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Published online by Cambridge University Press: 27 February 2023
Binary neutron star (NS) mergers have been expected to synthesize r-process elements and cause electromagnetic radiation called kilonovae. Although r-process nucleosynthesis was confirmed by the observations of GW170817/AT2017gfo, individual elements have not been identified except for strontium. Toward identification of elements in kilonova spectra, we perform radiative transfer simulations in NS merger ejecta. We find that Sr II triplet lines appear in the spectrum, which is consistent with the absorption feature observed in GW170817/AT2017gfo. The synthetic spectrum also shows the strong Ca II triplet lines. Absence of the Ca II line features in GW170817/AT2017gfo implies that the Ca/Sr ratio is < 0.002 in mass fraction, which is consistent with nucleosynthesis for electron fraction ≥ 0.40 and entropy per nucleon (in units of Boltzmann constant) ≥ 25. Identification of absorption lines in near-infrared wavelengths which have not yet been decoded may lead to clarify the abundances synthesized in NS merger ejecta.