Hostname: page-component-586b7cd67f-gb8f7 Total loading time: 0 Render date: 2024-11-24T05:53:16.715Z Has data issue: false hasContentIssue false
  • English
  • Français

Powder diffraction of [Co(NH3)5CO3]NO3·1/2H2O and [Co(NH3)4CO3]NO3·1/2H2O

Published online by Cambridge University Press:  10 January 2013

Hongxiang Wu ,
Jianghai Zhu ,
Lidun Ma ,
Xiaoliang Shen  and
Guoshun Shi
Hongxiang Wu
Affiliation:
Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People's Republic of China
Jianghai Zhu
Affiliation:
Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People's Republic of China
Lidun Ma
Affiliation:
Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People's Republic of China
Xiaoliang Shen
Affiliation:
Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People's Republic of China
Guoshun Shi
Affiliation:
Center for Analysis and Measurement, Fudan University, Shanghai, 200433, People's Republic of China
Get access Rights & Permissions [Opens in a new window]

Abstract

Two compounds, [Co(NH3)5CO3]NO3·1/2H2O (labeled A) and [Co(NH3)4CO3]NO3·1/2H2O (labeled B), were obtained and characterized by X-ray powder diffraction. The samples were indexed using the programs TREOR90 and DICVOL91. In a monoclinic setting, the cell parameters are a=7.6661(3) Å, b=9.6212(3) Å, c=7.0725(4) Å, β=106.261(4)°, V=500.78 Å3, M20=36, F30=65 (0.0106, 44) for A and a=10.5623(5) Å, b=22.7304(18) Å, c=7.5174(5) Å, β=91.350(5)°, V=1804.31 Å3, M20=36, F30=82 (0.0071, 52) for B. The space group is probably P21/m(11) for A and P21/n(14) for B according to their reflection conditions.

Type
Research Article
Information
Powder Diffraction , Volume 13 , Issue 1 , March 1998 , pp. 32 - 34
Copyright
Copyright © Cambridge University Press 1998

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Basolo, F., and Kent Murmann, R. (1953). “56. Acidopentamminecobalt(III) salts,” Inorg. Synth., 4, 171–172.Google Scholar
Boultif, A., and Louer, D. (1991). “Indexing of Powder Diffraction Pattern for Low-symmetry Lattices by Successive Dichotomy Method,” J. Appl. Crystallogr., 24, 987–993.CrossRefGoogle Scholar
Calvert, L. D., Flippen-Anderson, J. L., Hubbard, C. R., et al. (1983). “Appendix 4: The Standard Data Form for Powder Diffraction Data,” Guidelines for Grant-in-Aid Proposals, 14, Established by ACA and Endorsed By IUCr and ICDD.Google Scholar
Laligant, Y., and Le Bail, A. (1995). “Structure of [Pd(NH 3)4]Cr 2O 7,”Powder Diffr., 10, 159.CrossRefGoogle Scholar
Schlessinger, G. (1960). “55. Carbonatotetramminecobal t(III) Nitrate,” Inorg. Synth., 6, 173–175.CrossRefGoogle Scholar
Werner, P. E. (1969). “A FORTRAN program for least-squares refinement of crystal-structure cell dimensions,” Ark. Kemi 31, 513–516.Google Scholar
Werner, P. E. (1985). “TREOR, a semi-exhaustive trial-and-error powder indexing program for all symmetries,” J. Appl. Crystallogr., 18,367-370.CrossRefGoogle Scholar