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Gas-Phase Reactions in the ISM: Rate Coefficients, Temperature Dependences, and Reaction Products

Published online by Cambridge University Press:  21 December 2011

Ian W. M. Smith*
Affiliation:
Department of Chemistry, University of Cambridge, Lensfeld Road, Cambridge CB2 1EW, UK
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Abstract

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Information about the rate coefficients and products of processes that occur in the interstellar medium are required as input to computer models that seek to reproduce the abundances of the rich variety of molecules that have been observed in different regions of the interstellar medium. In this brief review, I seek to identify the different kinds of gas-phase processes for which information is required and to consider the experimental, theoretical, and semi-empirical methods which are employed to measure or predict rate coefficients, k(T), and how they depend on temperature (T) – and also how the products of reactions can, in favourable cases, be observed.

Type
Contributed Papers
Copyright
Copyright © International Astronomical Union 2011

References

Adams, N. G. & Smith, D. 1976, Int. J. Mass spectrom. Ion Proc., 21, 349CrossRefGoogle Scholar
Adams, N. G. & Smith, D. 1988, in Rate Coefficients for Astrochemistry, Millar, T.J. and Williams, D.A. (Ed.) (Kluer, Dordrecht) p. 173CrossRefGoogle Scholar
Anicich, V. G. 1993a, ApJS, 84, 215CrossRefGoogle Scholar
Anicich, V. G. 1993b, Phys. Chem. Ref. Data, 22, 1469CrossRefGoogle Scholar
Baulch, D. L., Bowman, C. T., Cobos, C. J., Cox, R. A., Just, Th., et al. , 2005, J. Phys. Chem. Ref. Data, 34, 757CrossRefGoogle Scholar
Bergeat, A., & Loison, J. C., 2001, Phys. Chem. Chem. Phys., 3, 2038CrossRefGoogle Scholar
Blitz, M. A., Seakins, P. W., & Smith, I. W. M., 2009, Phy. Chem. Chem. Phys., 11, 10824CrossRefGoogle Scholar
Bohringer, H., & Arnold, F., 1986, J. Chem. Phys., 48, 1459CrossRefGoogle Scholar
Canosa, A., Goulay, F., Sims, I. R., & Rowe, B. R., 2008, Low Temperatures and Cold Molecules, Smith, I.W.M. (Ed.) (Imperial College press, London) p. 55CrossRefGoogle Scholar
Carty, D., Goddard, A., Köhler, S. P. K., Sims, I. R., & Smith, I. W. M., 2006, J. Phys. Chem. A, 110, 3101CrossRefGoogle Scholar
Cosic, B., & Fontjin, A., 2000, J. Phys. Chem. A, 104, 5517CrossRefGoogle Scholar
Dunn, G. H., 1995, Phys. Scr., T59, 249CrossRefGoogle Scholar
Durkin, D. B., Fehsenfeld, F. C., Schmeltekoff, A. L., & Ferguson, E. E., 1968, J. Chem. Phys., 49, 1365Google Scholar
Ferguson, E. E., Bohme, D. K., Fehsenfeld, F. C., & Durkin, D. B., 1969, J. Chem. Phys., 50, 5039CrossRefGoogle Scholar
Fontijn, A., Shamsuddin, S. M., Anderson, W. R., & Marshall, P., 2006, Combust. Flame., 145, 543CrossRefGoogle Scholar
Fulle, D., Hamann, H. F., Hippler, H., & Troe, J., 1996, J. Chem. Phys., 105, 963Google Scholar
Gannon, K. L., Glowacki, D. R., Blitz, M. A., Hughes, K. J., Pilling, M. J., & Seakins, P. W., 2007, J. Phys. Chem. A., 111, 6676CrossRefGoogle Scholar
Georgievskii, Y., & Klippenstein, S. J., 2005, J. Chem. Phys., 122, 194103CrossRefGoogle Scholar
Georgievskii, Y., & Klippenstein, S. J., 2007, J. Phys. Chem. A., 111, 3802CrossRefGoogle Scholar
Gerlich, D., 1995, Phys. Scr, T59, 256CrossRefGoogle Scholar
Gerlich, D., 2008, Low Temperatures and Cold Molecules, Smith, I.W.M. (Ed.) (Imperial College press, London) p. 121CrossRefGoogle Scholar
Herbst, E., & Klemperer, W., 1973, ApJ, 185, 505CrossRefGoogle Scholar
Herbst, E., Smith, D., Adams, N. G., & DeFrees, D. J., 1987, ApJ, 312, 351CrossRefGoogle Scholar
Jensen, M. J., Bilodeau, R. C., Safvan, C. P., Seirsen, K., Andersen, L. H., Pedersen, H. B., & Heber, O., 2000, ApJ, 543, 764CrossRefGoogle Scholar
McIntosh, B. J., Adams, N. G., & Smith, D., 1988, Chem. Phys. Lett., 148, 143CrossRefGoogle Scholar
Millar, T. J., Rawlings, J. M. C., Bennett, A., & Brown, P. D., Charnley, S. B., 1991, A&A Supplt., 87, 585Google Scholar
Pilling, M. J., & Seakins, P. W., 1995, Reaction Kinetics (New York, Oxford University Press)Google Scholar
Rowe, B. R., Dupeyrat, G., Marquette, J. B., & Gaucherel, P., 1984, J. Chem. Phys., 80, 4915CrossRefGoogle Scholar
Rowe, B. R., Marquette, J. B., Dupeyrat G., & Ferguson, E. E., 1985, Chem. Phys. Lett., 113, 403CrossRefGoogle Scholar
Sabbah, H., Biennier, L., Sims, I. R., Georgievskii, Y., Klippenstein, S. J., & Smith, I. W. M., 2007, Science, 317, 102CrossRefGoogle Scholar
Seakins, P. W., 2007, Ann. Rep. Prog. Chem. Sect. C, 103, 173CrossRefGoogle Scholar
Sims, I. R., & Smith, I. W. M., 1988, J. Chem. Soc. Farad., 84 527CrossRefGoogle Scholar
Sims, I. R., Queffelec, J. L., Defrance, A., Rebrion-Rowe, C., Travers, D., Bocherel, P., Rowe, B. R., & Smith, I. W. M., 1994, J. Chem. Phys., 100, 4229CrossRefGoogle Scholar
Smith, I. W. M., 1988, in Rate Coefficients for Astrochemistry, Millar, T. J. and Williams, D. A. (Ed.) (Kluer, Dordrecht) p. 103CrossRefGoogle Scholar
Smith, I. W. M., 1997, in Molecules in Astrophysics: Probes and Processeses, IAU Symposium 178, van Dishoeck, E.F. (Ed.) p. 253Google Scholar
Smith, I. W. M., 2006, Angew. Chem. Int. Ed., 45, 2842CrossRefGoogle Scholar
Smith, I. W. M., Sage, A. M., Donahue, N. M., Herbst, E., & Quan, D., 2006, Faraday Discuss., 133, 137CrossRefGoogle Scholar
Smith, I. W. M., 2011, ARAA, to be published in September 2011.Google Scholar
Snow, T. P., & Bierbaum, V. M., 2008, Ann. Rev. Anal. Chem., 1, 229CrossRefGoogle Scholar
Taatjes, C. A., & Hershberger, J. F., 2001, Ann. Rev. Phys. Chem., 52, 41CrossRefGoogle Scholar
Talbi, D., & Smith, I. W. M., 2009, Phys. Chem. Chem. Phys., 11, 8477CrossRefGoogle Scholar
Wakelam, V., Smith, I. W. M., Herbst, E., Troe, J., Geppert, W., Linnnartz, H., Őberg, K., Roueff, E., Agundez, M., Pernot, P., et al. , 2010a, Space Science Reviews, 156, 13CrossRefGoogle Scholar
Wakelam, V., Herbst, E., Le Bourlot, J., Hersant, F., Selsis, F., & Guilloteau, S., 2010b, A&A, 156, 13Google Scholar
Viggiano, A. A., 2006, Phys. Chem. Chem. Phys., 8, 2557CrossRefGoogle Scholar