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X-ray powder diffraction data for some nitrogen-donor base adducts of bis(iso-propylxanthato)nickel(II)

Published online by Cambridge University Press:  10 January 2013

Dagmar Krausová ,
Zdeněk Trávníček  and
Tomáš Ondrůšek
Dagmar Krausová
Affiliation:
Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, Křižkovského 10, 771 47 Olomouc, Czech Republic
Zdeněk Trávníček
Affiliation:
Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, Křižkovského 10, 771 47 Olomouc, Czech Republic
Tomáš Ondrůšek
Affiliation:
Department of Inorganic and Physical Chemistry, Faculty of Natural Sciences, Palacký University, Křižkovského 10, 771 47 Olomouc, Czech Republic
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Abstract

X-ray powder diffraction data for [Ni(i-prxa)2(bpy)] (1), [Ni(i-prxa)2(phen)] (2), and [Ni(i-prxa)2(tmen)] (3), where i-pr=i-C3H7, xa=S2CO−, bpy=2,2′-bipyridine, phen=1,10-phenanthroline and tmen=N, N, N′, N′-tetramethylethylenediamine, are reported. For (1): Monoclinic, P21/n, a=10.8255(1) Å, b=12.7423(1) Å, c=15.9796(1) Å, β=92.037(3)°, V=2202.9(1) Å3, Z=4, Mr=485.3, T=296 K, DX=1.463 g/cm3, Dexp=1.47 g/cm3, CuKα1=1.540 51 Å, 63 lines. For (2): Monoclinic, P21/n, a=10.7591(1) Å, b=12.8115(2) Å, c=16.1162(3) Å, β=92.39(1)°, V=2219.5(2) Å3, Z=4, Mr=509.4, T=296 K, DX=1.525 g/cm3, Dexp=1.51 g/cm3, CuKα1=1.540 51 Å, 72 lines. For (3): Orthorhombic, P212121, a=9.341(4) Å, b=15.093(8) Å, c=15.990(7) Å, V=2254(2) Å3, Z=4, Mr=445.35, T=296 K, DX=1.312 g/cm3, Dexp=1.32 g/cm3, CuKα1=1.540 51 Å, 49 lines.

Keywords

nickel xanthatesX-ray powder diffraction2,2′-bipyridine1,10-phenanthrolineN,N,N′,N′-tetramethylethylenediamine
Type
Research Article
Information
Powder Diffraction , Volume 13 , Issue 3 , September 1998 , pp. 171 - 174
Copyright
Copyright © Cambridge University Press 1998

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References

Beneš, L. (1994) “A program package for analysis of X-ray powder diffraction patterns on PC,” Joint Laboratory of Solid State Chemistry of Academy of Science of Czech Republic and Institute of Chemical Technology, 532 10 Pardubice, Czech Republic.Google Scholar
Smith, G. S., and Snyder, R. L. (1979). “F N: A criterion for rating powder diffraction patterns and evaluating the reliability of powder pattern indexing,” J. Appl. Crystallogr. 12, 60.CrossRefGoogle Scholar
Trávníček, Z., Pastorek, R., Šindelář, Z., and Marek, J. (1995a). “Reactions of bis(isopropylxanthato)nickel(II) with N-donor ligands,” Trans. Met. Chem. 20, 67–71.CrossRefGoogle Scholar
Trávníček, Z., Pastorek, R., Šindelář, Z., and Marek, J. (1995b). “Reactions of bis(isopropylxanthato)nickel(II) with N-donor ligands-II,” Polyhedron 14, 3627–3633.CrossRefGoogle Scholar