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X-ray powder diffraction data for Copper (II). bis[(2E)-3-methoxy-2- [(2,4,6-trimethylphenyl)imino]-4-[(2,4,6-trimethylphenyl)imino-κN]- 3-pentanolato-κO] complex

Published online by Cambridge University Press:  15 October 2014

R. Pažout ,
J. Maixner ,
A. Sokolohorskyj  and
J. Merna
R. Pažout*
Affiliation:
Central Laboratories, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
J. Maixner
Affiliation:
Central Laboratories, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague 6, Czech Republic
A. Sokolohorskyj
Affiliation:
Department of Polymers, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague, Czech Republic
J. Merna
Affiliation:
Department of Polymers, Institute of Chemical Technology Prague, Technická 5, 166 28 Prague, Czech Republic
*
a) Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

X-ray powder diffraction data, unit-cell parameters and space group for a new bis(β-diiminato) Cu(II) complex, C48H62CuN4O4 are reported [a = 13.330 (3) Å, b = 11.137(2) Å, c = 8.832(2) Å, α = 78.88(2), β = 94.73(2), γ = 114.55(2), unit-cell volume V = 1170.26 Å3, Z = 1, and space group P − 1]. All measured lines were indexed and are consistent with the P−1 space group. No detectable impurity was observed.

Keywords

unit-cell parametersspace groupX-ray powder diffraction databis(β-diiminato) Cu(II) complex
Type
New Diffraction Data
Information
Powder Diffraction , Volume 29 , Issue 4 , December 2014 , pp. 389 - 392
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Copyright
Copyright © International Centre for Diffraction Data 2014 

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References

Asay, M., Jones, C., and Driess, M. (2011). “N-Heterocyclic carbene analogues with low-valent Group 13 and Group 14 elements: syntheses, structures, and reactivities of a new generation of multitalented ligands,” Chem. Rev. 111, 354–396.Google Scholar
Boultif, A. and Louër, D. (2004). “Powder pattern indexing with the dichotomy method,” J. Appl. Crystallogr. 37, 724–731.Google Scholar
Bourget-Merle, L., Lappert, M. F., and Severn, J. R. (2002). “The chemistry of beta-diketiminatometal complexes,” Chem. Rev. 102, 3031–3065.Google Scholar
De Wolff, P. M. (1968). “A simplified criterion for the reliability of a powder pattern indexing,” J. Appl. Crystallogr. 1, 108–113.Google Scholar
Feldman, J., McLain, S. J., Parthasarathy, A., Marshall, W. J., Calabrese, J. C., and Arthur, S. D. (1997). “Electrophilic metal precursors and a beta-diimine ligand for nickel(II)- and palladium(II)-catalyzed ethylene polymerizations,” Organometallics 16, 1514–1516.Google Scholar
Smith, G. S. and Snyder, R. L. (1979). “FN: a criterion for rating powder diffraction patterns and evaluating the reliability of powder indexing,” J. Appl. Crystallogr. 12, 60–65.Google Scholar
Yokota, S., Tachi, Y., and Itoh, S. (2002). “Oxidative degradation of β-diketiminate ligand in copper(II) and zinc(II) complexes,” Inorg. Chem. 41, 1342–1344.Google Scholar