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The water retention mechanism of a Cs+ and Na+ exchanged montmorillonite: effect of relative humidity and ionic radius on the interlayer

Published online by Cambridge University Press:  11 March 2015

Marwa Ammar ,
Walid Oueslati ,
Nejmeddine Chorfi  and
Abdesslem Ben Haj Amara
Marwa Ammar
Affiliation:
UR 05/13-01: Physique des Matériaux Lamellaires et Nanomatériaux Hybrides (PMLNMH), Faculté des Sciences de Bizerte, Zarzouna 7021, Tunisia
Walid Oueslati*
Affiliation:
UR 05/13-01: Physique des Matériaux Lamellaires et Nanomatériaux Hybrides (PMLNMH), Faculté des Sciences de Bizerte, Zarzouna 7021, Tunisia General Studies Department, College of Electronics and Communications, Technical and Vocational Training Corporation, TV Street, P.O. Box 2816, Jeddah 21461, Saudi Arabia
Nejmeddine Chorfi
Affiliation:
Department of Mathematics, College of Science, King Saud University, P.O. Box 2455, Riyadh 11451, Saudi Arabia
Abdesslem Ben Haj Amara
Affiliation:
UR 05/13-01: Physique des Matériaux Lamellaires et Nanomatériaux Hybrides (PMLNMH), Faculté des Sciences de Bizerte, Zarzouna 7021, Tunisia
*
a) Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

Dioctahedral smectites are clay minerals that widely used as a crucial component for the edifice of natural barriers in industrial wastes and wastewater treatment. The hydration behaviours of these mineral types are very sensitive by environmental surroundings changes. The present work focuses the evolution of the interlayer water amount as a function of the relative humidity rates (RH), varied along a humidifying-drying cycle, in the case of two dioctahedral smectites with different charge location (i.e. Wyoming montmorillonite SWy-2 and Beidellite SbId-1). The CEC (i.e. cation exchange capacity) of the studied sample is saturated by two monovalent cations (i.e., Cs+ and Na+) characterized by a different ionic radius. The X-ray diffraction (XRD) profile modelling tools based on the indirect method that consist on the comparison of experimental 00l reflections with other calculated from structural models is used to perform these aims. The qualitative XRD profile investigation suggests heterogeneous hydration behaviour at different stage of the cycle for all studied samples. The water content fluctuation, confirmed by the appearance of a hydration hysteresis, within the interlamellar space of diverse complexes is an irreversible process during the shrinking–rewetting sequence. Comparing to Na+ cations, the presence of the Cs+ ions in exchangeable sites of both smectite structures is accompanied by more orderliness of systems, which retunes the lowest water molecules amount over the applied cycle.

Keywords

dioctahedral smectitesXRD profile modellingshrinking–rewettingwater retention and hysteresis
Type
Technical Articles
Information
Powder Diffraction , Volume 30 , Supplement S1 , June 2015 , pp. S70 - S75
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Copyright
Copyright © International Centre for Diffraction Data 2015 

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References

Ammar, M., Oueslati, W., Ben Rhaiem, H., and Ben Haj Amara, A. (2013). “XRD profile modeling approach tools to investigate the effect of charge location on hydration behavior in the case of metal exchanged smectite,” Powder Diffr. 28(S2), 284–300.Google Scholar
Ammar, M., Oueslati, W., Ben Rhaiem, H., and Ben Haj Amara, A. (2014a). “Quantitative XRD analysis of the dehydration–hydration performance of (Na + , Cs+) exchanged smectite,” Desalination Water Treat. 52, 4314–4333.Google Scholar
Ammar, M., Oueslati, W., Ben Rhaiem, H., and Ben Haj Amara, A. (2014b). “Effect of the hydration sequence orientation on the structural properties of Hg exchanged montmorillonite: quantitative XRD analysis,” J. Environ. Chem. Eng. 2, 1604–1611.Google Scholar
Atun, J. G. and Bascetin, E. (2004). “Adsorption of barium on kaolinite, illite and montmorillonite at various ionic strengths,” Radiochim. Acta 91, 223–228.Google Scholar
Bradley, W. F., Grim, R. E., and Clar, G. F. (1937). “A study of the behavior of montmorillonite on wetting,” Z. Kristallogr. 97, 260–270.Google Scholar
Chalghaf, R., Oueslati, W., Ammar, M., Ben Rhaiema, H., and Ben Haj Amaraa, A. (2013). “Effect of temperature and pH value on cation exchange performance of a natural clay for selective (Cu2+, Co2+) removal: equilibrium, sorption and kinetics,” Progr. Nat. Sci.: Mater. Int. 23, 23–35.Google Scholar
Cháveza, M. L., Pablob, L., and Garcíaa, T. A. (2010). “Adsorption of Ba2+ by Ca-exchange clinoptilolite tuff and montmorillonite clay,” J. Hazard. Mater. 175, 216–223.Google Scholar
Cases, J. M., Berend, I., Besson, G., Franqois, M., Uriot, J. R., Thomas, F., and Poirier, J. E. (1992). “Mechanism of adsorption and desorption of water vapor by homoionic montmorillonite.1.The sodium exchanged form,” Langmuir 82, 2730–2739.Google Scholar
Drits, V. A. and Tchoubar, C. (1990). X-ray Diffraction by Disordered Lamellar Structures: Theory and Applications to Microdivided Silicates and Carbons (Springer-Verlag, Berlin), 371 pp.Google Scholar
Di, X., Zhou, X., and Wang, X. (2008). “Adsorption and desorption of Ni2+ on Na-montmorillonite: effect of pH, ionic strength, fulvic acid, humic acid and addition sequences,” Appl. Clay Sci. 39, 133–141.Google Scholar
Ferrage, E., Lanson, B., Malikova, N., Plançon, A., Sakharov, B. A., and Drits, V. A. (2005a). “New insights on the distribution of interlayer water in bi-hydrated smectite from X-ray diffraction profile modeling of 00l reflections,” Chem. Mater. 17, 3499–3512.Google Scholar
Ferrage, E., Lanson, A., Sakharov, B. A., and Drits, V. A. (2005b). “Investigation of smectite hydration properties by modeling of X-ray diffraction profiles. Part 1. Montmorillonite hydration properties,” Am. Miner. 90, 1358–1374.CrossRefGoogle Scholar
Ferrage, E., Kirk, C. A., Cressey, G., and Cuadros, J. (2007). “Dehydration of Ca-montmorillonite at the crystal scale. Part I: structure evolution,” Am. Miner. 92, 994–1006.Google Scholar
Ferrage, E., Lanson, B., Micho, L. J., and Robert, J. L. (2010). “Hydration properties and interlayer organization of water and Ions in synthetic Na-smectite with tetrahedral layer charge. Part 1. Results from X-ray diffraction profile modelin,” J. Phys. Chem. C 114, 4515–4526.Google Scholar
Gupta, S. S. and Bhattacharyya, K. G. (2008). “Immobilization of Pb(II), Cd(II) and Ni(II) ions on kaolinite and montmorillonite surfaces from aqueous medium,” J. Environ. Manag. 87, 46–58.Google Scholar
Lanson, B. (2011). “Modelling of X-ray diffraction profiles: investigation of defective lamellar structure crystal chemistry,” EMU Notes Miner. 11, 151–202.Google Scholar
Malikova, N., Marrya, V., Dufrechea, J. F., and Turqa, P. (2004). “Na/Cs montmorillonite: temperature activation of diffusion by simulation,” Curr. Opin. Colloid Interface Sci. 9, 124–127.Google Scholar
Moll, W. F. (2001). “Baseline studies of the clay minerals society source clays: geological origin,” Clays Clay Mine 49, 374–380.Google Scholar
Mooney, R. W., Keenan, A. G., and Wood, L. A. (1952). “Adsorption of water vapor by montmorillonite. II. Effect of exchangeable ions and lattice swelling as measured by X-ray diffraction,” J. Am. Chem. Soc. 74, 1331–1374.CrossRefGoogle Scholar
Moore, D. M. and Reynolds, R. C. (1997). X-ray Diffraction and the Identification and Analysis of Clay Minerals (Oxford University Press, New York), pp. 322.Google Scholar
Norrish, K. (1954). “The swelling of montmorillonite,” Discuss. Faraday Soc. 18, 120–133.Google Scholar
Oueslati, W., Karmous, M. S., Ben Rhaiem, H., Lanson, B., and Ben Haj Amara, A. (2007). “Effect of interlayer cation and relative humidity on the hydration properties of a dioctahedral smectite,” Z. Kristallogr. Suppl. 2(26), 417–422.Google Scholar
Oueslati, W., Ben Rhaiem, H., Lanson, B., and Ben Haj Amara, A. (2009a). “Selectivity of Na–montmorillonite in relation with the concentration of bivalent cation (Cu2+, Ca2+, Ni2+) by quantitative analysis of XRD patterns,” Appl. Clay Sci. 43, 224–227.Google Scholar
Oueslati, W., Meftah, M., Ben Rhaiem, H., and Ben Haj Amara, A. (2009b). “Selectivity of Na-montmorillonite versus concentration of two competitive bivalent cations (Cu2+, Pb2+): quantitative XRD investigation,” Adv. Mater. Sci. Eng., 2009, Article ID 385673.Google Scholar
Oueslati, W., Ben Rhaiem, H., and Ben Haj Amara, A. (2011). “XRD investigations of hydrated homoionic montmorillonite saturated by several heavy metal cations,” Desalination 271, 139–149.Google Scholar
Oueslati, W., Ben Rhaïem, H., Lanson, B., and Ben Haj Amara, , (2012). “Effect of relative humidity vconstraint on the metal exchanged montmorillonite performance: an XRD profile modeling approach,” Appl. Clay Sci. 261, 396–404.Google Scholar
Phothitontimongkol, Th., Siebers, N., Sukpirom, N., and Unob, F. (2009). “Preparation and characterization of novel organo-clay minerals for Hg(II) ions adsorption from aqueous solution,” Appl. Clay Sci. 43, 343–349.Google Scholar
Sakharov, B. A. and Drits, V. A. (1973). “Mixed-layer kaolinte–montmorillonite: a comparison observed and calculated diffraction patterns,” Clays Clay Miner. 21, 15–17.Google Scholar
Sato, T., Watanabe, T., and Otsuka, R. (1992). “Effects of layer charge, charge location, and energy change on expansion properties of dioctahedral smectites,” Clays Clay Miner. 40, 103–113.Google Scholar
Tessier, D. (1984). “Etude expérimentale de l'organisation des matériaux argileux. Hydratation, gonflement et structure au cours de la dessiccation et de la réhumectation”. Thèse Université de Paris VII, Publication INRA Versailles, (France).Google Scholar
Walker, G. F. (1956). “The mechanism of dehydration of Mg-vermiculite,” Clays Clay Miner. 4, 101–115.Google Scholar
Zamparas, M., Deligiannakis, Y., and Zacharias, I. (2013). “Phosphate adsorption from natural waters and evaluation of sediment capping using modified clays,” Desalination Water Treat. 51, 2895–2902.Google Scholar