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Progress in mineralogical quantitative analysis of rock samples: application to quartzites from Denali National Park, Alaska Range (USA)

Published online by Cambridge University Press:  17 February 2016

Mărgărit M. Nistor ,
Nicolae Har ,
Simona Marchetti Dori ,
Simona Bigi  and
Alessandro F. Gualtieri
Mărgărit M. Nistor
Affiliation:
Dipartimento di Scienze Chimiche e Geologiche, Università di Modena e Reggio Emilia, Via S. Eufemia 19, I-41121 Modena, Italy
Nicolae Har
Affiliation:
Department of Geology, University of Babeş-Bolyai, Kogălniceanu Street 1, 400084 Cluj-Napoca, Romania
Simona Marchetti Dori
Affiliation:
Dipartimento di Scienze Chimiche e Geologiche, Università di Modena e Reggio Emilia, Via S. Eufemia 19, I-41121 Modena, Italy
Simona Bigi
Affiliation:
Dipartimento di Scienze Chimiche e Geologiche, Università di Modena e Reggio Emilia, Via S. Eufemia 19, I-41121 Modena, Italy
Alessandro F. Gualtieri
Affiliation:
Dipartimento di Scienze Chimiche e Geologiche, Università di Modena e Reggio Emilia, Via S. Eufemia 19, I-41121 Modena, Italy
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Abstract

This work deals with the determination of the mineralogical composition of three quartzite samples, selected as case study to verify the viability and accuracy of various experimental techniques commonly used in geometallurgy and petrography for the determination of the mineralogical composition of rock samples. The investigated samples are from the North-Eastern side of the Denali National Park (Alaska Range, USA). The mineralogical phase abundance of the samples was determined by digitally assisted optical modal point counting, scanning electron microscopy (SEM) + energy dispersive spectroscopy (EDS) modal and digital image analysis, normative calculation from bulk chemistry calculation, and modal Rietveld X-ray powder diffraction. The results of our study indicate that the results provided by modal optical and SEM digitalized counting seem less accurate than the others. The determination with EDS mapping was found to be inaccurate only for one sample. Agreement was found between the X-ray diffraction estimates and bulk chemistry calculation. For both modal optical and SEM digitalized counting, the statistics was probably insufficient to provide accurate results. The estimates obtained from the various methods are compared with each other in the attempt to attain general indications on the precision, accuracy, advantages/disadvantages of each method.

Keywords

Rietveld methodDenali quartziteoptical countingSEMEDSbulk chemistry calculation
Type
Technical Articles
Information
Powder Diffraction , Volume 31 , Issue 1 , March 2016 , pp. 31 - 39
Copyright
Copyright © International Centre for Diffraction Data 2016 

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