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Powder X-ray diffraction structural characterization of the coordination complex cis-[Co(κ2N,N′-1,10-phenanthroline-5,6-dione)2Cl2]

Published online by Cambridge University Press:  19 February 2018

José A. Fernandes ,
Olufunso Abosede  and
Simona Galli
José A. Fernandes
Affiliation:
Dipartimento di Scienza e Alta Tecnologia, Università dell'Insubria, via Valleggio 11, 22100 Como, Italy
Olufunso Abosede
Affiliation:
Department of Chemistry, Federal University Otuoke, PMB 126, Yenagoa, Bayelsa State, Nigeria
Simona Galli*
Affiliation:
Dipartimento di Scienza e Alta Tecnologia, Università dell'Insubria, via Valleggio 11, 22100 Como, Italy
*
a)Author to whom correspondence should be addressed. Electronic mail: [email protected]
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Abstract

The reduction of cis-[CoIII(κ2N,N′-1,10-phenanthroline-5,6-dione)2Cl2]Cl into the neutral compound cis-[CoII(κ2N,N′-1,10-phenanthroline-5,6-dione)2Cl2] was observed during developmental studies of new antimalarial drugs. The crystal structure of cis-[CoII(κ2N,N′-1,10-phenanthroline-5,6-dione)2Cl2] was unveiled by powder X-ray diffraction studies (PXRD). PXRD details, unit cell parameters, and space group for cis-[CoII(κ2N,N′-1,10-phenanthroline-5,6-dione)2Cl2], C24H12Cl2CoN4O4, are reported [a = 41.4951 (13) Å, b = 8.2768 (2) Å, c = 12.4994 (3) Å, unit cell volume V = 4292.9 (2) Å3, Z = 8, and space group Fdd2]. Infrared spectroscopy features are also discussed.

Keywords

powder X-ray diffractioncobalt1,10-phenanthroline-5,6-dionecrystal structure
Type
New Diffraction Data
Information
Powder Diffraction , Volume 33 , Issue 1 , March 2018 , pp. 55 - 61
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Copyright
Copyright © International Centre for Diffraction Data 2018 

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