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X-ray powder diffraction data for κ-Al2O3

Published online by Cambridge University Press:  10 January 2013

M. Halvarsson
Affiliation:
Department of Physics, Chalmers University of Technology, SE-412 96 Göteborg, Sweden
V. Langer
Affiliation:
Department of Inorganic Environmental Chemistry, Chalmers University of Technology, SE-412 96 Göteborg, Sweden
S. Vuorinen
Affiliation:
Research and Development, Seco Tools AB, SE-737 82 Fagersta, Sweden

Abstract

X-ray powder diffraction data for κ-Al2O3 are reported. It was concluded that κ-Al2O3 belongs to the orthorhombic crystal system with space group Pna21. The lattice parameters were found to be a=4.8351(3) Å, b=8.3109(5) Å, c=8.9363(3) Å. There are 16 Al3+ and 24 O2− in the unit cell, and thus the number of chemical formulas in the unit cell, Z, is 8. The volume V of the unit cell is equal to 359.09(6) Å3 and the theoretical density Dx is 3.772 g/cm3. The Smith–Snyder (F20) and the de Wolff (M20) values for these data are 136.1 (0.0059, 25) and 98.4, respectively.

Keywords

Type
Research Article
Copyright
Copyright © Cambridge University Press 1999

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References

Halvarsson, M., Langer, V., and Vuorinen S. (1994). “Structure models for κ-Al 2O 3,” Paper 9 in The microstructure and stability of CVD alumina coatings, M. Halvarsson, Ph.D. Thesis, Chalmers Univ. of Technology, Göteborg, Sweden (1994), ISBN 91-7197-016-9.Google Scholar
Liu, P., and Skogsmo, J. (1991). “Space-group determination and structure model for κ-Al 2O 3 by convergent-beam electron diffraction (CBED),” Acta Crystallogr., Sect. B: Struct. Sci. 47, 425433.CrossRefGoogle Scholar
Ruppi, S. (1992). U.S. Patent 5137774.Google Scholar
Skogsmo, J., Liu, P., Chatfield, C., and Nordén, H. (1989). “Micro-structural observations on alumina coatings produced by Chemical Vapor Deposition,” in Proc. 12th Int. Plansee Seminar, edited by H. Bildstein and H. M. Ortner, Vol. 3 (Metallwerk Plansee, Reutte, Austria), pp. 129–142.Google Scholar
Stumpf, H. C., Russel, A. S., Newsome, J. W., and Tucker, C. M. (1950). “Thermal transformations of aluminas and alumina hydrates,” Ind. Eng. Chem. Res. 42, 13981403.CrossRefGoogle Scholar
WIN-METRIC, Ver 1.3, Sigma-C Gmbh, Siemens Analytical X-ray systems.Google Scholar