benz[de]anthracene, is discussed. Unsuccessful attempts to prepare 3-bromofluorene-9-acetic acid in good yield are reported.

Type
Research Article
Copyright
Copyright © Royal Society of Edinburgh 1969

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References

References to Literature

Bruson, H. A., 1942. J. Am. Chem. Soc., 64, 2457.CrossRefGoogle Scholar
Berkovic, S., 1963. Israel J. Chem., 1, 1.CrossRefGoogle Scholar
Campbell, A., and Tucker, S. H., 1949. J. Chem. Soc., 2623.CrossRefGoogle Scholar
Campbell, N., Andrew, H. F., and Hasan, N. M., 1968. [In the press.]Google Scholar
Campbell, N., and Woodham, A. A., 1953. J. Chem. Soc., 3429.CrossRefGoogle Scholar
Dickinson, J. D., and Eaborn, C., 1959. J. Chem. Soc., 2337.CrossRefGoogle Scholar
Hock, H., and Lang, S., 1944. Chem. Ber., 77, 257.CrossRefGoogle Scholar
Kharasch, M. S., and Sosnovsky, G., 1958. Tetrahedron, 3, 97.CrossRefGoogle Scholar
Kornblum, N., and Delamare, H. E., 1951. J. Am. Chem. Soc., 73, 880.CrossRefGoogle Scholar
Schlenk, W., and Bergmann, E., 1928. Justus Liebigs Annln Chem., 463, 203.CrossRefGoogle Scholar
Sprinzak, Y., 1958. J. Am. Chem. Soc., 80, 5449.CrossRefGoogle Scholar
Waters, W. A., 1964. Mechanisms of Oxidation of Organic Compounds. p. 460. London: Methuen.Google Scholar
Weisburger, J., and Weisburger, E., 1954. J. Chem. Soc., 758.Google Scholar
Wittig, G., and Pockels, U., 1936. Chem. Ber., 69, 790.CrossRefGoogle Scholar
Wittig, G., Todt, U., and Nagel, K., 1950. Chem. Ber., 83, 110.CrossRefGoogle Scholar
Wislicenus, W., and Mocker, W., 1913. Chem. Ber., 46, 2774, 2777.Google Scholar
Wislicenus, W., and Ruthing, A., 1913. Chem. Ber., 46, 2770.CrossRefGoogle Scholar