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Structural analysis of Ba0.8Sr0.2Ti0.6Zr0.3Mn0.1O3 ceramics

Published online by Cambridge University Press:  20 January 2023

G. Murugesan Open the ORCID record for G. Murugesan [Opens in a new window] ,
Nandhan K. R. Open the ORCID record for Nandhan K. R. [Opens in a new window] ,
N. Maruthi ,
A. Muthuraja ,
Saraswathi Bhaskar  and
M. Manigandan
G. Murugesan
Affiliation:
Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R and D Institute of Science and Technology, Chennai 600062, Tamil Nadu, India
Nandhan K. R.*
Affiliation:
Department of Physics, Faculty of Engineering and Technology, Jain University, Bangalore 562112, Karnataka, India
N. Maruthi
Affiliation:
Department of Physics, Faculty of Engineering and Technology, Jain University, Bangalore 562112, Karnataka, India
A. Muthuraja
Affiliation:
Department of Physics, Theivanai Ammal College for Women (Autonomous), Villupuram, Tamil Nadu, India
Saraswathi Bhaskar
Affiliation:
Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R and D Institute of Science and Technology, Chennai 600062, Tamil Nadu, India
M. Manigandan
Affiliation:
Department of Physics, Vel Tech Rangarajan Dr. Sagunthala R and D Institute of Science and Technology, Chennai 600062, Tamil Nadu, India Department of Physics, Government Arts and Science College, Thiruvennainallur, Villupuram, Tamil Nadu, India
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

Polycrystalline Ba0.8Sr0.2Ti0.6Zr0.3Mn0.1O3 was synthesized by solid-state reaction at 1600°C. The single phase formation of the compound without any impurities was confirmed by the X-ray diffraction technique. The prepared compound crystallized to a cubic structure with a space group of Pm-3m and the refined lattice parameters were a = b = c = 4.0253 Ǻ, α = β = γ = 90°. Rietveld refinement was carried for the powder XRD data using GSAS software and the experimental data peaks were indexed by Powder X software.

Keywords

Rietveld refinementoxidesX-ray diffraction
Type
New Diffraction Data
Information
Powder Diffraction , Volume 38 , Issue 1 , March 2023 , pp. 27 - 29
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Copyright
Copyright © Jain (Deemed-to-be University), Bangalore, 2023. Published by Cambridge University Press on behalf of International Centre for Diffraction Data

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References

REFERENCES

Das, S. K., Rout, P. P., Pradhan, S. K., and Roul, B. K.. 2012. “Effect of Equiproprotional Substitution of Zn and Mn in BaTiO3 Ceramic—An Index to Multiferroic Applications.” Journal of Advanced Ceramics 1 (3): 241–8.CrossRefGoogle Scholar
Dong, C. 1999. “PowderX: Windows-95-Based Program for Powder X-Ray Diffraction Data Processing.” Journal of Applied Crystallography 32: 4.CrossRefGoogle Scholar
Kim, Y. I., Jung, J. K., and Ryu, K. S.. 2004. “Structural Study of Nano BaTiO3 Powder by Rietveld Refinement.” Materials Research Bulletin 39 (7–8): 1045–53.CrossRefGoogle Scholar
Levin, I., Cockayne, E., Krayzman, V., Woicik, J. C., Lee, S., and Randall, C. A.. 2011. “Local Structure of Ba (Ti,Zr)O3 Perovskite-like Solid Solutions and Its Relation to the Band-Gap Behavior.” Physical Review B 83 (9): 094122.CrossRefGoogle Scholar
Momma, K., and Izumi, F.. 2013. “VESTA 3 for Three-Dimensional Visualization of Crystal, Volumetric and Morphology Data.” Journal of Applied Crystallography 44: 1272–6.CrossRefGoogle Scholar
Nandan, K. R., and Kumar, A. R.. 2017. “Effect of Sr-Doping on Structure and Electrical Properties of (Ba1−xSrxTi0.6Zr0.3Mn0.1O3)x=0.1 and 0.2 Synthesized by Solid State Reaction.” Journal of Materials Science: Materials in Electronics 28 (10): 7221–30.Google Scholar
Sindhu, M., Ahlawat, N., Sanghi, S., Kumari, R., and Agarwal, A.. 2013. “Crystal Structure Refinement and Investigation of Electrically Heterogeneous Microstructure of Single Phased Sr Substituted BaTiO3 Ceramics.” Journal of Alloys and Compounds 575: 109–14.CrossRefGoogle Scholar
Toby, B. H., and Von Dreele, R. B.. 2013. “GSAS-II: The Genesis of a Modern Open-Source All Purpose Crystallography Software Package.” Journal of Applied Crystallography 46 (2): 544–9.CrossRefGoogle Scholar
Wang, J., Rong, G., Wang, T., and Yao, H.. 2014. “Impact of Sr on the Performance of BaTi0.9Zr0.1O3–BaTiO3 Dielectric Powders.” Modern Physics Letters B 28 (14): 1450114.CrossRefGoogle Scholar
Xue, D., Zhou, Y., Bao, H., Gao, J., Zhou, C., and Ren, X.. 2011. “Large Piezoelectric Effect in Pb-free Ba(Ti,Sn)O3-x(Ba,Ca)TiO3 Ceramics.” Applied Physics Letters 99 (12): 122901.CrossRefGoogle Scholar
Yu, Y., Zou, H., Cao, Q. F., Wang, X. S., Li, Y. X., and Yao, X.. 2015. “Phase Transitions and Relaxation Behaviors in Barium Strontium Titanate Ceramics Determined by Dynamic Mechanical and Dielectric Analysis.” Ferroelectrics 487 (1): 77–85.CrossRefGoogle Scholar
Zhou, L., Vilarinho, P. M., and Baptista, J. L.. 1999. “Dependence of the Structural and Dielectric Properties of Ba1–xSrxTiO3 Ceramic Solid Solutions on Raw Material Processing.” Journal of the European Ceramic Society 19 (11): 2015–20.CrossRefGoogle Scholar